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Lead‐Free Halide Perovskite Nanocrystals: Crystal Structures, Synthesis, Stabilities, and Optical Properties

Fan, Qianqian, Biesold‐McGee, Gill V., Ma, Jianzhong, Xu, Qunna, Pan, Shuang, Peng, Juan, Lin, Zhiqun·2020·Angewandte Chemie International Edition

Abstract

In recent years, there have been rapid advances in the synthesis of lead halide perovskite nanocrystals (NCs) for use in solar cells, light emitting diodes, lasers, and photodetectors. These compounds have a set of intriguing optical, excitonic, and charge transport properties, including outstanding photoluminescence quantum yield (PLQY) and tunable optical band gap. However, the necessary inclusion of lead, a toxic element, raises a critical concern for future commercial development. To address the toxicity issue, intense recent research effort has been devoted to developing lead‐free halide perovskite (LFHP) NCs. In this Review, we present a comprehensive overview of currently explored LFHP NCs with an emphasis on their crystal structures, synthesis, optical properties, and environmental stabilities (e.g., UV, heat, and moisture resistance). In addition, strategies for enhancing optical properties and stabilities of LFHP NCs as well as the state‐of‐the‐art applications are discussed. With the perspective of their properties and current challenges, we provide an outlook for future directions in this rapidly evolving field to achieve high‐quality LFHP NCs for a broader range of fundamental research and practical applications.

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Metadata

Authors
Fan, Q., Biesold‐McGee, G. V., Ma, J., Xu, Q., Pan, S., Peng, J., & Lin, Z.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2019-12-12
Volume
59
Issue
3
Pages
1030-1046
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W2945879547
Cited by
460
References
3
FWCI
20.88
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Lead‐Free Halide Perovskite Nanocrystals: Crystal Structures, Synthesis, Stabilities, and Optical Properties. https://app.cochat.ai/papers/10.1002/anie.201904862
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Fan, Q., Biesold‐McGee, G. V., Ma, J., Xu, Q., Pan, S., Peng, J., & Lin, Z. (2020). Lead‐Free Halide Perovskite Nanocrystals: Crystal Structures, Synthesis, Stabilities, and Optical Properties. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201904862

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