The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Enhanced Electrocatalytic Hydrogen Oxidation on Ni/NiO/C Derived from a Nickel‐Based Metal–Organic Framework
Abstract
The sluggish hydrogen oxidation reaction (HOR) under alkaline conditions has hindered the commercialization of hydroxide‐exchange membrane hydrogen fuel cells. A low‐cost Ni/NiO/C catalyst with abundant Ni/NiO interfacial sites was developed as a competent HOR electrocatalyst in alkaline media. Ni/NiO/C exhibits an HOR activity one order of magnitude higher than that of its parent Ni/C counterpart. Moreover, Ni/NiO/C also shows better stability and CO tolerance than commercial Pt/C in alkaline media, which renders it a very promising HOR electrocatalyst for hydrogen fuel cell applications. Density functional theory (DFT) calculations were also performed to shed light on the enhanced HOR performance of Ni/NiO/C; the DFT results indicate that both hydrogen and hydroxide achieve optimal binding energies at the Ni/NiO interface, resulting from the balanced electronic and oxophilic effects at the Ni/NiO interface.
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Cites
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Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes
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Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption
Strmcnik, D., Uchimura, M., Wang, C., Subbaraman, R., Danilovic, N., van der Vliet, D., Paulikas, A. P., Stamenkovic, V. R., & Markovic, N. M. (2013) · Nature Chemistry · doi:10.1038/nchem.1574 · Cited by 1,426
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Cleaning the air and improving health with hydrogen fuel-cell vehicles
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Self-citation
Cited by
Electrocatalysis in Alkaline Media and Alkaline Membrane-Based Energy Technologies
Yang, Y., Peltier, C. R., Zeng, R., Schimmenti, R., Li, Q., Huang, X., Yan, Z., Potsi, G., Selhorst, R., Lu, X., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00331 · Cited by 544
Self-citationZhang, B., Wang, J., Liu, G., Weiss, C. M., Liu, D., Chen, Y., Xia, L., Zhou, P., Gao, M., Liu, Y., et al. (2024) · Nature Catalysis · doi:10.1038/s41929-024-01126-3 · Cited by 567
Recent progress in metal–organic frameworks (MOFs) for electrocatalysis
Li, C., Zhang, H., Liu, M., Lang, F.-F., Pang, J., & Bu, X.-H. (2023) · Industrial Chemistry & Materials · doi:10.1039/d2im00063f · Cited by 339
Alloying Nickel with Molybdenum Significantly Accelerates Alkaline Hydrogen Electrocatalysis
Wang, M., Yang, H., Shi, J., Chen, Y., Zhou, Y., Wang, L., Di, S., Zhao, X., Zhong, J., Cheng, T., et al. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202013047 · Cited by 285
Zhao, G., Jiang, Y., Dou, S.-X., Sun, W., & Pan, H. (2021) · Science Bulletin · doi:10.1016/j.scib.2020.09.014 · Cited by 253
Metadata
- Authors
- Yang, Y., Sun, X., Han, G., Liu, X., Zhang, X., Sun, Y., Zhang, M., Cao, Z., & Sun, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-06-27
- Volume
- 58
- Issue
- 31
- Pages
- 10644-10649
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2948994301
- Cited by
- 271
- References
- 7
- FWCI
- 6.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, Y., Sun, X., Han, G., Liu, X., Zhang, X., Sun, Y., Zhang, M., Cao, Z., & Sun, Y. (2019). Enhanced Electrocatalytic Hydrogen Oxidation on Ni/NiO/C Derived from a Nickel‐Based Metal–Organic Framework. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201905430
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