Correlating hydrogen oxidation and evolution activity on platinum at different pH with measured hydrogen binding energy
Open accessAbstract
The hydrogen oxidation/evolution reactions are two of the most fundamental reactions in distributed renewable electrochemical energy conversion and storage systems. The identification of the reaction descriptor is therefore of critical importance for the rational catalyst design and development. Here we report the correlation between hydrogen oxidation/evolution activity and experimentally measured hydrogen binding energy for polycrystalline platinum examined in several buffer solutions in a wide range of electrolyte pH from 0 to 13. The hydrogen oxidation/evolution activity obtained using the rotating disk electrode method is found to decrease with the pH, while the hydrogen binding energy, obtained from cyclic voltammograms, linearly increases with the pH. Correlating the hydrogen oxidation/evolution activity to the hydrogen binding energy renders a monotonic decreasing hydrogen oxidation/evolution activity with the hydrogen binding energy, strongly supporting the hypothesis that hydrogen binding energy is the sole reaction descriptor for the hydrogen oxidation/evolution activity on monometallic platinum. Hydrogen oxidation and evolution are two of the key reactions in renewable energy conversion and storage devices. Here, the authors report the correlation between reaction rate and measured hydrogen binding energy for polycrystalline platinum in buffer solutions ranging from pH 0 to 13.
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Increased HBE on Pt at high pH leads to much more sluggish HOR kinetics in alkaline media.
“The increased HBE on Pt at a high pH leads to the much more sluggish HOR kinetics in alkaline media [22,23].”
From Lamellar platinum–rhodium aerogels with superior electrocatalytic performance for both hydrogen oxidation and evolution reaction in alkaline environment (2019) · cites this paper as [23]
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- Authors
- Sheng, W., Zhuang, Z., Gao, M., Zheng, J., Chen, J. G., & Yan, Y.
- Affiliations
- University of Delaware (US)
- Columbia University (US)
- Corresponding author
- Chen, Jingguang G.
- Yan, Yushan
- Venue
- Nature Communications
- Published
- 2015-01-08
- Volume
- 6
- Issue
- 1
- Pages
- 5848-5848
- ISSN
- 2041-1723 (ISSN-L)
- OpenAlex
- W2079456080
- Cited by
- 1,136
- References
- 32
- Citations by year
- 2026: 116 · 2025: 121 · 2024: 117 · 2023: 136 · 2022: 119 · 2021: 125 · 2020: 115 · 2019: 93 · 2018: 79 · 2017: 50 · 2016: 45 · 2015: 20
- FWCI
- 19.14
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Nature Communications (publishedVersion)
- PubMed (publishedVersion)
- RePEc: Research Papers in Economics (submittedVersion)
- Funders
- U.S. Department of Energy (DE‐FG02‐, DE‐FG02‐13ER16381)
- Advanced Research Projects Agency - Energy (DE-AR0000009)
- Advanced Research Projects Agency
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Keywords
- hydrogen oxidation, hydrogen evolution reaction, platinum catalysts, hydrogen binding energy, electrolyte pH, polycrystalline platinum, electrocatalysis
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