The DOI matches its Crossref record; 79 of the 79 references it cites were found in a registry or an index.
Beyond Charge Balance: Counter‐Cations in Polyoxometalate Chemistry
Open accessAbstract
Polyoxometalates (POMs) are molecular metal‐oxide anions applied in energy conversion and storage, manipulation of biomolecules, catalysis, as well as materials design and assembly. Although often overlooked, the interplay of intrinsically anionic POMs with organic and inorganic cations is crucial to control POM self‐assembly, stabilization, solubility, and function. Beyond simple alkali metals and ammonium, chemically diverse cations including dendrimers, polyvalent metals, metal complexes, amphiphiles, and alkaloids allow tailoring properties for known applications, and those yet to be discovered. This review provides an overview of fundamental POM–cation interactions in solution, the resulting solid‐state compounds, and behavior and properties that emerge from these POM–cation interactions. We will explore how application‐inspired research has exploited cation‐controlled design to discover new POM materials, which in turn has led to the quest for fundamental understanding of POM–cation interactions.
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Cites
Ultrastructural Characterization of the Lower Motor System in a Mouse Model of Krabbe Disease
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The structure and formula of 12-phosphotungstic acid
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Self-citationHuang, Y., Zhong, M., Shi, F., Liu, X., Tang, Z., Wang, Y., Huang, Y., Hou, H., Xie, X., & Zhi, C. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201705212 · Cited by 563
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Cited by
Comprehensive overview of polyoxometalates for electrocatalytic hydrogen evolution reaction
Zeb, Z., Huang, Y., Chen, L., Zhou, W., Liao, M., Jiang, Y., Li, H., Wang, L., Wang, L., Wang, H., et al. (2023) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2023.215058 · Cited by 208
Metadata
- Authors
- Misra, A., Kozma, K., Streb, C., & Nyman, M.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-10-31
- Volume
- 59
- Issue
- 2
- Pages
- 596-612
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2953983428
- Cited by
- 482
- References
- 79
- FWCI
- 18.41
- Type
- journal article
- Language
- en
- Open access
- hybrid
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
