The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Edge Capping of 2D‐MXene Sheets with Polyanionic Salts To Mitigate Oxidation in Aqueous Colloidal Suspensions
Abstract
MXenes have shown promise in myriad applications, such as energy storage, catalysis, EMI shielding, among many others. However, MXene oxidation in aqueous colloidal suspensions when stored in water at ambient conditions remains a challenge. It is now shown that by simply capping the edges of individual MXene flakes, Ti 3 C 2 T z and V 2 CT z, by polyanions such as polyphosphates, polysilicates or polyborates, it is possible to quite significantly reduce their propensity for oxidation even when held in aerated water for weeks. This breakthrough resulted from the realization that the edges of MXene sheets are positively charged. It is thus an example of selectively functionalizing the edges differently from the MXene sheet surfaces.
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Cites
Two-dimensional atomic crystals
Novoselov, K. S., Jiang, D., Schedin, F., Booth, T. J., Khotkevich, V. V., Morozov, S. V., & Geim, A. K. (2005) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0502848102 · Cited by 11,788
Jiang, H., Wang, Z., Yang, Q., Tan, L., Dong, L., & Dong, M. (2019) · Nano-Micro Letters · doi:10.1007/s40820-019-0261-5 · Cited by 216
Cited by
Ten Years of Progress in the Synthesis and Development of MXenes
Naguib, M., Barsoum, M. W., & Gogotsi, Y. (2021) · Advanced Materials · doi:10.1002/adma.202103393 · Cited by 1,257
Self-citationA Review on MXene Synthesis, Stability, and Photocatalytic Applications
Murali, G., Reddy Modigunta, J. K., Park, Y. H., Lee, J.-H., Rawal, J., Lee, S.-Y., In, I., & Park, S.-J. (2022) · ACS Nano · doi:10.1021/acsnano.2c04750 · Cited by 668
Recent Advances in Oxidation Stable Chemistry of 2D MXenes
Cao, F., Zhang, Y., Wang, H., Khan, K., Tareen, A. K., Qian, W., Zhang, H., & Ågren, H. (2022) · Advanced Materials · doi:10.1002/adma.202107554 · Cited by 648
Flexible MXene‐Based Composites for Wearable Devices
Ma, C., Ma, M., Si, C., Ji, X., & Wan, P. (2021) · Advanced Functional Materials · doi:10.1002/adfm.202009524 · Cited by 544
Ambient‐Stable Two‐Dimensional Titanium Carbide (MXene) Enabled by Iodine Etching
Shi, H., Zhang, P., Liu, Z., Park, S., Lohe, M. R., Wu, Y., Shaygan Nia, A., Yang, S., & Feng, X. (2021) · Angewandte Chemie International Edition · doi:10.1002/anie.202015627 · Cited by 459
Metadata
- Authors
- Natu, V., Hart, J. L., Sokol, M., Chiang, H., Taheri, M. L., & Barsoum, M. W.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-08-22
- Volume
- 58
- Issue
- 36
- Pages
- 12655-12660
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2961863584
- Cited by
- 379
- References
- 2
- FWCI
- 13.20
- Type
- journal article
- Language
- en
- Open access
- closed
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- Natu, V., Hart, J. L., Sokol, M., Chiang, H., Taheri, M. L., & Barsoum, M. W. (2019). Edge Capping of 2D‐MXene Sheets with Polyanionic Salts To Mitigate Oxidation in Aqueous Colloidal Suspensions. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201906138
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