The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Visible‐Light‐Driven CO2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine
Open accessAbstract
The integration of molecular catalysts with low‐cost, solid light absorbers presents a promising strategy to construct catalysts for the generation of solar fuels. Here, we report a photocatalyst for CO 2 reduction that consists of a polymeric cobalt phthalocyanine catalyst (CoPPc) coupled with mesoporous carbon nitride (mpg‐CNx) as the photosensitizer. This precious‐metal‐free hybrid catalyst selectively converts CO 2 to CO in organic solvents under UV/Vis light (AM 1.5G, 100 mW cm−2, λ>300 nm) with a cobalt‐based turnover number of 90 for CO after 60 h. Notably, the photocatalyst retains 60 % CO evolution activity under visible light irradiation (λ>400 nm) and displays moderate water tolerance. The in situ polymerization of the phthalocyanine allows control of catalyst loading and is key for achieving photocatalytic CO 2 conversion.
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Cites
Ong, W.-J., Tan, L.-L., Ng, Y. H., Yong, S.-T., & Chai, S.-P. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00075 · Cited by 7,147
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Recent Advances in Heterogeneous Photocatalytic CO 2 Conversion to Solar Fuels
Li, K., Peng, B., & Peng, T. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b02089 · Cited by 1,355
Cited by
Fang, S., Rahaman, M., Bharti, J., Reisner, E., Robert, M., Ozin, G. A., & Hu, Y. H. (2023) · Nature Reviews Methods Primers · doi:10.1038/s43586-023-00243-w · Cited by 834
Self-citationAtomic‐Level Reactive Sites for Semiconductor‐Based Photocatalytic CO2 Reduction
Zhang, Y., Xia, B., Ran, J., Davey, K., & Qiao, S. Z. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903879 · Cited by 423
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Metadata
- Authors
- Roy, S., & Reisner, E.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-07-30
- Volume
- 58
- Issue
- 35
- Pages
- 12180-12184
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4248382734
- Cited by
- 203
- References
- 3
- FWCI
- 5.10
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Roy, S., & Reisner, E. (2019). Visible‐Light‐Driven CO2 Reduction by Mesoporous Carbon Nitride Modified with Polymeric Cobalt Phthalocyanine. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201907082
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