The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Stable Heterometallic Cluster‐Based Organic Framework Catalysts for Artificial Photosynthesis
Abstract
A series of stable heterometallic Fe 2 M cluster‐based MOFs (NNU‐31‐M, M=Co, Ni, Zn) photocatalysts are presented. They can achieve the overall conversion of CO 2 and H 2 O into HCOOH and O 2 without the assistance of additional sacrificial agent and photosensitizer. The heterometallic cluster units and photosensitive ligands excited by visible light generate separated electrons and holes. Then, low‐valent metal M accepts electrons to reduce CO 2, and high‐valent Fe uses holes to oxidize H 2 O. This is the first MOF photocatalyst system to finish artificial photosynthetic full reaction. It is noted that NNU‐31‐Zn exhibits the highest HCOOH yield of 26.3 μmol g−1 h−1 (selectivity of ca. 100 %). Furthermore, the DFT calculations based on crystal structures demonstrate the photocatalytic reaction mechanism. This work proposes a new strategy for how to design crystalline photocatalyst to realize artificial photosynthetic overall reaction.
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Cites
Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway
Liu, J., Liu, Y., Liu, N., Han, Y., Zhang, X., Huang, H., Lifshitz, Y., Lee, S.-T., Zhong, J., & Kang, Z. (2015) · Science · doi:10.1126/science.aaa3145 · Cited by 4,468
Self-citationFuture CO 2 Emissions and Climate Change from Existing Energy Infrastructure
Davis, S. J., Caldeira, K., & Matthews, H. D. (2010) · Science · doi:10.1126/science.1188566 · Cited by 1,399
Xu, H.-Q., Hu, J., Wang, D., Li, Z., Zhang, Q., Luo, Y., Yu, S.-H., & Jiang, H.-L. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08773 · Cited by 1,166
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Updates on the Roadmap for Photocatalysis
Melchionna, M., & Fornasiero, P. (2020) · ACS Catalysis · doi:10.1021/acscatal.0c01204 · Cited by 470
Metadata
- Authors
- Dong, L., Zhang, L., Liu, J., Huang, Q., Lu, M., Ji, W., & Lan, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-01-09
- Volume
- 59
- Issue
- 7
- Pages
- 2659-2663
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4239370604
- Cited by
- 257
- References
- 3
- FWCI
- 5.67
- Type
- journal article
- Language
- en
- Open access
- closed
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- Dong, L., Zhang, L., Liu, J., Huang, Q., Lu, M., Ji, W., & Lan, Y. (2020). Stable Heterometallic Cluster‐Based Organic Framework Catalysts for Artificial Photosynthesis. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201913284
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