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Inside Cover: Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Umpolung 1,4‐Addition of Aryl Iodides to Enals (Angew. Chem. Int. Ed. 1/2020)
Abstract
N-Heterocyclic carbene (NHC) organocatalysis in the presence of transition metals is a challenge because of the high affinity of NHCs for metals. In their Communication on page 161, J. Mao, P. J. Walsh, and co-workers present a system for the conjugate addition of aryl iodides to enals through cooperative catalysis between an NHC and a Pd catalyst. The catalytic cycles intersect at Pd, where the two newly formed Pd−C bonds undergo reductive elimination to give a C−C bond.
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Metadata
- Authors
- Yang, W., Ling, B., Hu, B., Yin, H., Mao, J., & Walsh, P. J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2019-11-27
- Volume
- 59
- Issue
- 1
- Pages
- 2-2
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W2994728060
- Cited by
- 991
- References
- 0
- FWCI
- 81.57
- Type
- journal article
- Language
- en
- Open access
- closed
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- Yang, W., Ling, B., Hu, B., Yin, H., Mao, J., & Walsh, P. J. (2020). Inside Cover: Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Umpolung 1,4‐Addition of Aryl Iodides to Enals (Angew. Chem. Int. Ed. 1/2020). Angewandte Chemie International Edition. https://doi.org/10.1002/anie.201914768
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