Cited by 18Catalytic Cross-Coupling ReactionsCoordination Chemistry and OrganometallicsOrganometallic Complex Synthesis and Catalysis

The Role of Organoferrates in Iron‐Catalyzed Cross‐Couplings

Sandl, Sebastian, Jacobi von Wangelin, Axel·2020·Angewandte Chemie International Edition

Abstract

Recent groundbreaking studies on organoferrates have demonstrated that coordinatively unsaturated three-coordinate-σ-alkylferrates are active catalysts in Fe-catalyzed cross-couplings with Grignard reagents and that pronounced solvent and counterion effects dictate metalate speciation and catalyst activity. Thanks to modern spectroscopic methods, sensitive catalyst intermediates could be analyzed.

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Crossref · 10.1002/anie.201914844

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53 of 53 references verified0 citation errors · 0 not checkable

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Authors
Sandl, S., & Jacobi von Wangelin, A.
Affiliations
  • Universität Hamburg (DE)
  • Department of Chemistry University of Hamburg Martin Luther King Platz 6 20146 Hamburg Germany
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-01-30
Volume
59
Issue
14
Pages
5434-5437
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W3004116745
Cited by
18
References
53
Citations by year
2026: 1 · 2025: 3 · 2024: 3 · 2023: 2 · 2022: 1 · 2021: 6 · 2020: 2
FWCI
0.21
Type
journal article
Language
en
Open access
closed
Locations
  • Angewandte Chemie International Edition (publishedVersion)
  • PubMed (publishedVersion)
Funders
H2020 European Research Council (CoG 683150)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Catalytic Cross-Coupling Reactions
  • Physical Sciences › Chemistry › Organic Chemistry › Coordination Chemistry and Organometallics
  • Physical Sciences › Chemistry › Organic Chemistry › Organometallic Complex Synthesis and Catalysis
Keywords
iron catalysis, cross-coupling reactions, Grignard reagents, solvent effects, counterion effects, catalytic intermediates, coordination chemistry

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