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Cited by 200

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In situ Synthesis of Biomimetic Silica Nanofibrous Aerogels with Temperature‐Invariant Superelasticity over One Million Compressions

Wang, Fei, Dou, Lvye, Dai, Jianwu, Li, Yuyao, Huang, Liqian, Si, Yang, Yu, Jianyong, Ding, Bin·2020·Angewandte Chemie International Edition

Abstract

Resilient and compressible three‐dimensional nanomaterials comprising polymers, carbon, and metals have been prepared in diverse forms. However, the creation of thermostable elastic ceramic aerogels remains an enormous challenge. We demonstrate an in situ synthesis strategy to develop biomimetic silica nanofibrous (SNF) aerogels with superelasticity by integrating flexible electrospun silica nanofibers and rubber‐like Si−O−Si bonding networks. The stable bonding structure among nanofibers is in situ constructed along with a fibrous freeze‐shaping process. The resultant SNF aerogels exhibit integrated properties of ultralow density (>0.25 mg cm−3), temperature‐invariant superelasticity up to 1100 °C, and robust fatigue resistance over one million compressions. The ceramic nature also endows the aerogels with fire resistance and ultralow thermal conductivity. The successful synthesis of the SNF aerogels opens new pathways for the design of superelastic ceramic aerogels in a structurally adaptive and scalable form.

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Metadata

Authors
Wang, F., Dou, L., Dai, J., Li, Y., Huang, L., Si, Y., Yu, J., & Ding, B.
Venue
Angewandte Chemie International Edition
Publisher
Wiley
Published
2020-03-03
Volume
59
Issue
21
Pages
8285-8292
ISSN
  • 1433-7851 (ISSN-L)
  • 1521-3773
OpenAlex
W3005673014
Cited by
200
References
1
FWCI
9.21
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: In situ Synthesis of Biomimetic Silica Nanofibrous Aerogels with Temperature‐Invariant Superelasticity over One Million Compressions. https://app.cochat.ai/papers/10.1002/anie.202001679
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Wang, F., Dou, L., Dai, J., Li, Y., Huang, L., Si, Y., Yu, J., & Ding, B. (2020). In situ Synthesis of Biomimetic Silica Nanofibrous Aerogels with Temperature‐Invariant Superelasticity over One Million Compressions. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202001679

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