The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.
Distance Synergy of MoS2‐Confined Rhodium Atoms for Highly Efficient Hydrogen Evolution
Abstract
Perturbing the electronic structure of the MoS 2 basal plane by confining heteroatoms offers the opportunity to trigger in‐plane activity for the hydrogen evolution reaction (HER). The key challenge consists of inducing the optimum HER activity by controlling the type and distribution of confined atoms. A distance synergy of MoS 2‐confined single‐atom rhodium is presented, leading to an ultra‐high HER activity at the in‐plane S sites adjacent to the rhodium. By optimizing the distance between the confined Rh atoms, an ultra‐low overpotential of 67 mV is achieved at a current density of 10 mA cm−2 in acidic solution. Experiments and first‐principles calculations demonstrate a unique distance synergy between the confined rhodium atoms in tuning the reactivity of neighboring in‐plane S atoms, which presents a volcanic trend with the inter‐rhodium distance. This study provides a new strategy to tailor the activity of MoS 2 surface via modulating the distance between confined single atoms.
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“Few HER non-Pt electrocatalysts can work well in a wide pH range.[20]”
From Functionalized Ultrafine Rhodium Nanoparticles on Graphene Aerogels for the Hydrogen Evolution Reaction (2021) · cites this paper as [20]
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Noble metal-free hydrogen evolution catalysts for water splitting
Zou, X., & Zhang, Y. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00448e · Cited by 5,955
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions
Jiao, Y., Zheng, Y., Jaroniec, M., & Qiao, S. Z. (2015) · Chemical Society Reviews · doi:10.1039/c4cs00470a · Cited by 5,388
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Biomimetic Hydrogen Evolution: MoS 2 Nanoparticles as Catalyst for Hydrogen Evolution
Hinnemann, B., Moses, P. G., Bonde, J., Jørgensen, K. P., Nielsen, J. H., Horch, S., Chorkendorff, I., & Nørskov, J. K. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0504690 · Cited by 4,065
Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250
Wu, H. B., Xia, B. Y., Yu, L., Yu, X.-Y., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7512 · Cited by 1,434
Self-citationFaber, M. S., & Jin, S. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01760a · Cited by 1,317
Tuning the MoS 2 Edge-Site Activity for Hydrogen Evolution via Support Interactions
Tsai, C., Abild-Pedersen, F., & Nørskov, J. K. (2014) · Nano Letters · doi:10.1021/nl404444k · Cited by 760
Structural and Electronic Optimization of MoS 2 Edges for Hydrogen Evolution
Wang, H., Xiao, X., Liu, S., Chiang, C.-L., Kuai, X., Peng, C.-K., Lin, Y.-C., Meng, X., Zhao, J., Choi, J., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b09932 · Cited by 383
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Research works printed but not linked: 31
- 10.1002/anie.201407031 · DOI · Paper page
- 10.1002/ange.201407031 · DOI
- 10.1002/adma.201202920 · DOI · Paper page
- 10.1039/C5CS00434A · DOI · Paper page
- 10.1021/acs.nanolett.5b04331 · DOI
- 10.1021/cs500923c · DOI · Paper page
- 10.1002/adfm.201300318 · DOI · Paper page
- 10.1021/ar5002846 · DOI
- 10.1073/pnas.1316792110 · DOI
- 10.1002/anie.201602237 · DOI
- 10.1002/ange.201602237 · DOI
- 10.1038/ncomms14430 · DOI
- 10.1039/C5EE00751H · DOI
- 10.1016/j.nanoen.2019.05.036 · DOI
- 10.1038/nmat4564 · DOI
- 10.1021/acsenergylett.7b00111 · DOI
- 10.1016/j.nanoen.2019.04.049 · DOI
- 10.1021/jacs.7b08881 · DOI · Paper page
- 10.1021/acs.chemrev.8b00501 · DOI
- 10.1038/s41467-019-12997-7 · DOI
- 10.1021/jacs.6b05940 · DOI · Paper page
- 10.1021/jacs.6b03714 · DOI
- 10.1002/adma.201901996 · DOI
- 10.1007/s10562-019-02768-w · DOI
- 10.1002/adfm.201700359 · DOI · Paper page
- 10.1039/b916192a · DOI
- 10.1107/S0909049505012719 · DOI
- 10.1021/jacs.8b10246 · DOI
- 10.1039/b926109e · DOI
- 10.1149/1.2779692 · DOI
- 10.1016/S0013-4686(02)00329-8 · DOI
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Sorted by citations
Single-Atom Catalysts Based on the Metal–Oxide Interaction
Lang, R., Du, X., Huang, Y., Jiang, X., Zhang, Q., Guo, Y., Liu, K., Qiao, B., Wang, A., & Zhang, T. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00797 · Cited by 1,106
Sun, Y., Xue, Z., Liu, Q., Jia, Y., Li, Y., Liu, K., Lin, Y., Liu, M., Li, G., & Su, C. (2021) · Nature Communications · doi:10.1038/s41467-021-21595-5 · Cited by 700
Sun, H., Zhang, W., Li, J., Li, Z., Ao, X., Xue, K., Ostrikov, K., Tang, J., & Wang, C. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.119740 · Cited by 533
Recent progress on the long‐term stability of hydrogen evolution reaction electrocatalysts
Zhai, W., Ma, Y., Chen, D., Ho, J. C., Dai, Z., & Qu, Y. (2022) · InfoMat · doi:10.1002/inf2.12357 · Cited by 375
Metal-metal interactions in correlated single-atom catalysts
Shan, J., Ye, C., Jiang, Y., Jaroniec, M., Zheng, Y., & Qiao, S. (2022) · Science Advances · doi:10.1126/sciadv.abo0762 · Cited by 412
Metadata
- Authors
- Meng, X., Ma, C., Jiang, L., Si, R., Meng, X., Tu, Y., Yu, L., Bao, X., & Deng, D.
- Affiliations
- Dalian Institute of Chemical Physics (CN)
- Hunan University (CN)
- Chinese Academy of Sciences (CN)
- Corresponding author
- Yu, Liang
- Deng, Dehui
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2020-04-30
- Volume
- 59
- Issue
- 26
- Pages
- 10502-10507
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3013511951
- Cited by
- 198
- References
- 0
- Citations by year
- 2026: 25 · 2025: 31 · 2024: 28 · 2023: 31 · 2022: 44 · 2021: 32 · 2020: 7
- FWCI
- 5.63
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Angewandte Chemie International Edition (publishedVersion)
- PubMed (publishedVersion)
- Funders
- the National Key R&D Program of China (No. 2016YFA0204100 and 2016YFA0200200)
- the National Natural Science Foundation of China (No. 21890753 and 21988101, No. 21872140)
- the Key Research Program of Frontier Sciences of the Chinese Academy of Sciences (No. QYZDB-SSW-JSC020)
- the DNL Cooperation Fund, CAS (No. DNL180201)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › 2D Materials and Applications
- Life Sciences › Biochemistry, Genetics and Molecular Biology › Biochemistry › Metalloenzymes and iron-sulfur proteins
- Keywords
- MoS2, single-atom catalysts, rhodium, hydrogen evolution reaction, electronic structure modulation, volcano plot, acidic electrocatalysis, overpotential
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