Recent progress on the long‐term stability of hydrogen evolution reaction electrocatalysts
Open accessAbstract
Developing new methodologies to produce clean and renewable energy resources is pivotal for carbon‐neutral initiatives. Hydrogen (H 2 ) is considered as an ideal energy resource due to its nontoxic, pollution‐free, high utilization rate, and high calorific combustion value. Electrolysis of water driven by the electricity generated from renewable and clean energy sources (e.g., solar energy, wind energy) to produce hydrogen attracts great efforts for hydrogen production with high purity. Recently, the breakthrough of the catalyst activity limit for the hydrogen evolution reaction (HER) catalysts has received extensive attention. Comparatively, fewer reviews have focused on the long‐term stability of HER catalysts, which is indeed decisive for large‐scale electrolytic industrialization. Therefore, a systematic summary concentrated on the durability of HER electrocatalysts would provide a fundamental understanding of the electrocatalytic performance for practical applications and offer new opportunities for the rational design of the highly performed HER electrocatalysts. This review summarizes the research progress toward the HER stability of precious metals, transition metals, and metal‐free electrocatalysts in the past few years. It discusses the challenges in the stability of HER electrocatalysts and the future perspectives. We anticipate that it would provide a valuable basis for designing robust HER electrocatalysts. image
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Electrocatalysts with low Pt loading often suffer from low stability and short durability due to detachment and dissolution of Pt-NPs.
“However, such electrocatalysts often suffer from low stability and short durability due to the detachment and dissolution of Pt-NPs.[24–26]”
From Synthesis of Pt Carbon Aerogel Electrocatalysts with Multiscale Porosity Derived from Cellulose and Chitosan Biopolymer Aerogels via Supercritical Deposition for Hydrogen Evolution Reaction (2025) · cites this paper as [24]
Section 4.1.1 (Platinum-based; page unavailable) says Pt-based HER catalysts face a stability challenge because Pt tends to leach or detach from its support. It does not specifically say that low Pt loading makes catalysts prone to this problem; it also describes low-loading catalysts with substantial durability. (LLM, conf=0.83)
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- Authors
- Zhai, W., Ma, Y., Chen, D., Ho, J. C., Dai, Z., & Qu, Y.
- Affiliations
- Northwestern Polytechnical University (CN)
- City University of Hong Kong (HK)
- Xi'an Jiaotong University (CN)
- Corresponding author
- Ho, Johnny C.
- Dai, Zhengfei
- Qu, Yongquan
- Venue
- InfoMat
- Publisher
- Wiley
- Published
- 2022-08-23
- Volume
- 4
- Issue
- 9
- ISSN
- 2567-3165 (ISSN-L)
- OpenAlex
- W4292707979
- Cited by
- 375
- References
- 246
- Citations by year
- 2026: 102 · 2025: 128 · 2024: 88 · 2023: 52 · 2022: 5
- FWCI
- 12.29
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- InfoMat (publishedVersion, cc-by)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- CityU Scholars (submittedVersion, cc-by)
- Funders
- National Natural Science Foundation of China (21872109, ECF 2020‐13)
- Fundamental Research Funds for the Central Universities (D5000210829, D5000210601)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Keywords
- hydrogen evolution reaction, electrocatalyst stability, catalyst stability, water electrolysis, hydrogen production, noble metal catalysts, transition metal catalysts, metal-free catalysts, catalyst deactivation
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
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