The DOI matches its Crossref record; 27 of the 27 references it cites were found in a registry or an index.
Built‐in Electric Field Triggered Interfacial Accumulation Effect for Efficient Nitrate Removal at Ultra‐Low Concentration and Electroreduction to Ammonia
Abstract
A built‐in electric field in electrocatalyst can significantly accumulate higher concentration of NO 3− ions near electrocatalyst surface region, thus facilitating mass transfer for efficient nitrate removal at ultra‐low concentration and electroreduction reaction (NO 3 RR). A model electrocatalyst is created by stacking CuCl (111) and rutile TiO 2 (110) layers together, in which a built‐in electric field induced from the electron transfer from TiO 2 to CuCl (CuCl_BEF) is successfully formed . This built‐in electric field effectively triggers interfacial accumulation of NO 3− ions around the electrocatalyst. The electric field also raises the energy of key reaction intermediate *NO to lower the energy barrier of the rate determining step. A NH 3 product selectivity of 98.6 %, a low NO 2− production of <0.6 %, and mass‐specific ammonia production rate of 64.4 h−1 is achieved, which are all the best among studies reported at 100 mg L−1 of nitrate concentration to date.
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Cites
Two‐Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
Naguib, M., Kurtoglu, M., Presser, V., Lu, J., Niu, J., Heon, M., Hultman, L., Gogotsi, Y., & Barsoum, M. W. (2011) · Advanced Materials · doi:10.1002/adma.201102306 · Cited by 11,855
Self-citationBeyond fossil fuel–driven nitrogen transformations
Chen, J. G., Crooks, R. M., Seefeldt, L. C., Bren, K. L., Bullock, R. M., Darensbourg, M. Y., Holland, P. L., Hoffman, B., Janik, M. J., Jones, A. K., et al. (2018) · Science · doi:10.1126/science.aar6611 · Cited by 2,441
Challenges and prospects in the catalysis of electroreduction of nitrogen to ammonia
Suryanto, B. H. R., Du, H.-L., Wang, D., Chen, J., Simonov, A. N., & MacFarlane, D. R. (2019) · Nature Catalysis · doi:10.1038/s41929-019-0252-4 · Cited by 1,654
Wang, Y., Zhou, W., Jia, R., Yu, Y., & Zhang, B. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201915992 · Cited by 1,641
Chen, G.-F., Yuan, Y., Jiang, H., Ren, S.-Y., Ding, L.-X., Ma, L., Wu, T., Lu, J., & Wang, H. (2020) · Nature Energy · doi:10.1038/s41560-020-0654-1 · Cited by 1,590
Self-citationEnhanced Nitrate-to-Ammonia Activity on Copper–Nickel Alloys via Tuning of Intermediate Adsorption
Wang, Y., Xu, A., Wang, Z., Huang, L., Li, J., Li, F., Wicks, J., Luo, M., Nam, D.-H., Tan, C.-S., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.9b13347 · Cited by 1,380
Self-citationElectrocatalytic reduction of nitrate: Fundamentals to full-scale water treatment applications
Garcia-Segura, S., Lanzarini-Lopes, M., Hristovski, K., & Westerhoff, P. (2018) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2018.05.041 · Cited by 1,196
Efficient Ammonia Electrosynthesis from Nitrate on Strained Ruthenium Nanoclusters
Li, J., Zhan, G., Yang, J., Quan, F., Mao, C., Liu, Y., Wang, B., Lei, F., Li, L., Chan, A. W. M., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00418 · Cited by 1,108
Self-citationReview of electrochemical ammonia production technologies and materials
Giddey, S., Badwal, S. P. S., & Kulkarni, A. (2013) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2013.09.054 · Cited by 886
Boosting Selective Nitrate Electroreduction to Ammonium by Constructing Oxygen Vacancies in TiO2
Jia, R., Wang, Y., Wang, C., Ling, Y., Yu, Y., & Zhang, B. (2020) · ACS Catalysis · doi:10.1021/acscatal.9b05260 · Cited by 863
Cited by
Electrocatalytic reduction of nitrate – a step towards a sustainable nitrogen cycle
Xu, H., Ma, Y., Chen, J., Zhang, W.-X., & Yang, J. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00857a · Cited by 1,160
Alloying of Cu with Ru Enabling the Relay Catalysis for Reduction of Nitrate to Ammonia
Gao, W., Xie, K., Xie, J., Wang, X., Zhang, H., Chen, S., Wang, H., Li, Z., & Li, C. (2023) · Advanced Materials · doi:10.1002/adma.202202952 · Cited by 532
Self-citationZhou, J., Wen, M., Huang, R., Wu, Q., Luo, Y., Tian, Y., Wei, G., & Fu, Y. (2023) · Energy & Environmental Science · doi:10.1039/d2ee04095f · Cited by 398
Zhang, Y., Ma, D., Lei, Y., Zhu, T., Hu, J., Tang, Y., Chen, Z., Huang, J., Lai, Y., & Lin, Z. (2023) · Nano Energy · doi:10.1016/j.nanoen.2023.108896 · Cited by 54
Metadata
- Authors
- Sun, W., Ji, H., Li, L., Zhang, H., Wang, Z., He, J., & Lu, J.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2021-09-14
- Volume
- 60
- Issue
- 42
- Pages
- 22933-22939
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W3194005125
- Cited by
- 367
- References
- 27
- FWCI
- 10.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- Sun, W., Ji, H., Li, L., Zhang, H., Wang, Z., He, J., & Lu, J. (2021). Built‐in Electric Field Triggered Interfacial Accumulation Effect for Efficient Nitrate Removal at Ultra‐Low Concentration and Electroreduction to Ammonia. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202109785
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