The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.
Extraordinary p–d Hybridization Interaction in Heterostructural Pd‐PdSe Nanosheets Boosts C−C Bond Cleavage of Ethylene Glycol Electrooxidation
Abstract
Advanced electrocatalysts for complete oxidation of ethylene glycol (EG) in direct EG fuel cells are strongly desired owing to the higher energy efficiency. Herein, Pd‐PdSe heterostructural nanosheets (Pd‐PdSe HNSs) have been successfully fabricated via a one‐step approach. These Pd‐PdSe HNSs feature unique electronic and geometrical structures, in which unconventional p–d hybridization interactions and tensile strain effect co‐exist. Compared with commercial Pd/C and Pd NSs catalysts, Pd‐PdSe HNSs display 5.5 (6.6) and 2.5 (2.6) fold enhancement of specific (mass) activity for the EG oxidation reaction (EGOR). Especially, the optimum C1 pathway selectivity of Pd‐PdSe HNSs reaches 44.3 %, illustrating the superior C−C bond cleavage ability. Electrochemical in situ FTIR spectroscopy and theoretical calculations demonstrate that the extraordinary p–d hybridization interaction and tensile strain effect could effectively reduce the activation energy of C−C bond breaking and accelerate CO* oxidation, boosting the complete oxidation of EG and improving the catalytic performance.
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Xiao, F., Wang, Y., Wu, Z., Chen, G., Yang, F., Zhu, S., Siddharth, K., Kong, Z., Lu, A., Li, J., et al. (2021) · Advanced Materials · doi:10.1002/adma.202006292 · Cited by 614
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Wu, D., Kusada, K., Yamamoto, T., Toriyama, T., Matsumura, S., Kawaguchi, S., Kubota, Y., & Kitagawa, H. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c04807 · Cited by 492
Gao, L., Li, X., Yao, Z., Bai, H., Lu, Y., Ma, C., Lu, S., Peng, Z., Yang, J., Pan, A., et al. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07238 · Cited by 376
Hong, W., Shang, C., Wang, J., & Wang, E. (2015) · Energy & Environmental Science · doi:10.1039/c5ee01988e · Cited by 324
Huang, W., Ma, X., Wang, H., Feng, R., Zhou, J., Duchesne, P. N., Zhang, P., Chen, F., Han, N., Zhao, F., et al. (2017) · Advanced Materials · doi:10.1002/adma.201703057 · Cited by 320
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Gao, F., Zhang, Y., Ren, F., Shiraishi, Y., & Du, Y. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202000255 · Cited by 244
Ai, X., Zou, X., Chen, H., Su, Y., Feng, X., Li, Q., Liu, Y., Zhang, Y., & Zou, X. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.201915663 · Cited by 232
Defect engineering for electrochemical nitrogen reduction reaction to ammonia
Yang, C., Zhu, Y., Liu, J., Qin, Y., Wang, H., Liu, H., Chen, Y., Zhang, Z., & Hu, W. (2020) · Nano Energy · doi:10.1016/j.nanoen.2020.105126 · Cited by 217
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Liang, Z., Song, L., Deng, S., Zhu, Y., Stavitski, E., Adzic, R. R., Chen, J., & Wang, J. X. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b03474 · Cited by 209
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Xie, M., Zhang, B., Jin, Z., Li, P., & Yu, G. (2022) · ACS Nano · doi:10.1021/acsnano.2c05190 · Cited by 167
Metadata
- Authors
- Qin, Y., Zhang, W., Wang, F., Li, J., Ye, J., Sheng, X., Li, C., Liang, X., Liu, P., Wang, X., Zheng, X., Ren, Y., Xu, C., & Zhang, Z.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-02-07
- Volume
- 61
- Issue
- 16
- Pages
- e202200899-e202200899
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4210699206
- Cited by
- 257
- References
- 34
- FWCI
- 8.85
- Type
- journal article
- Language
- en
- Open access
- closed
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