The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Constructing Organic Electroluminescent Material with Very High Color Purity and Efficiency Based on Polycyclization of the Multiple Resonance Parent Core
Abstract
Multiple resonance thermally activated delayed fluorescence (MR‐TADF) compounds have set off an upsurge of research because of their tremendous application prospects in the field of wide color gamut display. Herein, we propose a novel MR‐TADF molecular construction paradigm based on polycyclization of the multiple resonance parent core, and construct a representative multiple resonance polycyclic aromatic hydrocarbon (MR‐PAH) based on the para‐alignment of boron and nitrogen atoms into a six‐membered ring (p‐BNR). Through the retrosynthesis analysis, a concise synthesis strategy with wide applicability has been proposed, encompassing programmed sequential boron esterification, Suzuki coupling and Scholl oxidative coupling. The target model molecule BN‐TP shows green fluorescence with an emission peak at 523 nm and a narrow full‐width at half‐maximum (FWHM) of 34 nm. The organic light‐emitting diode (OLED) employing BN‐TP as an emitter exhibits ultrapure green emission with Commission Internationale de L'Eclairage (CIE) coordinates of (0.26, 0.70), and achieves a maximum external quantum efficiency (EQE) of 35.1 %.
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Cites
Recent advances in organic thermally activated delayed fluorescence materials
Yang, Z., Mao, Z., Xie, Z., Zhang, Y., Liu, S., Zhao, J., Xu, J., Chi, Z., & Aldred, M. P. (2017) · Chemical Society Reviews · doi:10.1039/c6cs00368k · Cited by 2,395
Samanta, P. K., Kim, D., Coropceanu, V., & Brédas, J.-L. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b12124 · Cited by 1,025
Cited by
Mamada, M., Hayakawa, M., Ochi, J., & Hatakeyama, T. (2024) · Chemical Society Reviews · doi:10.1039/d3cs00837a · Cited by 482
Wu, X., Ni, S., Wang, C.-H., Zhu, W., & Chou, P.-T. (2025) · Chemical Reviews · doi:10.1021/acs.chemrev.5c00021 · Cited by 325
Metadata
- Authors
- Xu, Y., Wang, Q., Wei, J., Peng, X., Xue, J., Wang, Z., Su, S., & Wang, Y.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-06-07
- Volume
- 61
- Issue
- 30
- Pages
- e202204652-e202204652
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4229004491
- Cited by
- 163
- References
- 2
- FWCI
- 9.50
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Constructing Organic Electroluminescent Material with Very High Color Purity and Efficiency Based on Polycyclization of the Multiple Resonance Parent Core. https://app.cochat.ai/papers/10.1002/anie.202204652
- The paper
- Xu, Y., Wang, Q., Wei, J., Peng, X., Xue, J., Wang, Z., Su, S., & Wang, Y. (2022). Constructing Organic Electroluminescent Material with Very High Color Purity and Efficiency Based on Polycyclization of the Multiple Resonance Parent Core. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202204652
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