The DOI matches its Crossref record; 47 of the 47 references it cites were found in a registry or an index.
Electrocatalytic Hydrogenation of 5‐Hydroxymethylfurfural Promoted by a Ru1Cu Single‐Atom Alloy Catalyst
Abstract
Electrochemical reduction of biomass‐derived 5‐hydroxymethylfurfural (HMF) represents an elegant route toward sustainable value‐added chemicals production that circumvents the use of fossil fuel and hydrogen. However, the reaction efficiency is hampered by the high voltage and low activity of electrodes (Cu, Bi, Pb). Herein, we report a Ru 1 Cu single‐atom alloy (SAA) catalyst with isolated Ru atoms on Cu nanowires that exhibits an electrochemical reduction of HMF to 2,5‐dihydroxymethylfuran (DHMF) with promoted productivity (0.47 vs. 0.08 mmol cm−2 h−1) and faradic efficiency (FE) (85.6 vs. 71.3 %) at −0.3 V (vs. RHE) compared with Cu counterpart. More importantly, the FE (87.5 %) is largely retained at high HMF concentration (100 mM). Kinetic studies by using combined electrochemical techniques suggest disparate mechanisms over Ru 1 Cu and Cu, revealing that single‐atom Ru promotes the dissociation of water to produce H* species that effectively react with HMF via an electrocatalytic hydrogenation (ECH) mechanism.
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Cites
Liquid‐Phase Catalytic Processing of Biomass‐Derived Oxygenated Hydrocarbons to Fuels and Chemicals
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Self-citationChen, F.-Y., Wu, Z.-Y., Gupta, S., Rivera, D. J., Lambeets, S. V., Pecaut, S., Kim, J. Y. T., Zhu, P., Finfrock, Y. Z., Meira, D. M., et al. (2022) · Nature Nanotechnology · doi:10.1038/s41565-022-01121-4 · Cited by 1,171
Metallic nanostructures with low dimensionality for electrochemical water splitting
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Light-driven methane dry reforming with single atomic site antenna-reactor plasmonic photocatalysts
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Copper-catalysed exclusive CO2 to pure formic acid conversion via single-atom alloying
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Catalytically highly active top gold atom on palladium nanocluster
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Cited by
Electrochemical hydrogenation and oxidation of organic species involving water
Liu, C., Chen, F., Zhao, B.-H., Wu, Y., & Zhang, B. (2024) · Nature Reviews Chemistry · doi:10.1038/s41570-024-00589-z · Cited by 269
Lin, G., Dong, A., Li, Z., Li, W., Cao, X., Zhao, Y., Wang, L., & Sun, L. (2025) · Advanced Materials · doi:10.1002/adma.202507525 · Cited by 93
Chen, H., Ding, R., Zeng, Z., Jia, X., Zhang, Y., Liu, B., Zeng, F., Wang, Y., & Zhao, H. (2025) · Advanced Functional Materials · doi:10.1002/adfm.202505802 · Cited by 18
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Metadata
- Authors
- Ji, K., Xu, M., Xu, S., Wang, Y., Ge, R., Hu, X., Sun, X., & Duan, H.
- Venue
- Angewandte Chemie International Edition
- Publisher
- Wiley
- Published
- 2022-08-04
- Volume
- 61
- Issue
- 37
- Pages
- e202209849-e202209849
- ISSN
- 1433-7851 (ISSN-L)
- 1521-3773
- OpenAlex
- W4287218642
- Cited by
- 334
- References
- 47
- FWCI
- 18.01
- Type
- journal article
- Language
- en
- Open access
- closed
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- Ji, K., Xu, M., Xu, S., Wang, Y., Ge, R., Hu, X., Sun, X., & Duan, H. (2022). Electrocatalytic Hydrogenation of 5‐Hydroxymethylfurfural Promoted by a Ru1Cu Single‐Atom Alloy Catalyst. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202209849
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