The DOI matches its Crossref record; 11 of the 11 references it cites were found in a registry or an index.
Plasticization of glassy polymers by CO2
Abstract
A technique is described which uses differential scanning calorimetry to estimate the glass transition of polymers containing a dissolved gas. The technique is simple and appears to give reliable results. The effects of CO 2 sorption at pressures up to 25 atm were examined in detail for poly(methyl methacrylate) and its blends with poly(vinylidene fluoride). Less extensive results for polystyrene, polycarbonate, poly(vinyl chloride), and poly(ethylene terephthalate) are also given. Reductions in Tg of up to 50°C are observed. A theoretical relation by Chow predicts results in reasonable agreement with the experimental data. These findings are relevant to various applications such as membrane separation processes for gases.
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Citations
Cites
Hodge, I. M., & Berens, A. R. (1982) · Macromolecules · doi:10.1021/ma00231a016 · Cited by 427
Molecular Interpretation of the Glass Transition Temperature of Polymer-Diluent Systems
Chow, T. S. (1980) · Macromolecules · doi:10.1021/ma60074a029 · Cited by 390
CO2 sorption in poly(ethylene terephthalate) above and below the glass transition
Koros, W. J., & Paul, D. R. (1978) · Journal of Polymer Science: Polymer Physics Edition · doi:10.1002/pol.1978.180161105 · Cited by 310
Self-citationThermal behavior of annealed organic glasses
Petrie, S. E. B. (1972) · Journal of Polymer Science Part A-2 Polymer Physics · doi:10.1002/pol.1972.160100706 · Cited by 309
Wang, W. V., Kramer, E. J., & Sachse, W. H. (1982) · Journal of Polymer Science: Polymer Physics Edition · doi:10.1002/pol.1982.180200804 · Cited by 250
Gas sorption and transport in polysulfone
Erb, A. J., & Paul, D. R. (1981) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)82135-3 · Cited by 181
Self-citationEffect of CO2 exposure history on sorption and transport in polycarbonate
Wonders, A. G., & Paul, D. R. (1979) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)80438-x · Cited by 176
Self-citationHodge, I. M., & Huvard, G. S. (1983) · Macromolecules · doi:10.1021/ma00237a006 · Cited by 160
Temperature dependence of some thermodynamic functions for amorphous and semi-crystalline polymers
Mathot, V. (1984) · Polymer · doi:10.1016/0032-3861(84)90025-9 · Cited by 118
Welch, G. J., & Miller, R. L. (1976) · Journal of Polymer Science Polymer Physics Edition · doi:10.1002/pol.1976.180140913 · Cited by 81
Cited by
Saha, D., Grappe, H. A., Chakraborty, A., & Orkoulas, G. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00745 · Cited by 316
Metadata
- Authors
- Chiou, J. S., Barlow, J. W., & Paul, D. R.
- Venue
- Journal of Applied Polymer Science
- Publisher
- Wiley
- Published
- 1985-06
- Volume
- 30
- Issue
- 6
- Pages
- 2633-2642
- ISSN
- 0021-8995 (ISSN-L)
- 1097-4628
- OpenAlex
- W2051626019
- Cited by
- 417
- References
- 11
- FWCI
- 24.93
- Type
- journal article
- Language
- en
- Open access
- closed
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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