The DOI matches its Crossref record.
Pulsradiolytische Beobachtungen über die Reduktion des NO3−‐Ions und über Bildung und Zerfall der persalpetrigen Säure in wäßriger Lösung
Open accessAbstract
Das Nitration reagiert mit dem hydratisierten Elektron zu NO 32‐. Dieses Teilchen absorbiert maximal bei 2500 Å mit = 3,1 ± 10 3 M−1 cm−1. Seine Leitfähigkeit beträgt 137 Ω−1 cm 2 mol−1. In alkalischer Lösung verschwindet es mit δ1/2 = 12,5 μs nach: NO 32‐ + H 2 O ± NO 2 + 2 OH−. In saurer Lösung nimmt es Protonen auf bis zur Erreichung der Gleichgewichte: Das OH‐Radikal reagiert mit NO 2 zu persalpetriger Säure, HO 2 NO, mit k = 1,3 · 10 9 M−1 s−1. Der pK‐Wert der persalpetrigen Säure wurde zu 5,3 bestimmt. HO 2 NO verschwindet nach erster Ordnung aus der Lösung, indem sich die undissoziierte Form spontan zu Salpetersäure, HNO 3, umlagert, während das Anion der persalpetrigen Säure stabil ist. Die Geschwindigkeitskonstante der Isomerisierung
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The reduction potential of nitric oxide (NO) and its importance to NO biochemistry
Bartberger, M. D., Liu, W., Ford, E., Miranda, K. M., Switzer, C., Fukuto, J. M., Farmer, P. J., Wink, D. A., & Houk, K. N. (2002) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.162095599 · Cited by 383
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Metadata
- Authors
- Grätzel, M., Henglein, A., & Taniguchi, S.
- Venue
- Berichte der Bunsengesellschaft für physikalische Chemie
- Publisher
- Wiley
- Published
- 1970-03
- Volume
- 74
- Issue
- 3
- Pages
- 292-298
- ISSN
- 0005-9021 (ISSN-L)
- OpenAlex
- W135372508
- Cited by
- 190
- References
- 0
- FWCI
- 6.55
- Type
- journal article
- Language
- en
- Open access
- green
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