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Carbon Nanofiber Supported Transition‐Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol

Open access
Jongerius, Anna L., Gosselink, Robert W., Dijkstra, Jelmer, Bitter, Johannes H., Bruijnincx, Pieter C. A., Weckhuysen, Bert M.·2013·ChemCatChem

Abstract

Hydrodeoxygenation (HDO) studies over carbon nanofiber‐supported (CNF) W 2 C and Mo 2 C catalysts were performed on guaiacol, a prototypical substrate to evaluate the potential of a catalyst for valorization of depolymerized lignin streams. Typical reactions were executed at 55 bar hydrogen pressure over a temperature range of 300–375 °C for 4 h in dodecane, using a batch autoclave system. Combined selectivities of up to 87 and 69 % to phenol and methylated phenolics were obtained at 375 °C for W 2 C/CNF and Mo 2 C/CNF at >99 % conversion, respectively. The molybdenum carbide‐based catalyst showed a higher activity than W 2 C/CNF and yielded more completely deoxygenated aromatic products, such as benzene and toluene. Catalyst recycling experiments, performed with and without regeneration of the carbide phase, showed that the Mo 2 C/CNF catalyst was stable during reusability experiments. The most promising results were obtained with the Mo 2 C/CNF catalyst, as it showed a much higher activity and higher selectivity to phenolics compared to W 2 C/CNF.

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Metadata

Authors
Jongerius, A. L., Gosselink, R. W., Dijkstra, J., Bitter, J. H., Bruijnincx, P. C. A., & Weckhuysen, B. M.
Venue
ChemCatChem
Publisher
Wiley
Published
2013-07-16
Volume
5
Issue
10
Pages
2964-2972
ISSN
  • 1867-3880 (ISSN-L)
  • 1867-3899
OpenAlex
W2150472887
Cited by
211
References
4
FWCI
8.33
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Carbon Nanofiber Supported Transition‐Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol. https://app.cochat.ai/papers/10.1002/cctc.201300280
The paper
Jongerius, A. L., Gosselink, R. W., Dijkstra, J., Bitter, J. H., Bruijnincx, P. C. A., & Weckhuysen, B. M. (2013). Carbon Nanofiber Supported Transition‐Metal Carbide Catalysts for the Hydrodeoxygenation of Guaiacol. ChemCatChem. https://doi.org/10.1002/cctc.201300280

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