The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Influence of Alkali Metal Cations on the Hydrogen Evolution Reaction Activity of Pt, Ir, Au, and Ag Electrodes in Alkaline Electrolytes
Abstract
Fundamental understanding of the influence of so‐called spectator electrolyte species on the catalytic activity of electrodes is considered as a relatively novel direction in electrocatalysis. Numerous recent examples show that seemingly inert electrolyte components drastically influence the performance of catalytic centers. Even alkali metal cations in aqueous electrolytes at high pH values can change the reaction turnover frequency by orders of magnitude, depending on their nature, from Li+ to Cs+. Here, we use several electrodes, namely Pt(polycrystalline), Pt(111), Pt(221), Ir(111), Au(111), and Ag(polycrystalline), in different alkali metal cation‐containing electrolytes to reveal their role in the hydrogen evolution reaction (HER). The HER activity trends of various Pt electrodes, irrespective of their surface structure, correlate with the hydration energy of the corresponding alkali metal cations present in the electrolyte (Li+>Na+>K+>Rb+>Cs+). The trend remains the same for the Ir(111), however, it is reversed for Au(111) and Ag(pc) electrocatalysts.
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Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Skúlason, E., Tripkovic, V., Björketun, M. E., Gudmundsdóttir, S., Karlberg, G., Rossmeisl, J., Bligaard, T., Jónsson, H., & Nørskov, J. K. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1048887 · Cited by 1,271
Stamenkovic, V. R., Mun, B. S., Mayrhofer, K. J. J., Ross, P. N., & Markovic, N. M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0600476 · Cited by 974
Cited by
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Shah, A. H., Zhang, Z., Huang, Z., Wang, S., Zhong, G., Wan, C., Alexandrova, A. N., Huang, Y., & Duan, X. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00851-x · Cited by 373
Lao, M., Li, P., Jiang, Y., Pan, H., Dou, S. X., & Sun, W. (2022) · Nano Energy · doi:10.1016/j.nanoen.2022.107231 · Cited by 290
Zhang, X., Zhang, Q., Xu, B., Liu, X., Zhang, K., Fan, G., & Jiang, W. (2020) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b22645 · Cited by 125
Metadata
- Authors
- Xue, S., Garlyyev, B., Watzele, S., Liang, Y., Fichtner, J., Pohl, M. D., & Bandarenka, A. S.
- Venue
- ChemElectroChem
- Publisher
- Wiley
- Published
- 2018-06-19
- Volume
- 5
- Issue
- 17
- Pages
- 2326-2329
- ISSN
- 2196-0216 (ISSN-L)
- OpenAlex
- W2805871080
- Cited by
- 179
- References
- 3
- FWCI
- 3.05
- Type
- journal article
- Language
- en
- Open access
- closed
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- Xue, S., Garlyyev, B., Watzele, S., Liang, Y., Fichtner, J., Pohl, M. D., & Bandarenka, A. S. (2018). Influence of Alkali Metal Cations on the Hydrogen Evolution Reaction Activity of Pt, Ir, Au, and Ag Electrodes in Alkaline Electrolytes. ChemElectroChem. https://doi.org/10.1002/celc.201800690
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