Efficient Hydrogen Generation from the NaBH4 Hydrolysis by Cobalt-Based Catalysts: Positive Roles of Sulfur-Containing Salts
Abstract
Development of a simple and efficient strategy for improving the catalytic activity of cobalt-based catalysts toward hydrogen evolution from sodium borohydride (NaBH 4 ) is paramount but remains challenging. Here, we reported a facile and efficient approach to tune the catalytic performance for NaBH 4 hydrolysis with Co-based catalysts prepared by using cobalt sulfate as a precursor or a mixture of sulfur-containing sodium salts/cobalt salts as a raw material. With the use of cobalt sulfate as the precursor, the CoSO 4 -doped Co 3 O 4 sample was formed and it exhibited excellent activity with the generation of ∼500 mL of hydrogen gas from NaBH 4 hydrolysis under mild conditions. In terms of sulfur-free cobalt salts (e.g., cobalt chloride, cobalt nitrate, and cobalt acetate) as precursors, the obtained Co-based samples were found to be entirely ineffective for hydrogen production. Interestingly, during the cobalt-based catalyst preparation, the introduction of sodium sulfate or sodium sulfide can considerably accelerate hydrogen production. On the contrary, adding sulfur-bearing salts did not inspire any activity improvement only during the hydrogen generation reaction. Control experiments indicate that during catalyst preparation, the presence of Na 2 SO 4 and Na 2 S is beneficial for the in situ transformation of Co 3 O 4 into catalytically active Co-B alloys, accompanying a positive change in surface morphology during the NaBH 4 hydrolysis, thereby inducing an excellent hyd…
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
NaBH4 has a high hydrogen storage capacity of 10.57%.
“NaBH4 has always been the research subject, owing to its high hydrogen storage capacity of 10.57 %, stability in alkaline solutions, and non-toxic and recyclable hydrolyzed products [5,6].”
From Aerogel composite of ultrafine Co2B supported mesoporous CuCoO and chitosan for catalyzed NaBH4 hydrolysis in hydrogen generation (2025) · cites this paper as [6]
NaBH4 is stable in alkaline solutions.
“NaBH4 has always been the research subject, owing to its high hydrogen storage capacity of 10.57 %, stability in alkaline solutions, and non-toxic and recyclable hydrolyzed products [5,6].”
From Aerogel composite of ultrafine Co2B supported mesoporous CuCoO and chitosan for catalyzed NaBH4 hydrolysis in hydrogen generation (2025) · cites this paper as [6]
NaBH4 hydrolyzed products are non-toxic and recyclable.
“NaBH4 has always been the research subject, owing to its high hydrogen storage capacity of 10.57 %, stability in alkaline solutions, and non-toxic and recyclable hydrolyzed products [5,6].”
From Aerogel composite of ultrafine Co2B supported mesoporous CuCoO and chitosan for catalyzed NaBH4 hydrolysis in hydrogen generation (2025) · cites this paper as [6]
Cites
Handbook of X-Ray Photoelectron Spectroscopy
Moulder, J. F., Chastain, J., & King, R. C. (1995) · Medical Entomology and Zoology · Cited by 26,854 · see citing works
Schlesinger, H. I., Brown, H. C., Finholt, A. E., Gilbreath, J. R., Hoekstra, H. R., & Hyde, E. K. (1953) · Journal of the American Chemical Society · doi:10.1021/ja01097a057 · Cited by 1,115 · see citing works
Cleaning the air and improving health with hydrogen fuel-cell vehicles
Jacobson, M. Z., Colella, W. G., & Golden, D. M. (2005) · Science · doi:10.1126/science.1109157 · Cited by 1,023 · see citing works
Marbán, G., & Valdés-Solı́s, T. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2006.12.017 · Cited by 906 · see citing works
Liquid-phase chemical hydrogen storage materials
Yadav, M., & Xü, Q. (2012) · Energy & Environmental Science · doi:10.1039/c2ee22937d · Cited by 842 · see citing works
Feasibility of biological hydrogen production from organic fraction of municipal solid waste
Lay, J., Lee, Y., & Noike, T. (1999) · Water Research · doi:10.1016/s0043-1354(98)00483-7 · Cited by 785 · see citing works
Photocatalytic production of hydrogen from biomass-derived feedstocks
Puga, A. V. (2016) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2015.12.009 · Cited by 438 · see citing works
Nickel- and cobalt-based catalysts for hydrogen generation by hydrolysis of borohydride
Liu, B. H., Li, Z. P., & Suda, S. (2005) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2005.08.019 · Cited by 327 · see citing works
Review of Methods for the Catalytic Hydrogenation of Carboxamides
Smith, A. M., II, & Whyman, R. (2014) · Chemical Reviews · doi:10.1021/cr400609m · Cited by 326 · see citing works
Ammonia borane, a material with exceptional properties for chemical hydrogen storage
Demirci, U. B. (2017) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2017.01.154 · Cited by 325 · see citing works
Demirci, U. B., Akdim, O., Andrieux, J., Hannauer, J., Chamoun, R., & Miele, P. (2010) · Fuel Cells · doi:10.1002/fuce.200800171 · Cited by 315 · see citing works
Hydrogen generation by hydrolysis of NaBH4 with efficient Co–P–B catalyst: A kinetic study
Patel, N., Fernandes, R., & Miotello, A. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.11.121 · Cited by 247 · see citing works
Demirci, U. B., & Miele, P. (2010) · Physical Chemistry Chemical Physics · doi:10.1039/c0cp00295j · Cited by 227 · see citing works
Carbon-supported platinum catalysts for on-site hydrogen generation from NaBH4 solution
Bai, Y., Wu, C., Wu, F., & Yi, B. (2006) · Materials Letters · doi:10.1016/j.matlet.2005.12.119 · Cited by 223 · see citing works
Research advances towards large-scale solar hydrogen production from water
Liu, G., Sheng, Y., Ager, J. W., Kraft, M., & Xu, R. Q. (2019) · EnergyChem · doi:10.1016/j.enchem.2019.100014 · Cited by 206 · see citing works
Pd-C powder and thin film catalysts for hydrogen production by hydrolysis of sodium borohydride
PATEL, N., PATTON, B., ZANCHETTA, C., FERNANDES, R., GUELLA, G., KALE, A., & MIOTELLO, A. (2008) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2007.07.018 · Cited by 199 · see citing works
The Surface Chemistry of Metal-Based Hydrogenation Catalysis
Zaera, F. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01368 · Cited by 197 · see citing works
Peschka, W. (1992) · Springer eBooks · doi:10.1007/978-3-7091-9126-2 · Cited by 183 · see citing works
Xue, S., Garlyyev, B., Watzele, S., Liang, Y., Fichtner, J., Pohl, M. D., & Bandarenka, A. S. (2018) · ChemElectroChem · doi:10.1002/celc.201800690 · Cited by 181 · see citing works
A Nickel Phosphine Complex as a Fast and Efficient Hydrogen Production Catalyst
Gan, L., Groy, T. L., Tarakeshwar, P., Mazinani, S. K. S., Shearer, J., Mújica, V., & Jones, A. K. (2015) · Journal of the American Chemical Society · doi:10.1021/ja509779q · Cited by 167 · see citing works
Chen, B., Chen, S., Bandal, H. A., Appiah‐Ntiamoah, R., Jadhav, A. R., & Kim, H. (2018) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2018.03.193 · Cited by 166 · see citing works
Hydrogen Generation from Chemical Hydrides
Marrero-Alfonso, E. Y., Beaird, A. M., Davis, T. A., & Matthews, M. (2009) · Industrial & Engineering Chemistry Research · doi:10.1021/ie8016225 · Cited by 166 · see citing works
Nahar, G. A., Mote, D. R., & Dupont, V. A. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.031 · Cited by 155 · see citing works
Cobalt-based catalysts for the hydrolysis of NaBH4 and NH3BH3
Demirci, U. B., & Miele, P. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp00250d · Cited by 155 · see citing works
Ding, X.-L., Yuan, X., Jia, C., & Ma, Z. (2010) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.07.030 · Cited by 152 · see citing works
Lu, Y.-C., Chen, M.-S., & Chen, Y. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.11.105 · Cited by 127 · see citing works
Xu, D., Wang, H., Guo, Q., & Ji, S. (2011) · Fuel Processing Technology · doi:10.1016/j.fuproc.2011.04.006 · Cited by 122 · see citing works
Jeong, S., Cho, E. A., Nam, S., Oh, I., Jung, U. H., & Kim, S. H. (2007) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2006.11.036 · Cited by 120 · see citing works
Patel, N., Fernandes, R., Guella, G., Kale, A., Miotello, A., Patton, B., & Zanchetta, C. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp7104192 · Cited by 118 · see citing works
Hydrogen generation by hydrolysis of sodium borohydride on CoB/SiO2 catalyst
Yang, C.-C., Chen, M.-S., & Chen, Y. (2010) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.11.006 · Cited by 115 · see citing works
Catalysts for the hydrolysis of aqueous borohydride solutions to produce hydrogen for PEM fuel cells
Krishnan, P., Hsueh, K., & Yim, S. (2007) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2007.07.024 · Cited by 114 · see citing works
Rossin, A., Tuci, G., Luconi, L., & Giambastiani, G. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b01495 · Cited by 113 · see citing works
Cobalt oxide catalyst for hydrolysis of sodium borohydride and ammonia borane
Simagina, V. I., Komova, O. V., Ozerova, A. M., Netskina, O. V., Odegova, G. V., Келлерман, Д. Г., Bulavchenko, O. A., & Ищенко, А. В. (2010) · Applied Catalysis A General · doi:10.1016/j.apcata.2010.12.028 · Cited by 110 · see citing works
Kim, D.-R., Cho, K.-W., Choi, Y.-I., & Park, C. (2009) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2008.12.097 · Cited by 106 · see citing works
Şahiner, N., Özay, Ö., İnger, E., & Aktaş, N. (2010) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2010.11.042 · Cited by 94 · see citing works
Ren, J., Chen, L., Weng, C., Yuan, G., & Yuan, Z. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b12108 · Cited by 84 · see citing works
RECENT PROGRESS IN BORON- AND NITROGEN-BASED CHEMICAL HYDROGEN STORAGE
Lu, Z., & Xü, Q. (2012) · Functional Materials Letters · doi:10.1142/s1793604712300010 · Cited by 82 · see citing works
Cooperative Strategies for Catalytic Hydrogenation of Unsaturated Hydrocarbons
Karunananda, M. K., & Mankad, N. P. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02203 · Cited by 81 · see citing works
Razavi-Tousi, S. S., & Szpunar, J. A. (2016) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2016.04.038 · Cited by 80 · see citing works
Huff, C., Long, J. M., Heyman, A., & Abdel‐Fattah, T. M. (2018) · ACS Applied Energy Materials · doi:10.1021/acsaem.8b00748 · Cited by 76 · see citing works
Niu, W., Ren, D., Han, Y., Wu, Y., & Gou, X. (2012) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2012.07.099 · Cited by 75 · see citing works
Zhu, J., Li, R., Niu, W., Wu, Y., & Gou, X. (2012) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.03.051 · Cited by 75 · see citing works
Crisafulli, C., Sciré, S., Salanitri, M., Zito, R., & Calamia, S. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.12.089 · Cited by 73 · see citing works
Yuan, X., Jia, C., Ding, X.-L., & Ma, Z. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.03.064 · Cited by 73 · see citing works
Improved hydrogen storage capacity through hydrolysis of solid NaBH4 catalyzed with cobalt boride
Delmas, J.-C., Laversenne, L., Rougeaux, I., Capron, P., Garron, A., Bennici, S. M., Świerczyński, D., & Auroux, A. (2010) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.11.036 · Cited by 69 · see citing works
Kinetics of NaBH4 hydrolysis on carbon-supported ruthenium catalysts
Zou, Y., Nie, M., Huang, Y., Wang, J. Q., & Liu, H. L. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.06.138 · Cited by 64 · see citing works
Vernekar, A. A., Bugde, S. T., & Tilve, S. G. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.09.033 · Cited by 62 · see citing works
Şahi̇n, Ö., Saka, C., Baytar, O., & Hansu, F. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2013.05.036 · Cited by 55 · see citing works
Bennici, S. M., Yu, H., Obeid, E., & Auroux, A. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.03.148 · Cited by 52 · see citing works
Cavaliere-Jaricot, S., Hannauer, J., Demirci, U. B., Akdim, O., & Miele, P. (2011) · Catalysis Today · doi:10.1016/j.cattod.2011.02.016 · Cited by 50 · see citing works
Karataş, Y., Gülcan, M., & Şen, F. (2019) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.04.012 · Cited by 46 · see citing works
Netskina, O. V., Kochubey, D. I., Prosvirin, I. P., Malykhin, S. E., Komova, O. V., Kanazhevskiy, V. V., Chukalkin, Y. G., Бобровский, В. И., Келлерман, Д. Г., Ищенко, А. В., et al. (2017) · Molecular Catalysis · doi:10.1016/j.mcat.2017.08.008 · Cited by 44 · see citing works
Jana, R., Chowdhury, C., Malik, S., & Datta, A. (2019) · ACS Applied Energy Materials · doi:10.1021/acsaem.9b00787 · Cited by 41 · see citing works
Netskina, O. V., Komova, O. V., Simagina, V. I., Odegova, G. V., Prosvirin, I. P., & Bulavchenko, O. A. (2016) · Renewable Energy · doi:10.1016/j.renene.2016.08.005 · Cited by 38 · see citing works
Liu, B. H., Li, Z. P., & Chen, L. L. (2008) · Journal of Power Sources · doi:10.1016/j.jpowsour.2008.02.058 · Cited by 38 · see citing works
Role of the electronic state of rhodium in sodium borohydride hydrolysis
Netskina, O. V., Kochubey, D. I., Prosvirin, I. P., Келлерман, Д. Г., Simagina, V. I., & Komova, O. V. (2014) · Journal of Molecular Catalysis A Chemical · doi:10.1016/j.molcata.2014.03.016 · Cited by 34 · see citing works
Determination of the heat evolved during sodium borohydride hydrolysis catalyzed by Co3O4
Damjanović-Vasilić, L., Majchrzak, M., Bennici, S. M., & Auroux, A. (2010) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2010.11.041 · Cited by 34 · see citing works
A durable ruthenium catalyst for the NaBH4 hydrolysis
Zou, Y., Huang, Y., Li, X., & Liu, H. L. (2011) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2011.01.027 · Cited by 30 · see citing works
Chamoun, R., Demırcı, B., Cornu, D., Zaatar, Y., Khoury, R., Khoury, A., & Miele, P. (2010) · Fuel · doi:10.1016/j.fuel.2010.11.037 · Cited by 25 · see citing works
Hydrogen generation from NaBH 4 hydrolysis using Co-B/AlPO 4 and Co-B/bentonite catalysts
Manna, J., Roy, B., Pareek, D., & Sharma, P. (2017) · Catalysis Structure & Reactivity · doi:10.1080/2055074x.2017.1344793 · Cited by 20 · see citing works
Superefficient thin film multilayer catalyst for generating hydrogen from sodium borohydride
Hu, L., Ceccato, R., & Raj, R. (2010) · Journal of Power Sources · doi:10.1016/j.jpowsour.2010.07.070 · Cited by 17 · see citing works
Netskina, O. V., Келлерман, Д. Г., Ищенко, А. В., Komova, O. V., & Simagina, V. I. (2017) · Colloids and Surfaces A Physicochemical and Engineering Aspects · doi:10.1016/j.colsurfa.2017.10.052 · Cited by 15 · see citing works
Oechsler, B. F., Dutra, J. C. S., Bittencourt, R. C. P., & Pinto, J. C. (2017) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.6b03665 · Cited by 9 · see citing works
Start Up of Biohydrogen Production System and Effect of Metal Ions on Hydrogen Production
An-ying, J., Li, Y., Yue, L., Yang, C., Jin, F., Zhou, Q., & Wu, B. (2010) · AIP conference proceedings · doi:10.1063/1.3529274 · Cited by 3 · see citing works
Flagged first, then by citations
Cited by
Sorted by citations
A review on hydrogen generation from the hydrolysis of sodium borohydride
Abdelhamid, H. N. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.09.186 · Cited by 501 · see citing works
(2021) · doi:10.1039/d0ee01545h · Cited by 409 · see citing works
Recent developments of nanocatalyzed liquid-phase hydrogen generation
Wang, C., & Astruc, D. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00515k · Cited by 336 · see citing works
Li, G., Han, G., Wang, L., Cui, X., Moehring, N. K., Kidambi, P. R., Jiang, D., & Sun, Y. (2023) · Nature Communications · doi:10.1038/s41467-023-36142-7 · Cited by 262 · see citing works
A review of cobalt-based catalysts for sustainable energy and environmental applications
Gupta, S., Fernandes, R., Patel, R., Spreitzer, M., & Patel, N. (2023) · Applied Catalysis A General · doi:10.1016/j.apcata.2023.119254 · Cited by 212 · see citing works
Wang, C., Li, L., Yu, X., Lu, Z., Zhang, X., Wang, X., Yang, X., & Zhao, J. (2020) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.0c01475 · Cited by 83 · see citing works
Self-citationZhou, S., Cheng, L., Huang, Y., Liu, Y., Shi, L., Isimjan, T. T., & Yang, X. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.122519 · Cited by 81 · see citing works
Mao, M., Chen, Q., Wu, J., & Fan, G. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.07.097 · Cited by 72 · see citing works
Self-citationDall’Armi, C., Pivetta, D., & Taccani, R. (2023) · Energies · doi:10.3390/en16042022 · Cited by 64 · see citing works
Wang, Y., & Liu, X. (2021) · ACS Applied Nano Materials · doi:10.1021/acsanm.1c03067 · Cited by 63 · see citing works
Self-citationYao, L., Li, X., Peng, W., Yao, Q., Xia, J., & Lu, Z. (2020) · Inorganic Chemistry Frontiers · doi:10.1039/d0qi01244k · Cited by 59 · see citing works
Singh, R. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.10.022 · Cited by 58 · see citing works
Abebe, M. W., Baye, A. F., & Kim, H. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.07.106 · Cited by 57 · see citing works
Feng, Y., Wang, H., Chen, X. D., Lv, F., Li, Y., Zhu, Y., Xu, C., Zhang, X., Liu, H., & Li, H. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.04.257 · Cited by 57 · see citing works
Self-citationHuang, W., Xu, F., & Liu, X. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.05.083 · Cited by 55 · see citing works
Self-citationBeheshti, A. K., Rezaei, M., Alavi, S. M., Akbari, E., & Varbar, M. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.10.168 · Cited by 51 · see citing works
Dou, S., Zhang, W., Yang, Y., Zhou, S., Rao, X., Yan, P., Isimjan, T. T., & Yang, X. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.12.011 · Cited by 50 · see citing works
The mechanism and challenges of cobalt-boron-based catalysts in the hydrolysis of sodium borohydride
Long, B., Chen, J., Sharshir, S. W., Lawa, I., Zhou, W., Wang, C., Wang, L., & Yuan, Z. (2024) · Journal of Materials Chemistry A · doi:10.1039/d3ta07308d · Cited by 49 · see citing works
Rehydrogenation of Sodium Borates to Close the NaBH4-H2 Cycle: A Review
Nunes, H. X., Silva, D. L., Rangel, C. M., & Pinto, A. M. F. R. (2021) · Energies · doi:10.3390/en14123567 · Cited by 47 · see citing works
Lim, D., Özkan, G., & Özkan, G. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.03.039 · Cited by 47 · see citing works
Function of Defects in NH2-MIL-125@PANI@Co3O4 Photocatalyst for Efficient Hydrogen Evolution
Sk, S., Mondal, I., Mahata, A., Abraham, B. M., Nayak, C., Bhattacharyya, D., Jha, S. N., Ghosh, R., & Pal, U. (2022) · ACS Applied Energy Materials · doi:10.1021/acsaem.2c01899 · Cited by 43 · see citing works
A concise review of recent biohydrogen production technologies
Pachaiappan, R., Cornejo‐Ponce, L., Sagade, A. A., Mani, M., Aroulmoji, V., Rajan, V. F., & Manavalan, K. (2024) · Sustainable Energy Technologies and Assessments · doi:10.1016/j.seta.2024.103606 · Cited by 41 · see citing works
Li, T., Xiang, C., Chu, H., Xu, F., Sun, L., Zou, Y., & Zhang, J. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.164380 · Cited by 40 · see citing works
Chen, Y., Qian, C., & Fan, G. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.07.255 · Cited by 39 · see citing works
Self-citationMengesha, D. N., Baye, A. F., & Kim, H. (2024) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2024.01.085 · Cited by 38 · see citing works
Sun, T., Li, Y., Liu, Y., Jiao, W., & Zhang, D. (2023) · Chemical Engineering Journal · doi:10.1016/j.cej.2023.145133 · Cited by 37 · see citing works
Shiferraw, B. T., Baye, A. F., & Kim, H. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.08.212 · Cited by 36 · see citing works
Dabaro, M. D., Appiah‐Ntiamoah, R., Guye, M. E., Kassahun, S. K., & Kim, H. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.10.336 · Cited by 36 · see citing works
Zhang, S., Xu, J. C., Cheng, H., Zang, C., Bian, F., Sun, B., Shen, Y., & Jiang, H. (2020) · ChemSusChem · doi:10.1002/cssc.202001536 · Cited by 35 · see citing works
Raza, W., Ahmad, K., & Kim, H. (2021) · Nanotechnology · doi:10.1088/1361-6528/ac1dd4 · Cited by 35 · see citing works
Graphene-Modified Co-B-P Catalysts for Hydrogen Generation from Sodium Borohydride Hydrolysis
Jia, X., Sang, Z., Sun, L., Xu, F., Pan, H., Zhang, C., Cheng, R., Yu, Y., Hu, H., Kang, L., et al. (2022) · Nanomaterials · doi:10.3390/nano12162732 · Cited by 35 · see citing works
Jacob, B., Mohan, M., Dhanyaprabha, K. C., & Thomas, H. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.11.325 · Cited by 35 · see citing works
Meng, A., Sun, Y., Cheng, W., Zhai, Z., Jiang, L., Chong, Z., Chen, Y., & Wu, A. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.09.127 · Cited by 33 · see citing works
Li, H., Li, B., Zou, Y., Xiang, C., Zhang, H., Xu, F., Sun, L., & He, K. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.166556 · Cited by 33 · see citing works
Colak, T. O., Altaf, Ç. T., Minkina, V. G., Shabunya, S. I., Sankır, M., Sankır, N. D., & Kalinin, V. I. (2021) · Catalysis Letters · doi:10.1007/s10562-021-03848-6 · Cited by 32 · see citing works
Su, M., Wang, H., Xu, H., Chen, F., Hu, H., & Gan, J. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.01.092 · Cited by 31 · see citing works
Hansu, T. A. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.04.269 · Cited by 31 · see citing works
Jiang, J., Yang, S., Lei, H., & Ai, L. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.07.073 · Cited by 30 · see citing works
Wen, Z., Fu, Q., Wu, J., & Fan, G. (2020) · Nanomaterials · doi:10.3390/nano10081612 · Cited by 29 · see citing works
Self-citationYe, S., Wang, Y., Wang, C., Cheng, L., Sun, L., & Yan, P. (2023) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2023.02.082 · Cited by 28 · see citing works
Ruthenium and Platinum-Modified Titanium Dioxide Support for NaBH4 Hydrolysis
Altaf, Ç. T., Minkina, V. G., Shabunya, S. I., Colak, T. O., Sankır, N. D., Sankır, M., & Kalinin, V. I. (2023) · ACS Omega · doi:10.1021/acsomega.3c04269 · Cited by 28 · see citing works
Dong, Y., Chen, Q., Qiu, C., Ma, X., Wang, Y., Sun, T., & Fan, G. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2020.03.016 · Cited by 27 · see citing works
Self-citationControllable hydrogen production from NaBH4 hydrolysis promoted by acetic acid
Song, J., Li, R., & Dong, H. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.11.204 · Cited by 27 · see citing works
On-demand hydrogen evolution upon magnetic composite-nanocatalyzed sodium borohydride hydrolysis
Wang, Y., Shen, J., Tian, H., Liu, X., & Huang, Y. (2021) · Journal of Molecular Liquids · doi:10.1016/j.molliq.2021.116633 · Cited by 26 · see citing works
Self-citationButenko, V. R., Komova, O. V., Simagina, V. I., Lipatnikova, I. L., Ozerova, A. M., Danilova, N. A., Rogov, V. A., Odegova, G. V., Bulavchenko, O. A., Chesalov, Y. A., et al. (2024) · Materials · doi:10.3390/ma17081794 · Cited by 25 · see citing works
Pham, S. H., Phan, T. S., Nguyen, H. N., Cong, H. H., Pham, D. K., Nguyen, N. L., Le, T. H. P., Nguyen, D. C., Nguyen, T. L., Nguyen, D. L., et al. (2024) · Journal of Energy Storage · doi:10.1016/j.est.2024.112545 · Cited by 25 · see citing works
Zhao, X., Hu, H., Guo, L., Cai, J., Wang, Y., & Fan, G. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.165076 · Cited by 23 · see citing works
Self-citationYu, X., Qian, K., Du, L., Zhang, J., Lu, N., Miao, Z., Li, Y., Kobayashi, H., Yan, X., & Li, R. (2022) · Sustainable Energy & Fuels · doi:10.1039/d2se00436d · Cited by 23 · see citing works
An Al–Li alloy/water system for superior and low-temperature hydrogen production
Liu, M., Liu, H., Chen, K., Sun, J., Wang, H., Liu, J., & Ouyang, L. (2021) · Inorganic Chemistry Frontiers · doi:10.1039/d1qi00487e · Cited by 22 · see citing works
Zhang, J., Li, Y., Yang, L., Zhang, F., Li, R., & Dong, H. (2021) · Catalysis Letters · doi:10.1007/s10562-021-03730-5 · Cited by 22 · see citing works
Feng, Z., Wang, Y., & Bai, X. (2022) · Environmental Science and Pollution Research · doi:10.1007/s11356-022-18926-4 · Cited by 22 · see citing works
Qin, C., Wu, W., Gomaa, H., Wu, S., An, C., Deng, Q., & Hu, N. (2023) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2023.07.027 · Cited by 22 · see citing works
Malode, S. J., Pandiaraj, S., Alodhayb, A. N., & Shetti, N. P. (2025) · Energy & Fuels · doi:10.1021/acs.energyfuels.5c00315 · Cited by 21 · see citing works
Protection and confinement effect of carbon on Co/CoxOy nano-catalyst for efficient NaBH4 hydrolysis
Ming-bin, L., Guan, S., An, L., Zhang, H., Chen, Y., Shi, J., Fan, Y., & Liu, B. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.04.139 · Cited by 21 · see citing works
Zhou, J., Yan, J., Meng, X., Chen, W., Guo, J., & Liu, X. (2021) · Catalysis Letters · doi:10.1007/s10562-021-03661-1 · Cited by 21 · see citing works
Self-citationZhu, H. Q., Guo, A., Long, Y., & Fan, G. (2022) · Fuel · doi:10.1016/j.fuel.2022.123616 · Cited by 20 · see citing works
Self-citationKaya, Ş., Saka, C., Yıldız, D., Erol, S., Ulaş, B., Demir, I., & Kıvrak, H. (2023) · Journal of Applied Electrochemistry · doi:10.1007/s10800-023-01873-4 · Cited by 20 · see citing works
A review of anodes for direct borohydride fuel cells: Electrode and catalytic environment
Zhang, D., Sun, T., Cao, D., Liu, Y., Jiao, W., & Wang, G. (2023) · Journal of Power Sources · doi:10.1016/j.jpowsour.2023.233684 · Cited by 20 · see citing works
Tang, C. W., Zhou, G., Chen, J., Yin, J., Li, Y., Liu, C., Li, Q., Wang, T., Wang, Z., Wen, S., et al. (2023) · Energy & Fuels · doi:10.1021/acs.energyfuels.3c00620 · Cited by 19 · see citing works
Guo, Q., Wang, X., Yang, F., Zhou, S., Wei, K., Zhang, Y., Sun, L., Sun, S., Liu, H., An, J., et al. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.164141 · Cited by 19 · see citing works
Dabaro, M. D., & Kim, H. (2024) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2024.05.007 · Cited by 19 · see citing works
Qiu, J., Gao, X., & Peng, J. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.162961 · Cited by 18 · see citing works
Wu, L., Yang, M., Liu, Y., Wu, Y., Huang, D., Shao, J., & Wang, X. (2024) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2024.05.324 · Cited by 18 · see citing works
Wang, C., Li, J., Zhang, F., Zhao, Y., & Xiao, T. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.11.076 · Cited by 17 · see citing works
Chairam, S., Jarujamrus, P., & Amatatongchai, M. (2020) · Journal of the Iranian Chemical Society · doi:10.1007/s13738-020-02056-0 · Cited by 17 · see citing works
Recent Progress on Cobalt‐Based Heterogeneous Catalysts for Hydrogen Production from Ammonia Borane
Li, Y., Gao, X., Iv, X., Duan, Y. W., Sui, D., Chang, W., & Yang, Y. (2024) · ChemCatChem · doi:10.1002/cctc.202401271 · Cited by 16 · see citing works
Guan, K., Wang, L., Huang, L. W., Lei, W., Jia, Q., Zhang, H., & Zhang, S. (2020) · Catalysis Today · doi:10.1016/j.cattod.2020.10.028 · Cited by 15 · see citing works
Zhang, X., Li, P., Xu, B., Wang, J., Fan, G., Zhang, X., Liu, X., Zhang, K., & Jiang, W. (2021) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.1c00330 · Cited by 15 · see citing works
Self-citationHydrogen generation and stoichiometric hydrolysis of core–shell Al-Li-NaBH4 composite
Zhang, H., Fan, Y., Zhang, J., Xiao, X., & Ouyang, L. (2022) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2022.168638 · Cited by 14 · see citing works
Co@SiO2/C catalyst shielded by hierarchical shell for robust hydrogen production
Sun, L., Liu, M., Zhang, T., Huang, Y., Song, H., Yang, J., Dou, J., 李大成, Gao, X., Zhang, Q., et al. (2023) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2023.123537 · Cited by 14 · see citing works
Self-citationPDMA cryogel beads as a catalyst for hydrogen generation from NaBH4 alcoholysis
Şengel, S. B., Deveci, H., & Bütün, V. (2023) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2023.04.074 · Cited by 13 · see citing works
Saka, C. (2025) · Biomass and Bioenergy · doi:10.1016/j.biombioe.2025.108038 · Cited by 13 · see citing works
Ye, H., Hu, R., Wang, Z., Wang, J., & Zhou, S. (2023) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.3c03396 · Cited by 13 · see citing works
Lopez, M. A. R., Fajardo, H. V., Ferreira, G. M. D., Souza, T. F., Park, V. N., dos Santos, A. F. S. M., Rodrigues, T. S., Ramos, L. D., & Ferreira, G. M. D. (2024) · Waste and Biomass Valorization · doi:10.1007/s12649-024-02756-1 · Cited by 12 · see citing works
Şahi̇n, Ö., Lakhali, H., & Ceyhan, A. A. (2025) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2025.150114 · Cited by 12 · see citing works
Simultaneous preparation of sodium borohydride and ammonia gas by ball milling
Liu, Y., Paskevicius, M., Humphries, T. D., & Buckley, C. E. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.05.262 · Cited by 12 · see citing works
Khasanah, R. A. N., Lin, H.-C., Ho, H.-Y., Peng, Y.-P., Hsiao, H.-L., Wang, C.-R., & Chien, F. S.-S. (2022) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2022.01.167 · Cited by 11 · see citing works
Carbon Based Supports for Metal Nanoparticles for Hydrogen Generation Reactions Review
Abdel‐Fattah, T. M., & Biehler, E. (2024) · Advanced carbon journal. · doi:10.62184/acj.jacj100020241 · Cited by 10 · see citing works
Chen, P., Li, K., Yan, P., Wang, J., & Zhou, S. (2021) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.0c11161 · Cited by 10 · see citing works
Abutaleb, A. (2023) · Inorganics · doi:10.3390/inorganics11090352 · Cited by 9 · see citing works
Wang, Y., Sun, L., Sun, Y., Xu, F., Song, L., Peng, X., Wang, H., Zhao, Z., Su, Y., & Pan, H. (2025) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2025.181241 · Cited by 9 · see citing works
Osborne, J., Horten, M., & Abdel‐Fattah, T. M. (2020) · ECS Journal of Solid State Science and Technology · doi:10.1149/2162-8777/abb036 · Cited by 9 · see citing works
Zhang, D., Xue, B., Wang, F., Liang, H., Cao, Y., Zhang, D., & Liu, B. (2024) · ACS Applied Nano Materials · doi:10.1021/acsanm.4c01074 · Cited by 9 · see citing works
Deka, J. R., Saikia, D., Lu, N.-F., Chen, C., Kao, H., & Yang, Y. (2024) · Nanomaterials · doi:10.3390/nano14221818 · Cited by 8 · see citing works
Abraham, A. P. J., Fernandes, R., Nandana, S. M., Sunny, J., John, R. A. B., Gupta, S., Suryawanshi, A., Bhabal, R., Patel, R., & Patel, N. (2025) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2025.183440 · Cited by 8 · see citing works
Boron materials for energy applications
Ali, F. (2022) · Elsevier eBooks · doi:10.1016/b978-0-12-822127-3.00004-1 · Cited by 8 · see citing works
Synthesis and physical characterization of ZnW1-xInxO4 nanostructures for hydrogen production
Heiba, Z. K., Ghannam, M. M., Mohamed, M. B., Elshimy, H., & Badawi, A. (2025) · Physica B Condensed Matter · doi:10.1016/j.physb.2025.417111 · Cited by 7 · see citing works
Yelboğa, M., & Akbayrak, M. (2025) · Journal of Water Process Engineering · doi:10.1016/j.jwpe.2025.107866 · Cited by 7 · see citing works
Suryawanshi, A., Abraham, A. P. J., Gupta, S., Patel, R., Fernandes, R., & Patel, N. (2025) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2025.152927 · Cited by 6 · see citing works
Yurderi, M. (2024) · Research on Chemical Intermediates · doi:10.1007/s11164-024-05457-5 · Cited by 6 · see citing works
Synergistic catalytic hydrolysis of ammonia borane to release hydrogen over AgCo@CN
He, Y., Wu, J., Wang, Y., Long, Y., & Fan, G. (2022) · New Journal of Chemistry · doi:10.1039/d1nj05902e · Cited by 6 · see citing works
Self-citationNie, Y., Lin, W., Zhang, Y., Chen, Y., & Nie, R. (2022) · Dalton Transactions · doi:10.1039/d2dt02750j · Cited by 6 · see citing works
Meng, A., Sun, Y., Wu, P., Xue, L., Wei, N., & Li, C. (2025) · Chemical Engineering Journal · doi:10.1016/j.cej.2025.169747 · Cited by 5 · see citing works
Reversible Hydrogen Storage in Solid‐State Reaction Derived Core‐Shell NaBH 4 @Ni Nanocubes
Salman, M. S., & Aguey‐Zinsou, K. (2023) · Advanced Energy and Sustainability Research · doi:10.1002/aesr.202300215 · Cited by 5 · see citing works
Tuan, D. D., Kwon, E. E., Lin, J.-Y., Duan, X., Lin, Y., & Lin, K. A. (2020) · Chemical Papers · doi:10.1007/s11696-020-01326-8 · Cited by 5 · see citing works
Hydrogen Production from Ammonia Borane Hydrolysis Catalyzed by Metal Oxide-Based Materials
Wang, M., Wang, J., Zhao, X., Qin, G., Zhang, X., Lu, Z., Yu, X., Li, L., & Yang, X. (2023) · Russian Journal of Physical Chemistry A · doi:10.1134/s0036024423050175 · Cited by 5 · see citing works
Self-citationHeterogeneous kinetics of NaBH4 hydrolysis catalyzed by Co/TiO2
Shabunya, S. I., Minkina, V. G., Kalinin, V. I., & Martynenko, V. V. (2023) · Reaction Kinetics Mechanisms and Catalysis · doi:10.1007/s11144-023-02450-8 · Cited by 4 · see citing works
Kumari, S., Thakur, M., & Kumari, M. (2024) · ChemistrySelect · doi:10.1002/slct.202303916 · Cited by 3 · see citing works
Chen, C., Yang, X., Fu, Z., Zhou, L., Xu, B., Zhang, K., Zhou, S., Zhou, L., & Jiang, W. (2025) · ACS Applied Nano Materials · doi:10.1021/acsanm.5c02353 · Cited by 3 · see citing works
Self-citation
- Authors
- Zhang, X., Zhang, Q., Xu, B., Liu, X., Zhang, K., Fan, G., & Jiang, W.
- Affiliations
- Sichuan University of Science and Engineering (CN)
- Sichuan Normal University (CN)
- Corresponding author
- Jiang, Weidong
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-01-31
- Volume
- 12
- Issue
- 8
- Pages
- 9376-9386
- ISSN
- 1944-8244 (ISSN-L)
- 1944-8252
- OpenAlex
- W3004190582
- Cited by
- 125
- References
- 64
- Citations by year
- 2026: 10 · 2025: 19 · 2024: 16 · 2023: 25 · 2022: 22 · 2021: 20 · 2020: 13
- FWCI
- 7.78
- Type
- journal article
- Language
- en
- Open access
- closed
- Licence
- Locations
- ACS Applied Materials & Interfaces (publishedVersion)
- PubMed (publishedVersion)
- Funders
- State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization (2018FTSZ04)
- Zigong Science and Technology Bureau (2018YYJC20)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
- Physical Sciences › Materials Science › Materials Chemistry › Layered Double Hydroxides Synthesis and Applications
- Keywords
- hydrogen production, sodium borohydride hydrolysis, cobalt catalysts, sodium sulfate, sodium sulfide, Co3O4, Co-B alloys, catalyst preparation, hydrogen evolution reaction
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review