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Tubular‐Shaped Stoichiometric Chrysotile Nanocrystals
Open accessAbstract
Stoichiometric chrysotile tubular nanocrystals have been synthesized as possible starting materials for applications toward nanotechnology, and as a standard reference sample for the investigation of the molecular interactions between chrysotile, the most utilized asbestos, and biological systems. Chrysotile nanocrystals have been synthesized under controlled hydrothermal conditions, and have been characterized by chemical, morphological, structural, spectroscopic and microcalorimetric analyses. They show a constant “cylinder‐in‐cylinder” morphology constituted by two or three concentric subunits. Each single nanocrystal has a tubular shape of about 49±1 nm in outer maximum diameter, and a hollow core of about 7±1 nm. Structural investigation carried out on an X‐ray powder pattern allowed to improve the structural model proposed for chrysotile mineral samples. Synthetic chrysotile crystallizes in the monoclinic Cc space group with a=0.5340(1) nm, b=0.9241(1) nm, and c=1.4689(2) nm, β=93.66(3)°.
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The g_eff=4.3 isotropic resonance is assigned to isolated octahedral or tetrahedral high-spin Fe3+ under rhombic distortion.
“Several theoretical and experimental studies [36] have confidently assigned the g eff = 4.3 isotropic resonance to isolated octahedral or tetrahedral high-spin Fe 3+ under rhombic distortion”
From The Iron‐Related Molecular Toxicity Mechanism of Synthetic Asbestos Nanofibres: A Model Study for High‐Aspect‐Ratio Nanoparticles (2011) · cites this paper as [36]
The g_eff≈6 resonance is assigned to axially-distorted ferric ions.
“and the resonance at g eff ≈ 6 to axially-distorted ferric ions.”
From The Iron‐Related Molecular Toxicity Mechanism of Synthetic Asbestos Nanofibres: A Model Study for High‐Aspect‐Ratio Nanoparticles (2011) · cites this paper as [36]
Turci et al. have shown that HO. generation by synthetic, Fe-doped chrysotile nanocrystals first increased with increasing Fe content (up to 0.67 wt% Fe), but decreased again with further increasing Fe content.
“Turci et al. have shown that HO. generation by synthetic, Fe‐doped chrysotile nanocrystals42 first increased with increasing Fe content (up to 0.67 wt % Fe), but decreased again with further increasing Fe content.43”
Citations
Cites
Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism
Kresge, C. T., Leonowicz, M. E., Roth, W. J., Vartuli, J. C., & Beck, J. S. (1992) · Nature · doi:10.1038/359710a0 · Cited by 16,283
TREOR, a semi-exhaustive trial-and-error powder indexing program for all symmetries
Werner, P. ‐., Eriksson, L., & Westdahl, M. (1985) · Journal of Applied Crystallography · doi:10.1107/s0021889885010512 · Cited by 1,788
Carbon Nanotubes and Related Structures
Harris, P. J. F. (1999) · Cambridge University Press eBooks · doi:10.1017/cbo9780511605819 · Cited by 973
Treacy, M. M. J., Newsam, J. M., & Deem, M. W. (1991) · Proceedings of the Royal Society of London Series A Mathematical and Physical Sciences · doi:10.1098/rspa.1991.0062 · Cited by 607
Study of microstructure of chrysotile asbestos by high-resolution electron microscopy
Yada, K. (1971) · Acta Crystallographica Section A · doi:10.1107/s0567739471001402 · Cited by 290
THE BIOLOGICAL EFFECTS OF MINERAL FIBRES
Davis, J. M. (1981) · The Annals of Occupational Hygiene · doi:10.1093/annhyg/24.2.227 · Cited by 237
Chemical aspects of the toxicity of inhaled mineral dusts
Fubini, B., & Otero Areán, C. (1999) · Chemical Society Reviews · doi:10.1039/a805639k · Cited by 224
Non-carbon nanotubes: synthesis and simulation
Ivanovskii, A. L. (2002) · Russian Chemical Reviews · doi:10.1070/rc2002v071n03abeh000709 · Cited by 128
Single crystal Raman microscopic study of the asbestos mineral chrysotile
Kloprogge, J. T., Frost, R. L., & Rintoul, L. (1999) · Physical Chemistry Chemical Physics · doi:10.1039/a809238i · Cited by 114
The structure of chrysotile. II. Clino-chrysotile
Whittaker, E. J. W. (1956) · Acta Crystallographica · doi:10.1107/s0365110x5600245x · Cited by 106
Kinetic study of the dehydroxylation of chrysotile asbestos with temperature by in situ XRPD
Cattaneo, A., Gualtieri, A. F., & Artioli, G. (2003) · Physics and Chemistry of Minerals · doi:10.1007/s00269-003-0298-2 · Cited by 102
Self-citationSimultaneous refinement of structure and microstructure of layered materials
Leoni, M., Gualtieri, A. F., & Roveri, N. (2004) · Journal of Applied Crystallography · doi:10.1107/s0021889803022787 · Cited by 89
Self-citationHemley, J. J., Montoya, J. W., Shaw, D. R., et al. (1977) · American Journal of Science · doi:10.2475/ajs.277.4.353 · Cited by 78
Structural and morphological characterization of synthetic chrysotile single crystals
Falini, G., Foresti, E., Lesci, G., & Roveri, N. (2002) · Chemical Communications · doi:10.1039/b203430a · Cited by 61
Self-citationThe structure of chrysotile. III. Ortho-chrysotile
Whittaker, E. J. W. (1956) · Acta Crystallographica · doi:10.1107/s0365110x56002461 · Cited by 51
Gualtieri, A. F., & Artioli, G. (1995) · Powder Diffraction · doi:10.1017/s0885715600014962 · Cited by 51
Self-citationAsbestos in the natural environment
(1991) · Environment International · doi:10.1016/0160-4120(91)90303-8 · Cited by 43
Foresti, E., Gazzano, M., Gualtieri, A. F., et al. (2003) · Analytical and Bioanalytical Chemistry · doi:10.1007/s00216-003-1965-3 · Cited by 39
Self-citationNovel quantum confined structures via atmospheric pressure MOCVD growth in asbestos and opals
Yates, H. M., Flavell, W. R., Pemble, M. E., et al. (1997) · Journal of Crystal Growth · doi:10.1016/s0022-0248(96)00512-x · Cited by 36
A classification of cylindrical lattices
Whittaker, E. J. W. (1955) · Acta Crystallographica · doi:10.1107/s0365110x55001771 · Cited by 35
Wicks, F. J. (2000) · Powder Diffraction · doi:10.1017/s0885715600010824 · Cited by 31
Association of Tremolite Habit with Biological Potential: Preliminary Report
Nolan, R. P., Langer, A. M., Oechsle, G. W., Addison, J., & Colflesh, D. E. (1991) · Springer eBooks · doi:10.1007/978-1-4684-1363-2_21 · Cited by 24
Filling of Chrysotile Nanotubes with Metals
Métraux, C., Grobéty, B., & Ulmer, P. (2002) · Journal of materials research/Pratt's guide to venture capital sources · doi:10.1557/jmr.2002.0167 · Cited by 20
Asbestos in The Natural Environment
(1989) · Studies in environmental science · doi:10.1016/s0166-1116(08)x7003-7 · Cited by 18
On the transformation of synthetic diopside into chrysotile
Barrese, E., Belluso, E., & Abbona, F. (1996) · European Journal of Mineralogy · doi:10.1127/ejm/9/1/0083 · Cited by 7
Choquette, D. (1983) · Cited by 1
Flagged first, then by citations
Research works printed but not linked: 19
- 1983, Asbestos: Properties, Applications, and Hazards. Vol. 2
- Ross M., 1981, ”: Rev. Mineral, 9, 279
- Mossman B. T., 1992, Rev. Mineral, 513
- Cressey B. A., 1993, Mineral. Mag., 57
- Jagodzinski H., 1953, Neues Jahrbuch fuer Mineralogie, 97
- Devouard B., 1995, Eur. J. Mineral., 7
- Veblen D. R., Science, 1398
- Wicks F. J., 1988, Serpentine Minerals: Structures and Petrology, in Hydrous Phyllosilicates, 19
- Yada K., 1977, Am. Mineral., 62, 958
- Pott F., 1980, IARC, 2, 261
- Noll W., 1958, Kolloid‐Z., 1, 157
- Ushio M., 1970, J. Chem. Soc. Jpn., 73, 1775
- Korytkova E. N., 1971, Doklady Earth Sci. Sect., 196, 144
- Moody J., 1976, Can. Mineral., 14, 462
- Koshimizu H., 1981, Clay Sci., 21, 130
- Chernosky J., 1975, Am. Mineral., 60, 200
- Dungan M. A., 1977, Am. Mineral., 62, 1018
- Oterdoom W. K., 1978, Schweiz. Mineral. Petrogr. Mitt., 58, 127
- Hodgson A. A., 1985, Asbestos, 67
Cited by
Sorted by citations
Wilson, S. A. (2006) · American Mineralogist · doi:10.2138/am.2006.2058 · Cited by 172
Gazzano, E., Turci, F., Foresti, E., Putzu, M. G., Aldieri, E., Silvagno, F., Lesci, I. G., Tomatis, M., Riganti, C., Romano, C., et al. (2007) · Chemical Research in Toxicology · doi:10.1021/tx600354f · Cited by 88
Self-citationTurci, F., Tomatis, M., Lesci, I. G., Roveri, N., & Fubini, B. (2011) · Chemistry – A European Journal · doi:10.1002/chem.201001893 · Cited by 73
Self-citationAsbestos health hazard: A spectroscopic study of synthetic geoinspired Fe-doped chrysotile
Foresti, E., Fornero, E., Lesci, I. G., Rinaudo, C., Zuccheri, T., & Roveri, N. (2009) · Journal of Hazardous Materials · doi:10.1016/j.jhazmat.2009.01.103 · Cited by 60
Self-citationAdsorption of bovine serum albumin onto synthetic Fe-doped Geomimetic chrysotile
Adamiano, A., Lesci, I. G., Fabbri, D., & Roveri, N. (2015) · Journal of The Royal Society Interface · doi:10.1098/rsif.2015.0186 · Cited by 17
Walter, M., Schenkeveld, W. D. C., Reissner, M., Gille, L., & Kraemer, S. M. (2019) · Chemistry – A European Journal · doi:10.1002/chem.201804319 · Cited by 14
Metadata
- Authors
- Falini, G., Foresti, E., Gazzano, M., Gualtieri, A. F., Leoni, M., Lesci, I. G., & Roveri, N.
- Affiliations
- University of Bologna (IT)
- Institute of Organic Synthesis and Photoreactivity (IT)
- University of Modena and Reggio Emilia (IT)
- University of Trento (IT)
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2004-06-15
- Volume
- 10
- Issue
- 12
- Pages
- 3043-3049
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2164799993
- Cited by
- 150
- References
- 26
- Citations by year
- 2026: 2 · 2025: 7 · 2024: 6 · 2023: 9 · 2022: 8 · 2021: 7 · 2020: 4 · 2019: 9 · 2018: 10 · 2017: 8 · 2016: 6 · 2015: 7 · 2014: 4 · 2013: 11 · 2012: 6
- FWCI
- 3.82
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Locations
- Chemistry - A European Journal (publishedVersion)
- PubMed (publishedVersion)
- Archivio istituzionale della ricerca (Alma Mater Studiorum Università di Bologna) (submittedVersion)
- IRIS UNIMORE (University of Modena and Reggio Emilia) (submittedVersion, cc-by)
- Iris (University of Trento) (submittedVersion)
- Topics
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Clay minerals and soil interactions
- Physical Sciences › Materials Science › Materials Chemistry › Chemical and Physical Properties of Materials
- Physical Sciences › Earth and Planetary Sciences › Geochemistry and Petrology › Mineralogy and Gemology Studies
- Keywords
- chrysotile, asbestos, hydrothermal synthesis, hollow core, monoclinic crystal structure, structural model, reference samples
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