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Polymer‐Induced Alignment of dl‐Alanine Nanocrystals to Crystalline Mesostructures
Abstract
Crystallization of dl‐alanine by cooling of a supersaturated solution in the presence of a chiral double‐hydrophilic block copolymer poly(ethylene glycol)‐block‐poly(ethylene imine)‐S‐isobutyric acid (PEG 4700‐PEI 1200‐S‐i BAc) yields crystal superstructures with an astonishing morphology. Although analysis by light microscopy reveals these crystals to be apparently well facetted, electron microscopy shows that they consist of three‐dimensionally, well‐aligned nanocrystals that are scaffolded to a so‐called mesocrystal. This mesocrystal is formed by polymer‐mediated structuration, and provides evidence for the importance of mesoscopic events in a typical crystallization process.
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Lowenstam, H. A., & Weiner, S. (1989) · doi:10.1093/oso/9780195049770.001.0001 · Cited by 2,090
Addadi, L., Weinstein, S., Gati, E., Weissbuch, I., & Lahav, M. (1982) · Journal of the American Chemical Society · doi:10.1021/ja00381a018 · Cited by 186
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Metadata
- Authors
- Wohlrab, S., Pinna, N., Antonietti, M., & Cölfen, H.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2005-01
- Volume
- 11
- Issue
- 10
- Pages
- 2903-2913
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2100144401
- Cited by
- 163
- References
- 2
- FWCI
- 10.08
- Type
- journal article
- Language
- en
- Open access
- closed
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- Wohlrab, S., Pinna, N., Antonietti, M., & Cölfen, H. (2005). Polymer‐Induced Alignment of dl‐Alanine Nanocrystals to Crystalline Mesostructures. Chemistry – A European Journal. https://doi.org/10.1002/chem.200400420
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