Construction of Inorganic Bulks through Coalescence of Particle Precursors
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Bulk inorganic materials play important roles in human society, and their construction is commonly achieved by the coalescence of inorganic nano- or micro-sized particles. Understanding the coalescence process promotes the elimination of particle interfaces, leading to continuous bulk phases with improved functions. In this review, we mainly focus on the coalescence of ceramic and metal materials for bulk construction. The basic knowledge of coalescent mechanism on inorganic materials is briefly introduced. Then, the properties of the inorganic precursors, which determine the coalescent behaviors of inorganic phases, are discussed from the views of particle interface, size, crystallinity, and orientation. The relationships between fundamental discoveries and industrial applications are emphasized. Based upon the understandings, the applications of inorganic bulk materials produced by the coalescence of their particle precursors are further presented. In conclusion, the challenges of particle coalescence for bulk material construction are presented, and the connection between recent fundamental findings and industrial applications is highlighted, aiming to provide an insightful outlook for the future development of functional inorganic materials.
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Sintering depends on the crystalline orientation of particles because grain boundary energy relates to the degree of misorientation between two particles and gives an energy barrier for particle coalescence.
“It should be noted that sintering depends on the crystalline orientation of particles as the grain boundary energy relates to the degree of misorientation between two particles and gives an energy barrier for particle coalescence [83,85].”
From Control of Columnar Grain Microstructure in CSD LaNiO3 Films (2023) · cites this paper as [85]
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Taking advantage of disorder: amorphous calcium carbonate and its roles in biomineralization
Addadi, L., Raz, S., & Weiner, S. (2003) · Advanced Materials · doi:10.1002/adma.200300381 · Cited by 1,594 · see citing works
A review of ceramic sintering and suggestions on reducing sintering temperatures
Kuang, X., Carotenuto, G., & Nicolais, L. (1997) · Advanced Performance Materials · doi:10.1023/a:1008621020555 · Cited by 147 · see citing works
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Atanova, A. V., Seregin, D. S., Zhigalina, O. M., Khmelenin, D. N., Orlov, G. A., Turkina, D. I., Sigov, A. S., & Vorotilov, K. A. (2023) · Molecules · doi:10.3390/molecules28041938 · Cited by 5 · see citing works
- Authors
- Mu, Z., Tang, R., & Liu, Z.
- Affiliations
- Zhejiang University (CN)
- State Key Laboratory of Silicon Materials (CN)
- Corresponding author
- Liu, Zhaoming
- Venue
- Nanomaterials
- Publisher
- MDPI AG
- Published
- 2021-01-18
- Volume
- 11
- Issue
- 1
- Pages
- 241
- ISSN
- 2079-4991 (ISSN-L)
- PMC
- PMC7831130
- OpenAlex
- W3121264815
- Cited by
- 20
- References
- 2
- Citations by year
- 2026: 6 · 2025: 3 · 2024: 3 · 2023: 5 · 2022: 1 · 2021: 2
- FWCI
- 0.42
- Type
- journal article
- Language
- en
- Open access
- gold
- doi.org
- Licence
- Locations
- Nanomaterials (publishedVersion, cc-by)
- PubMed Central (publishedVersion, cc-by)
- PubMed (publishedVersion)
- DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
- Funders
- National Natural Science Foundation of China (22022511, 21805241)
- Topics
- Physical Sciences › Materials Science › Ceramics and Composites › Advanced ceramic materials synthesis
- Physical Sciences › Materials Science › Materials Chemistry › Chemical and Physical Properties of Materials
- Physical Sciences › Engineering › Building and Construction › Recycling and utilization of industrial and municipal waste in materials production
- Keywords
- particle coalescence, ceramics, metals, particle interfaces, particle size, crystallinity, crystal orientation, functional inorganic materials
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