Near Monodisperse TiO2 Nanoparticles and Nanorods
Abstract
Highly crystalline, near monodisperse TiO2 nanoparticles, nanorods and their metal-ion-doped (Sn4+, Fe3+, Co2+, and Ni2+, etc.) derivatives have been prepared by well-controlled solvothermal reactions. Through adjusting the reaction parameters, such as reaction temperature, duration, and concentration of the reactants, the size, shape, and dispersibility of the products can be controlled. A possible reaction mechanism can be proposed based on experimental evidence.
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Ester elimination takes place between metal alkoxides and carboxylates and is applied in synthesis of zinc oxide, titania, and indium oxide.
“Ester elimination takes place between metal alkoxides and carboxylates, a method applied in the synthesis of zinc oxide [45], titania [46], and indium oxide [47] ((3) in Scheme 1).”
From Recent Advances in Metal-Oxide-Based Photoresists for EUV Lithography (2024) · cites this paper as [46]
TiO2, ZrO2, and HfO2 can create diverse nanostructures with controlled dimensions and distinctive morphologies using surfactant-mediated synthesis.
“TiO2, ZrO2, and HfO2 exhibits the ability to create diverse nanostructures with controlled dimensions and distinctive morphologies using surfactant-mediated synthesis [46,54,55].”
From Recent Advances in Metal-Oxide-Based Photoresists for EUV Lithography (2024) · cites this paper as [46]
Cites
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487 · see citing works
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Nonaqueous sol–gel routes to metal oxide nanoparticles
Niederberger, M. (2007) · Accounts of Chemical Research · doi:10.1021/ar600035e · Cited by 761 · see citing works
Recent Advances in Metal-Oxide-Based Photoresists for EUV Lithography
Hasan, M. W., Deeb, L., Kumaniaev, S., Wei, C., & Wang, K. (2024) · Micromachines · doi:10.3390/mi15091122 · Cited by 29 · see citing works
“Ester elimination takes place between metal alkoxides and carboxylates, a method applied in the synthesis of zinc oxide [45], titania [46], and indium oxide [47] ((3) in Scheme 1).”
BackgroundMethod
- Authors
- Li, X., Peng, Q., Yi, J., Wang, X., & Li, Y.
- Affiliations
- Tsinghua University (CN)
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2006-02-21
- Volume
- 12
- Issue
- 8
- Pages
- 2383-2391
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2141487191
- Cited by
- 175
- References
- 1
- Citations by year
- 2026: 2 · 2025: 1 · 2024: 5 · 2023: 2 · 2022: 7 · 2021: 4 · 2020: 7 · 2019: 6 · 2018: 7 · 2017: 9 · 2016: 9 · 2015: 13 · 2014: 12 · 2013: 15 · 2012: 10
- FWCI
- 5.76
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Chemistry - A European Journal (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › TiO2 Photocatalysis and Solar Cells
- Physical Sciences › Materials Science › Materials Chemistry › Chemical and Physical Properties of Materials
- Physical Sciences › Chemistry › Inorganic Chemistry › Pigment Synthesis and Properties
- Keywords
- titanium dioxide, titanium dioxide nanoparticles, TiO2 nanorods, monodispersity, solvothermal synthesis, metal ion doping, tin doping, iron doping, cobalt doping, nickel doping, particle size control, reaction mechanism, crystallinity
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