The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.
Selectivity Effects in Bimetallic Catalysis
Abstract
An emerging area of homogeneous catalysis is the use of catalysts featuring two closely associated metal sites. This approach complements the traditional focus on single‐site catalysts and makes available new parameters with which to optimize catalytic behavior. Single‐site catalysts are optimized through changing 1) the identity of the metal, and 2) the steric and electronic properties of the ligands. Bimetallic catalysts introduce new optimization parameters such as 3) catalyst nuclearity (mononuclear vs. binuclear), and 4) bimetallic pairing (relative compatibility of two metal sites). In order to harness these new optimization parameters in developing systems, it is necessary to first understand the origin of bimetallic selectivity effects that already have been documented. This Concept article highlights bimetallic effects on the chemo‐, regio‐, and stereoselectivity of catalytic transformations, using selected case studies from the recent literature as illustrative examples.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Cited by
Metal–Metal Bonds in Catalysis
Powers, I. G., & Uyeda, C. (2017) · ACS Catalysis · doi:10.1021/acscatal.6b02692 · Cited by 369
Metadata
- Authors
- Mankad, N. P.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2016-02-16
- Volume
- 22
- Issue
- 17
- Pages
- 5822-5829
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2280849059
- Cited by
- 199
- References
- 1
- FWCI
- 10.39
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Selectivity Effects in Bimetallic Catalysis. https://app.cochat.ai/papers/10.1002/chem.201505002
- The paper
- Mankad, N. P. (2016). Selectivity Effects in Bimetallic Catalysis. Chemistry – A European Journal. https://doi.org/10.1002/chem.201505002
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
