The DOI matches its Crossref record; 7 of the 7 references it cites were found in a registry or an index.
Immobilizing Molecular Metal Dithiolene–Diamine Complexes on 2D Metal–Organic Frameworks for Electrocatalytic H2 Production
Abstract
Carbon electrocatalysts consisting of metal complexes such as MNx or MSx are promising alternatives to high‐cost Pt catalysts for the hydrogen evolution reaction (HER). However, the exact HER active sites remain elusive. Here, molecular metal dithiolene‐diamine (MS 2 N 2, M=Co and Ni), metal bis(dithiolene) (MS 4), and metal bis(diamine) (MN 4) complexes were selectively incorporated into carbon‐rich 2D metal–organic frameworks (2D MOFs) as model carbon electrocatalysts. The 2D MOF single layers, powders, and composites with graphene were thus prepared and showed definite active sites for H 2 generation. The electrocatalytic HER activity of the 2D MOF‐based catalysts with different metal complexes follow the order of MS 2 N 2>MN 4>MS 4. Moreover, the protonation preferentially occurred on the metal atoms, and the concomitant heterolytic elimination of H 2 was favored on the M–N units in the MS 2 N 2 active centers. The results provide an in‐depth understanding of the catalytic active sites, thus making way for the future development of metal complexes in carbon‐rich electrode materials for energy generation.
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Cites
Hydrogen evolution by a metal-free electrocatalyst
Zheng, Y., Jiao, Y., Zhu, Y., Li, L. H., Han, Y., Chen, Y., Du, A., Jaroniec, M., & Qiao, S. Z. (2014) · Nature Communications · doi:10.1038/ncomms4783 · Cited by 2,236
Atomic cobalt on nitrogen-doped graphene for hydrogen generation
Fei, H., Dong, J., Arellano-Jiménez, M. J., Ye, G., Dong Kim, N., Samuel, E. L. G., Peng, Z., Zhu, Z., Qin, F., Bao, J., et al. (2015) · Nature Communications · doi:10.1038/ncomms9668 · Cited by 1,621
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Qiu, H. ‐., Ito, Y., Cong, W., Tan, Y., Liu, P., Hirata, A., Fujita, T., Tang, Z., & Chen, M. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201507381 · Cited by 756
Molecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution
Liang, H.-W., Brüller, S., Dong, R., Zhang, J., Feng, X., & Müllen, K. (2015) · Nature Communications · doi:10.1038/ncomms8992 · Cited by 655
Self-citationA Cobalt–Dithiolene Complex for the Photocatalytic and Electrocatalytic Reduction of Protons
McNamara, W. R., Han, Z., Alperin, P. J., Brennessel, W. W., Holland, P. L., & Eisenberg, R. (2011) · Journal of the American Chemical Society · doi:10.1021/ja207842r · Cited by 398
Singh, W. M., Baine, T., Kudo, S., Tian, S., Ma, X. A. N., Zhou, H., DeYonker, N. J., Pham, T. C., Bollinger, J. C., Baker, D. L., et al. (2012) · Angewandte Chemie · doi:10.1002/ange.201200082 · Cited by 66
Cited by
Interface-Assisted Synthesis of 2D Materials: Trend and Challenges
Dong, R., Zhang, T., & Feng, X. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00056 · Cited by 710
Self-citationRecent progress in metal-organic frameworks as active materials for supercapacitors
Wang, K.-B., Xun, Q., & Zhang, Q. (2020) · EnergyChem · doi:10.1016/j.enchem.2019.100025 · Cited by 474
RETRACTED: Metallic Conductivity in a Two-Dimensional Cobalt Dithiolene Metal–Organic Framework
Clough, A. J., Skelton, J. M., Downes, C. A., de la Rosa, A. A., Yoo, J. W., Walsh, A., Melot, B. C., & Marinescu, S. C. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b05742 · Cited by 359
RetractedHuang, H., Zhao, Y., Bai, Y., Li, F., Zhang, Y., & Chen, Y. (2020) · Advanced Science · doi:10.1002/advs.202000012 · Cited by 335
Tu, K., Tranca, D., Rodríguez‐Hernández, F., Jiang, K., Huang, S., Zheng, Q., Chen, M., Lu, C., Su, Y., Chen, Z., et al. (2020) · Advanced Materials · doi:10.1002/adma.202005433 · Cited by 244
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Metadata
- Authors
- Dong, R., Zheng, Z., Tranca, D. C., Zhang, J., Chandrasekhar, N., Liu, S., Zhuang, X., Seifert, G., & Feng, X.
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2016-12-12
- Volume
- 23
- Issue
- 10
- Pages
- 2255-2260
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2553238286
- Cited by
- 263
- References
- 7
- FWCI
- 5.99
- Type
- journal article
- Language
- en
- Open access
- closed
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- The paper
- Dong, R., Zheng, Z., Tranca, D. C., Zhang, J., Chandrasekhar, N., Liu, S., Zhuang, X., Seifert, G., & Feng, X. (2017). Immobilizing Molecular Metal Dithiolene–Diamine Complexes on 2D Metal–Organic Frameworks for Electrocatalytic H2 Production. Chemistry – A European Journal. https://doi.org/10.1002/chem.201605337
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