The DOI matches its Crossref record.
Making Nanosized CHA Zeolites with Controlled Al Distribution for Optimizing Methanol‐to‐Olefin Performance
Open accessAbstract
From theoretical calculations and a rational synthesis methodology, it has been possible to prepare nanocrystalline (60–80 nm) chabazite with an optimized framework Al distribution that has a positive impact on its catalytic properties. This is exemplified for the methanol‐to‐olefin (MTO) process. The nanosized material with the predicted Al distribution maximizes the formation of the required MTO hydrocarbon pool intermediates, while better precluding excessive diffusion pathways that favor the rapid catalyst deactivation by coke formation.
Overview
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The reduction of average crystal size of a zeolite is mostly done directly by hydrothermal synthesis promoting nucleation versus crystal growth.
“The reduction of average crystal size of a zeolite is mostly done directly by hydrothermal synthesis promoting nucleation versus crystal growth,99,134−138 although other nonconventional methods have been applied as well.139”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [138]
The charge density, size, and concentration of the SDA play an important role in controlling Al distribution.
“The charge density, size, and concentration of the SDA play an important role in this sense.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [138]
Al distribution in the zeolite framework can be controlled by modifying the synthesis conditions.
“It has been found that selectivity in many acid-catalyzed reactions by Al-containing zeolites strongly depends on the Al distribution in the zeolite framework, which can be controlled by modifying the synthesis conditions.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [138]
Selectivity in many acid-catalyzed reactions by Al-containing zeolites strongly depends on the Al distribution in the zeolite framework.
“It has been found that selectivity in many acid-catalyzed reactions by Al-containing zeolites strongly depends on the Al distribution in the zeolite framework, which can be controlled by modifying the synthesis conditions.”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [138]
Citations
Cites
No references could be resolved yet.
Research works printed but not linked: 19
- 10.1021/acscatal.5b00007 · DOI
- 10.1002/anie.201103657 · DOI
- 10.1002/ange.201103657 · DOI
- 10.1021/cm4015095 · DOI · Paper page
- 10.1016/S1387-1811(98)00319-9 · DOI
- 10.1016/S1387-1811(98)00325-4 · DOI
- 10.1002/cphc.201201023 · DOI
- 10.1007/s11244-005-3798-0 · DOI
- 10.1007/s11244-008-9158-0 · DOI
- 10.1021/ja00332a063 · DOI
- 10.1016/j.cattod.2005.07.178 · DOI
- 10.1016/j.micromeso.2016.01.045 · DOI
- 10.1039/c2cc33994c · DOI
- 10.1016/j.jcat.2012.10.029 · DOI
- 10.1039/C6CY00433D · DOI
- 10.1039/C6CC00201C · DOI
- 10.1021/acs.chemmater.6b00181 · DOI
- 10.1021/acscatal.7b01273 · DOI
- 10.1039/C5CC09719C · DOI
Cited by
Sorted by citations
Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126
A priori control of zeolite phase competition and intergrowth with high-throughput simulations
Schwalbe-Koda, D., Kwon, S., Paris, C., Bello-Jurado, E., Jensen, Z., Olivetti, E., Willhammar, T., Corma, A., Román-Leshkov, Y., Moliner, M., et al. (2021) · Science · doi:10.1126/science.abh3350 · Cited by 175
Self-citation
Metadata
- Authors
- Gallego, E. M., Li, C., Paris, C., Martín, N., Martínez‐Triguero, J., Boronat, M., Moliner, M., & Corma, A.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Instituto de Tecnología Química Universitat Politècnica de València-Consejo Superior, de Investigaciones Científicas Avenida de los Naranjos s/n 46022 València Spain
- Corresponding author
- Moliner, Manuel
- Corma, Avelino
- Venue
- Chemistry – A European Journal
- Publisher
- Wiley
- Published
- 2018-09-10
- Volume
- 24
- Issue
- 55
- Pages
- 14631-14635
- ISSN
- 0947-6539 (ISSN-L)
- 1521-3765
- OpenAlex
- W2886834445
- Cited by
- 73
- References
- 0
- Citations by year
- 2026: 3 · 2025: 6 · 2024: 5 · 2023: 13 · 2022: 13 · 2021: 12 · 2020: 16 · 2019: 5
- FWCI
- 3.01
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- Locations
- Chemistry - A European Journal (publishedVersion)
- PubMed (publishedVersion)
- DIGITAL.CSIC (Spanish National Research Council (CSIC)) (submittedVersion)
- RiuNet (Universitat Politècnica de València) (submittedVersion, cc-by-nc-nd)
- Zenodo (CERN European Organization for Nuclear Research) (submittedVersion, other-oa)
- Funders
- H2020 European Research Council (ERC-AdG-2014-671093)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemical Engineering › Catalysis › Catalysis and Oxidation Reactions
- Physical Sciences › Chemical Engineering › Catalysis › Catalysts for Methane Reforming
- Keywords
- chabazite zeolite, zeolite nanocrystals, aluminum distribution, methanol-to-olefins, zeolite synthesis, catalyst deactivation, coke formation, hydrocarbon intermediates, diffusion paths, zeolite structure
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
