Synthesis Strategies for Preparing Useful Small Pore Zeolites and Zeotypes for Gas Separations and Catalysis
Open accessAbstract
In the last years, the preparation of small pore zeolites, especially those presenting large cavities in their structure, have received much attention because they have shown excellent application in catalysis (such as methanol-to-olefins or selective catalytic reduction of NOx) and gas separations. In the present review, we will focus on the diverse synthetic routes followed to direct the crystallization of small pore zeolites and, on the other hand, the most outstanding applications of those small pore microporous materials.
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Reducing the amount of OSDA needed for zeolite synthesis would lower the environmental impact and cost of zeolite production, easing scale-up requirements.
“By doing so, the environmental impact of zeolite production as well as its cost would be lower, thus easing the requirements for scale-up.48,103”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [103]
New zeolites can be obtained by topotactic transformation in which labile atoms are removed by mild secondary treatments followed by condensation or pillarization of remaining zeolitic layers, providing new fully ordered microporous materials.
“On the other hand, new zeolites can be obtained by topotactic transformation in which some labile atoms are removed by mild secondary treatments followed by condensation or pillarization of the remaining zeolitic layers, providing new fully ordered microporous materials.72,103,124−126”
From Zeolites in Adsorption Processes: State of the Art and Future Prospects (2022) · cites this paper as [103]
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Zeolites in Adsorption Processes: State of the Art and Future Prospects
Pérez-Botella, E., Valencia, S., & Rey, F. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.2c00140 · Cited by 1,126 · see citing works
Engineering Zeolites for Catalytic Cracking to Light Olefins
Blay, V., Louis, B., Miravalles, R., Yokoi, T., Peccatiello, K. A., Clough, M., & Yilmaz, B. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b02011 · Cited by 277 · see citing works
Synthesis of Zeolites via Interzeolite Transformations without Organic Structure-Directing Agents
Goel, S., Zones, S. I., & Iglesia, E. (2015) · Chemistry of Materials · doi:10.1021/cm504510f · Cited by 209 · see citing works
Georgieva, V. M., Bruce, E. L., Verbraeken, M. C., Scott, A. R., Casteel, W. J., Brandani, S., & Wright, P. A. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b05539 · Cited by 147 · see citing works
- Authors
- Moliner, M., Martínez, C., & Corma, A.
- Affiliations
- Consejo Superior de Investigaciones Científicas (ES)
- Instituto de Tecnología Química (UPV-CSIC), Universidad Politécnica de Valencia, Consejo Superior de Investigaciones Científicas, Valencia, 46022, Spain
- Corresponding author
- Corma, Avelino
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-07-03
- Volume
- 26
- Issue
- 1
- Pages
- 246-258
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2332908243
- Cited by
- 311
- References
- 3
- Citations by year
- 2026: 8 · 2025: 18 · 2024: 16 · 2023: 16 · 2022: 40 · 2021: 26 · 2020: 32 · 2019: 23 · 2018: 32 · 2017: 33 · 2016: 23 · 2015: 29 · 2014: 14 · 2013: 1
- FWCI
- 10.52
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- cc-by-nc-nd
- Locations
- Chemistry of Materials (publishedVersion)
- RiuNet (Universitat Politècnica de València) (submittedVersion, cc-by-nc-nd)
- Topics
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Physical Sciences › Engineering › Mechanical Engineering › Membrane Separation and Gas Transport
- Keywords
- small-pore zeolites, zeotypes, zeolite synthesis, crystallization, gas separation, catalysis, methanol-to-olefins, selective catalytic reduction of NOx, microporous materials
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