ChemInform Abstract: Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)‐Catalyzed Annulation of Indoles.
Abstract
Various title compounds are prepared with high levels of enantioinduction via a formal [3 + 2] cycloaddition of C(3)‐substituted indoles and 4‐aryl‐1‐sulfonyl‐1,2,3‐triazoles as carbenoid precursors.
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Rh is a platinum-group metal with impressive catalytic activity and has been widely utilized in electrocatalysis, photocatalysis, coupling, oxidation, hydrogenation, etc.
“Rhodium (Rh), platinum-group metal, which exhibits impressive catalytic activity, has been widely utilized in electrocatalysis [8,9], photocatalysis [10], coupling [11], oxidation [12], hydrogenation [13] and so on.”
Cites
Catalytic Asymmetric Synthesis of Pyrroloindolines via a Rhodium(II)-Catalyzed Annulation of Indoles
Spangler, J. E., & Davies, H. M. L. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4025337 · Cited by 366 · see citing works
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Lu, R., Sam, D. K., Gong, S., Wang, W., Ge, D., Liu, J., Zhang, Y., Gao, M., & Lv, X. (2022) · Diamond and Related Materials · doi:10.1016/j.diamond.2022.109292 · Cited by 7 · see citing works
- Authors
- Spangler, J. E., & Davies, H. M. L.
- Affiliations
- Emory University (US)
- ORCID
- Davies, Huw M. L.
- Venue
- ChemInform
- Publisher
- Wiley
- Published
- 2013-09-19
- Volume
- 44
- Issue
- 41
- ISSN
- 0009-2975 (ISSN-L)
- 0931-7597
- 1522-2667
- OpenAlex
- W2949369063
- Cited by
- 0
- References
- 1
- FWCI
- 0.00
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ChemInform (publishedVersion)
- Topics
- Physical Sciences › Chemistry › Organic Chemistry › Cyclopropane Reaction Mechanisms
- Physical Sciences › Chemistry › Organic Chemistry › Asymmetric Synthesis and Catalysis
- Physical Sciences › Chemistry › Organic Chemistry › Synthesis of Indole Derivatives
- Keywords
- pyrroloindolines, rhodium(II) catalysis, asymmetric synthesis, indole annulation, [3+2] cycloaddition, 1,2,3-triazoles, enantioinduction
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