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A Topological Analysis of the Electron Density in Anion–π Interactions
Abstract
Novel nonbonding interaction: The “atoms in molecules” (AIM) and the molecular interaction potential with polarization (MIPp) tools are successfully used i) to predict the energetic characteristics of π complexes of the chloride anion with electron-deficient aromatic rings (see graphic), which have a positive quadrupole moment and ii) to analyze the physical nature of this novel nonbonding interaction in detail.
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Citations
Cited by
Aromatic Rings in Chemical and Biological Recognition: Energetics and Structures
Salonen, L. M., Ellermann, M., & Diederich, F. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007560 · Cited by 1,539
The Bright Future of Unconventional σ/π‐Hole Interactions
Bauzá, A., Mooibroek, T. J., & Frontera, A. (2015) · ChemPhysChem · doi:10.1002/cphc.201500314 · Cited by 710
Self-citationLone Pair−Aromatic Interactions: To Stabilize or Not to Stabilize
Egli, M., & Sarkhel, S. (2007) · Accounts of Chemical Research · doi:10.1021/ar068174u · Cited by 587
Philip, V., Harris, J., Adams, R., Nguyen, D., Spiers, J., Baudry, J., Howell, E. E., & Hinde, R. J. (2011) · Biochemistry · doi:10.1021/bi200066k · Cited by 109
Metadata
- Authors
- Garau, C., Frontera, A., Quiñonero, D., Ballester, P., Costa, A., & Deyà, P. M.
- Venue
- ChemPhysChem
- Publisher
- Wiley
- Published
- 2003-12-08
- Volume
- 4
- Issue
- 12
- Pages
- 1344-1348
- ISSN
- 1439-4235 (ISSN-L)
- 1439-7641
- OpenAlex
- W2037155785
- Cited by
- 201
- References
- 0
- FWCI
- 6.96
- Type
- journal article
- Language
- en
- Open access
- closed
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- Garau, C., Frontera, A., Quiñonero, D., Ballester, P., Costa, A., & Deyà, P. M. (2003). A Topological Analysis of the Electron Density in Anion–π Interactions. ChemPhysChem. https://doi.org/10.1002/cphc.200300886
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