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Model for the Conductivity of Ionic Liquids Based on an Infinite Dilution of Holes
Abstract
Charge transport in an ambient-temperature ionic liquid is limited by the mobility of suitably sized voids into which ions can migrate (see figure). This allows conductivity data to be simply analyzed by using the Stokes–Einstein equation. The mechanism of charge transport is contrasted with that in high-temperature molten salts, which is different from that in low-temperature systems.
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Citations
Cited by
Deep Eutectic Solvents (DESs) and Their Applications
Smith, E. L., Abbott, A. P., & Ryder, K. S. (2014) · Chemical Reviews · doi:10.1021/cr300162p · Cited by 7,378
Self-citationDeep eutectic solvents: A review of fundamentals and applications
Hansen, B. B., Spittle, S., Chen, B., Poe, D., Zhang, Y., Klein, J. M., Horton, A., Adhikari, L., Zelovich, T., Doherty, B. W., et al. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00385 · Cited by 3,422
Design of improved deep eutectic solvents using hole theory
Abbott, A. P., Capper, G., & Gray, S. (2006) · ChemPhysChem · doi:10.1002/cphc.200500489 · Cited by 545
Self-citationImanishi, A., Okamura, T., Ohashi, N., Nakamura, R., & Nakato, Y. (2007) · Journal of the American Chemical Society · doi:10.1021/ja073206+ · Cited by 254
Metadata
- Authors
- Abbott, A. P.
- Venue
- ChemPhysChem
- Publisher
- Wiley
- Published
- 2005-12-06
- Volume
- 6
- Issue
- 12
- Pages
- 2502-2505
- ISSN
- 1439-4235 (ISSN-L)
- 1439-7641
- OpenAlex
- W2115482446
- Cited by
- 184
- References
- 0
- FWCI
- 2.86
- Type
- journal article
- Language
- en
- Open access
- closed
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