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Novel Polymeric Materials from Vegetable Oils and Vinyl Monomers: Preparation, Properties, and Applications
Abstract
Veggie‐based products: Vegetable‐oil‐based polymeric materials, prepared by free radical, cationic, and olefin metathesis polymerizations, range from soft rubbers to ductile or rigid plastics, and to high‐performance biocomposites and nanocomposites. They display a wide range of thermophysical and mechanical properties and may find promising applications as alternatives to petroleum‐based polymers.magnified image Vegetable oils are considered to be among the most promising renewable raw materials for polymers, because of their ready availability, inherent biodegradability, and their many versatile applications. Research on and development of vegetable oil based polymeric materials, including thermosetting resins, biocomposites, and nanocomposites, have attracted increasing attention in recent years. This Minireview focuses on the latest developments in the preparation, properties, and applications of vegetable oil based polymeric materials obtained by free radical, cationic, and olefin metathesis polymerizations. The novel vegetable oil based polymeric materials obtained range from soft rubbery materials to ductile or rigid plastics and to high‐performance biocomposites and nanocomposites. These vegetable oil based polymeric materials display a wide range of thermophysical and mechanical properties and should find useful applications as alternatives to their petroleum‐based counterparts.
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Cites
Lendlein, A., & Kelch, S. (2002) · Kirk-Othmer Encyclopedia of Chemical Technology · doi:10.1002/0471238961.1908011612051404.a01 · Cited by 2,566
Natural Fibers, Biopolymers, and Biocomposites
(2005) · CRC Press eBooks · doi:10.1201/9780203508206 · Cited by 1,617
Plant oil renewable resources as green alternatives in polymer science
Meier, M. A. R., Metzger, J. O., & Schubert, U. S. (2007) · Chemical Society Reviews · doi:10.1039/b703294c · Cited by 1,487
Silver-nanoparticle-embedded antimicrobial paints based on vegetable oil
Kumar, A., Vemula, P. K., Ajayan, P. M., & John, G. (2008) · Nature Materials · doi:10.1038/nmat2099 · Cited by 1,033
Polymers from Renewable Resources: A Perspective for a Special Issue of Polymer Reviews
Williams, C., & Hillmyer, M. (2008) · Polymer Reviews · doi:10.1080/15583720701834133 · Cited by 977
Natural Fibers, Biopolymers, and Biocomposites: An Introduction
Mohanty, A., Misra, M., Drzal, L., Selke, S., Harte, B., & Hinrichsen, G. (2005) · Natural Fibers, Biopolymers, and Biocomposites · doi:10.1201/9780203508206.ch1 · Cited by 976
Polyurethanes from Vegetable Oils
Petrović, Z. S. (2008) · Polymer Reviews · doi:10.1080/15583720701834224 · Cited by 929
Polymers from triglyceride oils
Seniha Güner, F., Yağcı, Y., & Tuncer Erciyes, A. (2006) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2006.07.001 · Cited by 785
Silver bromide nanoparticle/polymer composites: dual action tunable antimicrobial materials
Sambhy, V., MacBride, M. M., Peterson, B. R., & Sen, A. (2006) · Journal of the American Chemical Society · doi:10.1021/ja061442z · Cited by 748
Behl, M., & Lendlein, A. (2011) · Kirk-Othmer Encyclopedia of Chemical Technology · doi:10.1002/0471238961.1908011612051404.a01.pub2 · Cited by 663
Development and application of triglyceride‐based polymers and composites
Khot, S. N., Lascala, J. J., Can, E., Morye, S. S., Williams, G. I., Palmese, G. R., Kusefoglu, S. H., & Wool, R. P. (2001) · Journal of Applied Polymer Science · doi:10.1002/app.1897 · Cited by 647
Natural fiber composites with plant oil-based resin
O'Donnell, A., Dweib, M. A., & Wool, R. P. (2004) · Composites Science and Technology · doi:10.1016/j.compscitech.2003.09.024 · Cited by 443
Olefin Disproportionation. A New Catalytic Process
Banks, R. L., & Bailey, G. C. (1964) · I&EC Product Research and Development · doi:10.1021/i360011a002 · Cited by 385
Effect of structure on properties of polyols and polyurethanes based on different vegetable oils
Zlatanić, A., Lava, C., Zhang, W., & Petrović, Z. S. (2004) · Journal of Polymer Science Part B: Polymer Physics · doi:10.1002/polb.10737 · Cited by 378
Lu, Y., & Larock, R. C. (2008) · Biomacromolecules · doi:10.1021/bm801030g · Cited by 377
Self-citationStrong, Tailored, Biocompatible Shape‐Memory Polymer Networks
Yakacki, C. M., Shandas, R., Safranski, D., Ortega, A. M., Sassaman, K., & Gall, K. (2008) · Advanced Functional Materials · doi:10.1002/adfm.200701049 · Cited by 368
10 Years after Rio-Concepts on the Contribution of Chemistry to a Sustainable Development
Eissen, M., Metzger, J. O., Schmidt, E., & Schneidewind, U. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020201)41:3<414::aid-anie414>3.0.co;2-n · Cited by 350
Mai, Y.-W., & Yu, Z.-Z. (2006) · Woodhead Publishing Limited eBooks · doi:10.1533/9781845691127 · Cited by 336
Composites from Natural Fibers and Soy Oil Resins
Williams, G. I., & Wool, R. P. (2000) · Applied Composite Materials · doi:10.1023/a:1026583404899 · Cited by 335
All natural composite sandwich beams for structural applications
Dweib, M. A., Hu, B., O'Donnell, A. J., et al. (2003) · Composite Structures · doi:10.1016/s0263-8223(03)00143-0 · Cited by 315
Mechanism of Ene Reactions of Singlet Oxygen. A Two-Step No-Intermediate Mechanism
Singleton, D. A., Hang, C., Szymanski, M. J., Meyer, M. P., Leach, A. G., Kuwata, K. T., Chen, J. S., Greer, A., Foote, C. S., & Houk, K. N. (2003) · Journal of the American Chemical Society · doi:10.1021/ja027225p · Cited by 287
Puskas, J. E., & Kaszas, G. (2003) · Encyclopedia of Polymer Science and Technology · doi:10.1002/0471440264.pst040 · Cited by 272
Bio-Based Polymers and Composites
(2005) · Elsevier eBooks · doi:10.1016/b978-0-12-763952-9.x5000-x · Cited by 266
New sheet molding compound resins from soybean oil. I. Synthesis and characterization
Lu, J., Khot, S., & Wool, R. P. (2005) · Polymer · doi:10.1016/j.polymer.2004.10.060 · Cited by 249
Drier influence on the curing of linseed oil
Mallégol, J., Lemaire, J., & Gardette, J.-L. (2000) · Progress in Organic Coatings · doi:10.1016/s0300-9440(00)00126-0 · Cited by 241
Li, F., Hanson, M. V., & Larock, R. C. (2001) · Polymer · doi:10.1016/s0032-3861(00)00546-2 · Cited by 227
Self-citationSynthesis and Thermal Properties of Epoxidized Vegetable Oil
Park, S., Jin, F., & Lee, J. (2004) · Macromolecular Rapid Communications · doi:10.1002/marc.200300191 · Cited by 211
Development of a bio‐based composite material from soybean oil and keratin fibers
Hong, C. K., & Wool, R. P. (2005) · Journal of Applied Polymer Science · doi:10.1002/app.21044 · Cited by 208
Property analysis of triglyceride-based thermosets
La Scala, J., & Wool, R. P. (2005) · Polymer · doi:10.1016/j.polymer.2004.11.002 · Cited by 203
Lu, Y., & Larock, R. C. (2007) · Biomacromolecules · doi:10.1021/bm700522z · Cited by 198
Self-citationHydroxylation of Monounsaturated Fatty Materials with Hydrogen Peroxide
Swern, D., Billen, G. N., Findley, T. W., & Scanlan, J. T. (1945) · Journal of the American Chemical Society · doi:10.1021/ja01226a050 · Cited by 183
Andjelkovic, D. D., Valverde, M., Henna, P., Li, F., & Larock, R. C. (2005) · Polymer · doi:10.1016/j.polymer.2005.08.022 · Cited by 181
Self-citationLi, F., & Larock, R. C. (2003) · Biomacromolecules · doi:10.1021/bm034049j · Cited by 178
Self-citationPark, S., Jin, F., & Lee, J. (2004) · Macromolecular Chemistry and Physics · doi:10.1002/macp.200400214 · Cited by 177
Metathesis as a versatile tool in oleochemistry
Rybak, A., Fokou, P. A., & Meier, M. A. R. (2008) · European Journal of Lipid Science and Technology · doi:10.1002/ejlt.200800027 · Cited by 174
Effect of different isocyanates on the properties of soy‐based polyurethanes
Javni, I., Zhang, W., & Petrovìć, Z. S. (2003) · Journal of Applied Polymer Science · doi:10.1002/app.11966 · Cited by 163
Lu, Y., Tighzert, L., Dole, P., & Erre, D. (2005) · Polymer · doi:10.1016/j.polymer.2005.08.026 · Cited by 161
Self-citationStructure and properties of polyurethanes based on halogenated and nonhalogenated soy-polyols
Petrovi?, Z. S., Guo, A., & Zhang, W. (2000) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/1099-0518(20001115)38:22<4062::aid-pola60>3.0.co;2-l · Cited by 159
Can, E., Küsefoǧlu, S. H., & Wool, R. P. (2001) · Journal of Applied Polymer Science · doi:10.1002/app.1414 · Cited by 150
Bio-based composite roof structure: Manufacturing and processing issues
Dweib, M. A., Hu, B., Shenton, H. W., & Wool, R. P. (2005) · Composite Structures · doi:10.1016/j.compstruct.2005.04.018 · Cited by 133
Rybak, A., & Meier, M. A. R. (2008) · ChemSusChem · doi:10.1002/cssc.200800047 · Cited by 129
New soybean oil-styrene-divinylbenzene thermosetting copolymers. I. Synthesis and characterization
Li, F., & Larock, R. C. (2001) · Journal of Applied Polymer Science · doi:10.1002/1097-4628(20010425)80:4<658::aid-app1142>3.0.co;2-d · Cited by 128
Self-citationMoisture diffusion in polyester–woodflour composites
Marcovich, N. E., Reboredo, M. M., & Aranguren, M. I. (1999) · Polymer · doi:10.1016/s0032-3861(99)00093-2 · Cited by 125
Lligadas, G., Ronda, J. C., Galià, M., & Cádiz, V. (2007) · Biomacromolecules · doi:10.1021/bm060977h · Cited by 125
Soybean‐ and castor‐oil‐based thermosetting polymers: Mechanical properties
Can, E., Wool, R. P., & Küsefoǧlu, S. H. (2006) · Journal of Applied Polymer Science · doi:10.1002/app.24423 · Cited by 123
New soybean oil–styrene–divinylbenzene thermosetting copolymers. v. shape memory effect
Li, F., & Larock, R. C. (2002) · Journal of Applied Polymer Science · doi:10.1002/app.10493 · Cited by 117
Self-citationMaterials from Vegetable Oils: Major Sources, Properties and Applications
Belgacem, M. N., & Gandini, A. (2008) · Elsevier eBooks · doi:10.1016/b978-0-08-045316-3.00003-x · Cited by 116
Innovative plasticized starch films modified with waterborne polyurethane from renewable resources
Lu, Y., Tighzert, L., Berzin, F., & Rondot, S. (2005) · Carbohydrate Polymers · doi:10.1016/j.carbpol.2005.04.013 · Cited by 115
Self-citationLarock, R. C., Dong, X., Chung, S., Reddy, C. K., & Ehlers, L. E. (2001) · Journal of the American Oil Chemists Society · doi:10.1007/s11746-001-0284-1 · Cited by 113
Self-citationNatural Oil-Based Polymers: Opportunities and Challenges
Nayak, P. L. (2000) · Journal of macromolecular science. Part C, Reviews in macromolecular chemistry and physics/Journal of macromolecular science. Reviews in macromolecular chemistry and physics · doi:10.1081/mc-100100576 · Cited by 105
Soybean and castor oil based monomers: Synthesis and copolymerization with styrene
Can, E., Wool, R. P., & Küsefoǧlu, S. H. (2006) · Journal of Applied Polymer Science · doi:10.1002/app.24548 · Cited by 102
Morye, S. S., & Wool, R. P. (2005) · Polymer Composites · doi:10.1002/pc.20099 · Cited by 99
New soybean oil-styrene-divinylbenzene thermosetting copolymers. III. Tensile stress-strain behavior
Li, F., & Larock, R. C. (2000) · Journal of Polymer Science Part B Polymer Physics · Cited by 98
Self-citationKundu, P. P., & Larock, R. C. (2005) · Biomacromolecules · doi:10.1021/bm049429z · Cited by 97
Self-citationRenewable bioresources : scope and modification for non-food applications
Stevens, C. V., & Verhé, R. (2004) · Ghent University Academic Bibliography (Ghent University) · Cited by 93
Andjelkovic, D. D., & Larock, R. C. (2006) · Biomacromolecules · doi:10.1021/bm050787r · Cited by 91
Self-citationDevelopment of novel phosphorus‐containing epoxy resins from renewable resources
Lligadas, G., Ronda, J. C., Galià, M., & Cádiz, V. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21794 · Cited by 85
Eren, T., & Küsefoǧlu, S. H. (2003) · Journal of Applied Polymer Science · doi:10.1002/app.13471 · Cited by 82
Can, E., Küsefoǧlu, S. H., & Wool, R. P. (2001) · Journal of Applied Polymer Science · doi:10.1002/app.2277 · Cited by 81
Henna, P. H., & Larock, R. C. (2007) · Macromolecular Materials and Engineering · doi:10.1002/mame.200700209 · Cited by 80
Self-citationNew soybean oil-styrene-divinylbenzene thermosetting copolymers. II. Dynamic mechanical properties
Li, F., & Larock, R. C. (2000) · Journal of Polymer Science Part B Polymer Physics · Cited by 78
Self-citationFokou, P. A., & Meier, M. A. R. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800365 · Cited by 77
Lendlein, A., & Kelch, S. (2002) · Angewandte Chemie · doi:10.1002/1521-3757(20020617)114:12<2138::aid-ange2138>3.0.co;2-t · Cited by 77
Mechanical properties of linseed oil monoglyceride maleate/styrene copolymers
Mosiewicki, M. A., Aranguren, M. I., & Borrajo, J. (2005) · Journal of Applied Polymer Science · doi:10.1002/app.21790 · Cited by 76
Çakmaklı, B., Hazer, B., Tekin, İ. Ö., & Cömert, F. (2005) · Biomacromolecules · doi:10.1021/bm050063f · Cited by 75
Lligadas, G., Ronda, J. C., Galià, M., & Cádiz, V. (2006) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.21691 · Cited by 74
Synthesis and Characterization of Polymeric Linseed Oil Grafted Methyl Methacrylate or Styrene
Çakmaklı, B., Hazer, B., Tekin, İ. Ö., Kızgut, S., Koksal, M., & Menceloǵlu, Y. Z. (2004) · Macromolecular Bioscience · doi:10.1002/mabi.200300117 · Cited by 71
New soybean oil‐Styrene‐Divinylbenzene thermosetting copolymers—IV. Good damping properties
Li, F., & Larock, R. C. (2002) · Polymers for Advanced Technologies · doi:10.1002/pat.206 · Cited by 69
Self-citationHenna, P. H., Kessler, M. R., & Larock, R. C. (2008) · Macromolecular Materials and Engineering · doi:10.1002/mame.200800202 · Cited by 64
Self-citationRuthenium‐catalyzed metathesis of vegetable oils
Refvik, M. D., Larock, R. C., & Tian, Q. (1999) · Journal of the American Oil Chemists Society · doi:10.1007/s11746-999-0053-z · Cited by 64
Self-citationBiobased thermosets from the free‐radical copolymerization of conjugated linseed oil
Henna, P. H., Andjelkovic, D. D., Kundu, P. P., & Larock, R. C. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.25788 · Cited by 64
Self-citationModel studies and the ADMET polymerization of soybean oil
Tian, Q., & Larock, R. C. (2002) · Journal of the American Oil Chemists Society · doi:10.1007/s11746-002-0509-3 · Cited by 61
Self-citationRing‐opening metathesis polymerization of a modified linseed oil with varying levels of crosslinking
Mauldin, T. C., Haman, K. J., Sheng, X., Henna, P. H., Larock, R. C., & Kessler, M. R. (2008) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.22995 · Cited by 60
Self-citationValverde, M., Andjelkovic, D. D., Kundu, P. P., & Larock, R. C. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.27080 · Cited by 57
Self-citationMetathesis of fatty acid esters
Boelhouwer, C., & Mol, J. C. (1984) · Journal of the American Oil Chemists Society · doi:10.1007/bf02678808 · Cited by 55
The Chemistry of Oils and Fats
Marangoni, A. G. (2005) · Trends in Food Science & Technology · doi:10.1016/j.tifs.2005.07.005 · Cited by 49
Novel Polymeric Materials from Biological Oils
Li, F., & Larock, R. C. (2002) · Journal of Polymers and the Environment · doi:10.1023/a:1021026224642 · Cited by 44
Self-citationLu, Y., & Larock, R. C. (2007) · Macromolecular Materials and Engineering · doi:10.1002/mame.200700150 · Cited by 37
Self-citationÇakmaklı, B., Hazer, B., Açıkgöz, Ş., Can, M., & Cömert, F. (2007) · Journal of Applied Polymer Science · doi:10.1002/app.26397 · Cited by 33
Marks, D. W., Li, F., Pacha, C. M., et al. (2001) · Journal of Applied Polymer Science · doi:10.1002/app.1632 · Cited by 27
Li, F., & Larock, R. C. (2003) · Polymer International · doi:10.1002/pi.1060 · Cited by 27
Self-citationTurley, D. (2008) · Wiley eBooks · doi:10.1002/9780470697474.ch2 · Cited by 21
Keleş, E., & Hazer, B. (2008) · Macromolecular Symposia · doi:10.1002/masy.200850919 · Cited by 15
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Metadata
- Authors
- Lu, Y., & Larock, R. C.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2009-02-17
- Volume
- 2
- Issue
- 2
- Pages
- 136-147
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2109114462
- Cited by
- 324
- References
- 83
- FWCI
- 17.84
- Type
- journal article
- Language
- en
- Open access
- closed
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