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Polyurethanes from Vegetable Oils
Abstract
Vegetable oils are excellent but very heterogeneous renewable raw materials for polyols and polyurethanes. This review discusses the specific nature of vegetable oils and the effect of their structures on the structure of polyols and polyurethanes. One section is dedicated to polyols for rigid and flexible foams and methods of their preparation such as direct oxidation of oils, epoxidation followed by ring opening, hydroformylation, ozonolysis, and transesterification. The next section deals with preparation and structure‐property relationships in polyurethanes from different groups of polyols, different isocyanates, and different degrees of crosslinking. The final section covers the environmental aspects of bio‐based polyurethanes, i.e., thermal stability, hydrolytic stability, and some aspects of biodegradability.
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Citations
Cited by
Conversion of Biomass into Chemicals over Metal Catalysts
Besson, M., Gallezot, P., & Pinel, C. (2014) · Chemical Reviews · doi:10.1021/cr4002269 · Cited by 1,780
Vegetable oil-based polymeric materials: synthesis, properties, and applications
Xia, Y., & Larock, R. C. (2010) · Green Chemistry · doi:10.1039/c0gc00264j · Cited by 864
Degradation and stabilization of polyurethane elastomers
Xie, F., Zhang, T., Bryant, P., Kurusingal, V., Colwell, J. M., & Laycock, B. (2019) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.12.003 · Cited by 722
Vegetable-oil-based polymers as future polymeric biomaterials
Miao, S., Wang, P., Su, Z., & Zhang, S. (2014) · Acta Biomaterialia · doi:10.1016/j.actbio.2013.08.040 · Cited by 573
Stempfle, F., Ortmann, P., & Mecking, S. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00705 · Cited by 397
Metadata
- Authors
- Petrović, Z. S.
- Venue
- Polymer Reviews
- Publisher
- Informa UK Limited
- Published
- 2008-02
- Volume
- 48
- Issue
- 1
- Pages
- 109-155
- ISSN
- 0736-6574 (ISSN-L)
- 1558-3724
- 1558-3716
- OpenAlex
- W1997814023
- Cited by
- 929
- References
- 0
- FWCI
- 28.18
- Type
- journal article
- Language
- en
- Open access
- closed
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