The DOI matches its Crossref record; 52 of the 52 references it cites were found in a registry or an index.
Merging Sustainability with Organocatalysis in the Formation of Organic Carbonates by Using CO2 as a Feedstock
Abstract
The use of phenolic compounds as organocatalysts is discussed in the context of the atom‐efficient cycloaddition of carbon dioxide to epoxides, forming useful cyclic organic carbonate products. The presence and cooperative nature of adjacent phenolic groups in the catalyst structure results in significantly enhanced catalytic efficiencies, allowing these CO 2 fixation reactions to operate efficiently under virtually ambient conditions. The cooperative effect has also been studied by computational methods. Furthermore, when the cycloaddition reactions are carried out on a larger scale and under solvent‐free conditions, further enhancements in activity are observed, combined with the advantageous requirement of reduced loadings of the binary organocatalyst system. The reported system is among one of the mildest and most effective metal‐free catalysts for this conversion and contributes to a much more sustainable development of organic carbonate production; this feature has not been the main focus of previous contributions in this area.
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Cites
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Cited by
Sustainable conversion of carbon dioxide: the advent of organocatalysis
Fiorani, G., Guo, W., & Kleij, A. W. (2015) · Green Chemistry · doi:10.1039/c4gc01959h · Cited by 658
Self-citationAlves, M., Grignard, B., Mereau, R., Jerome, C., Tassaing, T., & Detrembleur, C. (2017) · Catalysis Science & Technology · doi:10.1039/c7cy00438a · Cited by 531
Castro‐Gómez, F., Salassa, G., Kleij, A. W., & Bo, C. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201203985 · Cited by 339
Self-citationRecent advances in the synthesis of cyclic carbonates via CO2 cycloaddition to epoxides
Rehman, A., Saleem, F., Javed, F., Ikhlaq, A., Ahmad, S. W., & Harvey, A. (2021) · Journal of Environmental Chemical Engineering · doi:10.1016/j.jece.2021.105113 · Cited by 281
Green catalytic process for cyclic carbonate synthesis from carbon dioxide under mild conditions
Lang, X.-D., & He, L.-N. (2016) · The Chemical Record · doi:10.1002/tcr.201500293 · Cited by 122
Metadata
- Authors
- Whiteoak, C. J., Nova, A., Maseras, F., & Kleij, A. W.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2012-09-04
- Volume
- 5
- Issue
- 10
- Pages
- 2032-2038
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2130216417
- Cited by
- 339
- References
- 52
- FWCI
- 8.86
- Type
- journal article
- Language
- en
- Open access
- closed
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- Whiteoak, C. J., Nova, A., Maseras, F., & Kleij, A. W. (2012). Merging Sustainability with Organocatalysis in the Formation of Organic Carbonates by Using CO2 as a Feedstock. ChemSusChem. https://doi.org/10.1002/cssc.201200255
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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
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