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Cited by 331

The DOI matches its Crossref record; 1 of the 1 references it cites were found in a registry or an index.

Catalytic Transfer Hydrogenation/Hydrogenolysis for Reductive Upgrading of Furfural and 5‐(Hydroxymethyl)furfural

Scholz, David, Aellig, Christof, Hermans, Ive·2014·ChemSusChem

Abstract

The sequential transfer hydrogenation/hydrogenolysis of furfural and 5‐hydroxymethylfurfural to 2‐methylfuran and 2,5‐dimethylfuran was studied over in situ reduced, Fe 2 O 3‐supported Cu, Ni, and Pd catalysts, with 2‐propanol as hydrogen donor. The remarkable activity of Pd/Fe 2 O 3 in both transfer hydrogenation/hydrogenolysis is attributed to a strong metal–support interaction. Selectivity towards hydrogenation, hydrogenolysis, decarbonylation, and ring‐hydrogenation products is shown to strongly depend on the Pd loading. A significant enhancement in yield to 62 %, of 2‐methylfuran and 2‐methyltetrahydrofuran was observed under continuous flow conditions.

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Metadata

Authors
Scholz, D., Aellig, C., & Hermans, I.
Venue
ChemSusChem
Publisher
Wiley
Published
2013-11-13
Volume
7
Issue
1
Pages
268-275
ISSN
  • 1864-5631 (ISSN-L)
  • 1864-564X
OpenAlex
W1997739344
Cited by
331
References
1
FWCI
12.75
Type
journal article
Language
en
Open access
closed

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