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A Continuous Flow Strategy for the Coupled Transfer Hydrogenation and Etherification of 5‐(Hydroxymethyl)furfural using Lewis Acid Zeolites
Abstract
Hf‐, Zr‐ and Sn‐Beta zeolites effectively catalyze the coupled transfer hydrogenation and etherification of 5‐(hydroxymethyl)furfural with primary and secondary alcohols into 2,5‐bis(alkoxymethyl)furans, thus making it possible to generate renewable fuel additives without the use of external hydrogen sources or precious metals. Continuous flow experiments reveal nonuniform changes in the relative deactivation rates of the transfer hydrogenation and etherification reactions, which impact the observed product distribution over time. We found that the catalysts undergo a drastic deactivation for the etherification step while maintaining catalytic activity for the transfer hydrogenation step. 119 Sn and 29 Si magic angle spinning (MAS) NMR studies show that this deactivation can be attributed to changes in the local environment of the metal sites. Additional insights were gained by studying effects of various alcohols and water concentration on the catalytic reactivity.
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Cites
Catalytic conversion of biomass to biofuels
Alonso, D. M., Bond, J. Q., & Dumesic, J. A. (2010) · Green Chemistry · doi:10.1039/c004654j · Cited by 2,333
Furfural—A Promising Platform for Lignocellulosic Biofuels
Lange, J., van der Heide, E., van Buijtenen, J., & Price, R. (2012) · ChemSusChem · doi:10.1002/cssc.201100648 · Cited by 1,323
Cited by
New trends in tailoring active sites in zeolite-based catalysts
Shamzhy, M., Opanasenko, M., Concepción, P., & Martínez, A. (2019) · Chemical Society Reviews · doi:10.1039/c8cs00887f · Cited by 508
Hu, L., Lin, L., Wu, Z., Zhou, S., & Liu, S. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2017.02.042 · Cited by 445
Chen, S. S., Maneerung, T., Tsang, D. C. W., Ok, Y. S., & Wang, C.-H. (2017) · Chemical Engineering Journal · doi:10.1016/j.cej.2017.07.020 · Cited by 258
Influence of solvent structure and hydrogen bonding on catalysis at solid–liquid interfaces
Potts, D. S., Bregante, D. T., Adams, J. S., Torres, C., & Flaherty, D. W. (2021) · Chemical Society Reviews · doi:10.1039/d1cs00539a · Cited by 190
Analyses of Adsorption Behavior of CO2, CH4, and N2 on Different Types of BETA Zeolites
Henrique, A., Karimi, M., Silva, J. A. C., & Rodrigues, A. E. (2019) · Chemical Engineering & Technology · doi:10.1002/ceat.201800386 · Cited by 51
Metadata
- Authors
- Lewis, J. D., Van de Vyver, S., Crisci, A. J., Gunther, W. R., Michaelis, V. K., Griffin, R. G., & Román‐Leshkov, Y.
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2014-07-08
- Volume
- 7
- Issue
- 8
- Pages
- 2255-2265
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2080028927
- Cited by
- 207
- References
- 2
- FWCI
- 11.09
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: A Continuous Flow Strategy for the Coupled Transfer Hydrogenation and Etherification of 5‐(Hydroxymethyl)furfural using Lewis Acid Zeolites. https://app.cochat.ai/papers/10.1002/cssc.201402100
- The paper
- Lewis, J. D., Van de Vyver, S., Crisci, A. J., Gunther, W. R., Michaelis, V. K., Griffin, R. G., & Román‐Leshkov, Y. (2014). A Continuous Flow Strategy for the Coupled Transfer Hydrogenation and Etherification of 5‐(Hydroxymethyl)furfural using Lewis Acid Zeolites. ChemSusChem. https://doi.org/10.1002/cssc.201402100
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