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Cited by 57Electrocatalysts for Energy ConversionCO2 Reduction Techniques and CatalystsHydrogen Storage and Materials

Electrochemical Hydrogen Generation Technology: Challenges in Electrodes Materials for a Sustainable Energy

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Inocêncio, Carlos V. M., Holade, Yaovi, Morais, Claudia, Kokoh, K. Boniface, Napporn, Teko W.·2023·Electrochemical Science Advances
DOI 10.1002/elsa.202100206
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Abstract

Abstract Foresee advanced and innovative strategies is a key approach and constitutes a cornerstone for accessing clean, affordable, and reliable energy to satisfy the world's increasing prosperity and economic growth. To this end, hydrogen energy technologies parade as promising sustainable solutions to the looming energy crisis at either the small or large industrial scale, which will enable to reduce significantly our dependence on conventional energy sources based on fossil fuels without increasing atmospheric CO 2 levels. Water electrolysis with renewable energy is one of the best solutions to produce hydrogen without CO x (CO and CO 2 ) emissions. However, the practical realization of this elegant opportunity of paramount importance is facing several challenges, among which are: (i) the efficient design of cathode and anode catalytic materials exhibiting improved intrinsic and durable activity; (ii) the scale‐up of the system for the large‐scale hydrogen production through the electrochemical water splitting. This review puts these opportunities and challenges into a broad context, discusses the recent research and technological advances, and finally provides several pathways and guidelines that could inspire the development of groundbreaking electrochemical devices for hydrogen production. It also points out the materials design and preparation for the efficient electrochemical production of the molecular hydrogen in acidic and alkaline environments, from a simple electrolytic solution to the water splitting reaction, which is also considered in the process. Furthermore, the main technology keys for designing a reliable electrochemical system will be noticed.

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  • Even a 100% Faradaic-efficient rechargeable battery needs to be charged at a voltage higher than it generates when discharged.

    “In general, energy efficiency is impacted, since even a 100% Faradaic-efficient rechargeable battery needs to be charged at a voltage higher than it generates when discharged [75].”

    From Silica Aerogels as a Promising Vehicle for Effective Water Splitting for Hydrogen Production (2025) · cites this paper as [75]

    Section 2.2.3 (p. 7) defines Faradaic efficiency for hydrogen production, while Section 1 (p. 4) says water electrolysis requires an applied voltage above its thermodynamic potential. Neither passage addresses the charging and discharging voltages of a rechargeable battery; searches for battery charging and discharge found no passage that does. (LLM, conf=0.72)

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Authors
Inocêncio, C. V. M., Holade, Y., Morais, C., Kokoh, K. B., & Napporn, T. W.
Affiliations
  • Centre National de la Recherche Scientifique (FR)
  • École Nationale Supérieure de Chimie de Montpellier (FR)
Corresponding author
Napporn, Teko W.
ORCID
Venue
Electrochemical Science Advances
Publisher
Wiley
Published
2022-03-16
Volume
3
Issue
3
Pages
e2100206
ISSN
2698-5977 (ISSN-L)
DOI
10.1002/elsa.202100206
OpenAlex
W4221113833
Cited by
57
References
197
Citations by year
2026: 8 · 2025: 20 · 2024: 19 · 2023: 4 · 2022: 6
FWCI
2.21
Type
journal article
Language
en
Open access
Licence
Locations
  • Electrochemical Science Advances (publishedVersion, cc-by-nc-nd)
  • HAL (submittedVersion, cc-by-nc-nd)
  • DOAJ (DOAJ: Directory of Open Access Journals) (submittedVersion, cc-by-sa)
Topics
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › Electrocatalysts for Energy Conversion
  • Physical Sciences › Energy › Renewable Energy, Sustainability and the Environment › CO2 Reduction Techniques and Catalysts
  • Physical Sciences › Materials Science › Materials Chemistry › Hydrogen Storage and Materials
Keywords
electrochemical hydrogen production, water electrolysis, electrocatalysts, electrode materials, cathode catalysts, anode catalysts, electrocatalyst durability, large-scale hydrogen production, renewable energy, sustainable energy

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