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Cited by 375

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Environmental factors affecting the formation of methylmercury in low pH lakes

Open access
Winfrey, Michael R., Rudd, John W. M.·1990·Environmental Toxicology and Chemistry

Abstract

Recent studies have demonstrated elevated levels of mercury in fish from remote, low alkalinity and low pH lakes. The mechanisms of this enhanced bioaccumulation are poorly understood, but the amount of methylmercury produced in a lake can play a major role. Decreased pH stimulates methylmercury production at the sediment-water interface and possibly in the aerobic water column. Decreased pH also decreases loss of volatile mercury from lake water and increases mercury binding to particulates in water – factors that may increase methylation at low pH by enhancing the bioavailability of mercury for methylation. In anoxic subsurface sediments, decreased pH decreases the rate of mercury methylation, suggesting that methylmercury formation in the water column and at the sediment-water interface may be most important in acidified lakes. Sulfate-reducing bacteria are important mercury methylators in acidified lakes. Whether enhanced sulfate reduction stimulates methylmercury production in low pH lakes is presently unclear, although most of the available data do not support this hypothesis.

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Metadata

Authors
Winfrey, M. R., & Rudd, J. W. M.
Venue
Environmental Toxicology and Chemistry
Published
1990-07-01
Volume
9
Issue
7
Pages
853-869
ISSN
  • 0730-7268 (ISSN-L)
  • 1552-8618
OpenAlex
W2034483350
Cited by
375
References
52
FWCI
14.13
Type
journal article
Language
en
Open access
bronze

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CoChat. (2026). Citation check: Environmental factors affecting the formation of methylmercury in low pH lakes. https://app.cochat.ai/papers/10.1002/etc.5620090705
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Winfrey, M. R., & Rudd, J. W. M. (1990). Environmental factors affecting the formation of methylmercury in low pH lakes. Environmental Toxicology and Chemistry. https://doi.org/10.1002/etc.5620090705

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