The DOI matches its Crossref record; 13 of the 13 references it cites were found in a registry or an index.
PBI‐Based Polymer Membranes for High Temperature Fuel Cells – Preparation, Characterization and Fuel Cell Demonstration
Abstract
Proton exchange membrane fuel cell (PEMFC) technology based on perfluorosulfonic acid (PFSA) polymer membranes is briefly reviewed. The newest development in alternative polymer electrolytes for operation above 100 °C is summarized and discussed. As one of the successful approaches to high operational temperatures, the development and evaluation of acid doped polybenzimidazole (PBI) membranes are reviewed, covering polymer synthesis, membrane casting, acid doping, physicochemical characterization and fuel cell testing. A high temperature PEMFC system, operational at up to 200 °C based on phosphoric acid‐doped PBI membranes, is demonstrated. It requires little or no gas humidification and has a CO tolerance of up to several percent. The direct use of reformed hydrogen from a simple methanol reformer, without the need for any further CO removal, has been demonstrated. A lifetime of continuous operation, for over 5000 h at 150 °C, and shutdown‐restart thermal cycle testing for 47 cycles has been achieved. Other issues such as cooling, heat recovery, possible integration with fuel processing units, associated problems and further development are discussed.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
On the development of proton conducting polymer membranes for hydrogen and methanol fuel cells
Kreuer, K. D. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00632-3 · Cited by 2,969
Development of ionomer membranes for fuel cells
Kerres, J. A. (2001) · Journal of Membrane Science · doi:10.1016/s0376-7388(00)00631-1 · Cited by 1,022
The water content dependence of electro-osmotic drag in proton-conducting polymer electrolytes
Zawodzinski, T. A., Davey, J., Valerio, J., & Gottesfeld, S. (1995) · Electrochimica Acta · doi:10.1016/0013-4686(94)00277-8 · Cited by 586
Proton conduction in acid doped polybenzimidazole
Bouchet, R. (1999) · Solid State Ionics · doi:10.1016/s0167-2738(98)00466-4 · Cited by 501
Kerres, J., Ullrich, A., Meier, F., & Häring, T. (1999) · Solid State Ionics · doi:10.1016/s0167-2738(99)00181-2 · Cited by 454
Antonucci, P. L., Aricò, A. S., Cretı̀, P., Ramunni, E., & Antonucci, V (1999) · Solid State Ionics · doi:10.1016/s0167-2738(99)00206-4 · Cited by 436
Investigation of the conduction properties of phosphoric and sulfuric acid doped polybenzimidazole
Glipa, X., Bonnet, B., Mula, B., Jones, D. J., & Rozière, J. (1999) · Journal of Materials Chemistry · doi:10.1039/a906060j · Cited by 315
New membranes for direct methanol fuel cells
Jörissen, L., Gogel, V., Kerres, J., & Garche, J. (2002) · Journal of Power Sources · doi:10.1016/s0378-7753(01)00952-1 · Cited by 279
Real‐Time Mass Spectrometric Study of the Methanol Crossover in a Direct Methanol Fuel Cell
Wang, J. ‐., Wasmus, S., & Savinell, R. F. (1996) · Journal of The Electrochemical Society · doi:10.1149/1.1836622 · Cited by 237
Electroosmotic drag in polymer electrolyte membranes: an electrophoretic NMR study
Ise, M., Kreuer, K. D., & Maier, J. (1999) · Solid State Ionics · doi:10.1016/s0167-2738(99)00178-2 · Cited by 235
High pressure electrical conductivity studies of acid doped polybenzimidazole
Fontanella, J. J., Wintersgill, M. C., Wainright, J. S., Savinell, R. F., & Litt, M. (1998) · Electrochimica Acta · doi:10.1016/s0013-4686(97)10032-9 · Cited by 165
Hasiotis, C., Qingfeng, L., Deimede, V., Kallitsis, J. K., Kontoyannis, C. G., & Bjerrum, N. J. (2001) · Journal of The Electrochemical Society · doi:10.1149/1.1366621 · Cited by 154
Self-citationTrimethoxymethane as an alternative fuel for a direct oxidation PBI polymer electrolyte fuel cell
Wang, J. T., Lin, W. F., Weber, M., Wasmus, S., & Savinell, R. F. (1998) · Electrochimica Acta · doi:10.1016/s0013-4686(98)00142-x · Cited by 60
Cited by
Scientific Aspects of Polymer Electrolyte Fuel Cell Durability and Degradation
Borup, R., Meyers, J., Pivovar, B., Kim, Y. S., Mukundan, R., Garland, N., Myers, D., Wilson, M., Garzon, F., Wood, D., et al. (2007) · Chemical Reviews · doi:10.1021/cr050182l · Cited by 3,402
Water transport in polymer electrolyte membrane fuel cells
Jiao, K., & Li, X. (2011) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2010.06.002 · Cited by 1,086
Haider, R., Wen, Y., Ma, Z.-F., Wilkinson, D. P., Zhang, L., Yuan, X., Song, S., & Zhang, J. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00296h · Cited by 785
Asensio, J. A., Sánchez, E. M., & Gómez-Romero, P. (2010) · Chemical Society Reviews · doi:10.1039/b922650h · Cited by 746
Aliphatic/Aromatic Polyimide Ionomers as a Proton Conductive Membrane for Fuel Cell Applications
Asano, N., Aoki, M., Suzuki, S., Miyatake, K., Uchida, H., & Watanabe, M. (2006) · Journal of the American Chemical Society · doi:10.1021/ja0571491 · Cited by 657
Metadata
- Authors
- Li, Q., He, R., Jensen, J. O., & Bjerrum, N. J.
- Venue
- Fuel Cells
- Publisher
- Wiley
- Published
- 2004-07-29
- Volume
- 4
- Issue
- 3
- Pages
- 147-159
- ISSN
- 1615-6846 (ISSN-L)
- 1615-6854
- OpenAlex
- W1982511023
- Cited by
- 637
- References
- 13
- FWCI
- 18.31
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
