The water content dependence of electro-osmotic drag in proton-conducting polymer electrolytes
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Several later studies have presented evidence that the electroosmotic drag coefficient is constant and very close to unity up to a critical water content associated with the liquid-equilibration phase transition, whereafter it rises linearly.
“However, several later studies have presented evidence that the electroosmotic drag coefficient is constant and very close to unity up to a critical water content associated with the liquid-equilibration phase transition, whereafter it rises linearly (data tabulated in Table 7) [80,87,103,107]”
From Modelling the Proton-Conductive Membrane in Practical Polymer Electrolyte Membrane Fuel Cell (PEMFC) Simulation: A Review (2020) · cites this paper as [80]
Rigorous measurement of proton conductivity, water diffusivity, and electroosmotic drag coefficient for Nafion 1100 was initiated in the early 1990s in works by Zawodzinski et al. and Fuller and Newman.
“The rigorous measurement of these properties for Nafion 1100 was initiated in the early 1990s in a series of works by Zawodzinski et al. [52,53,79,80] and Fuller and Newman [81].”
From Modelling the Proton-Conductive Membrane in Practical Polymer Electrolyte Membrane Fuel Cell (PEMFC) Simulation: A Review (2020) · cites this paper as [80]
Cites
Determination of water diffusion coefficients in perfluorosulfonate ionomeric membranes
Zawodzinski, T. A., Neeman, M., Sillerud, L. O., & Gottesfeld, S. (1991) · The Journal of Physical Chemistry · doi:10.1021/j100168a060 · Cited by 987 · see citing works
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Holdcroft, S. (2014) · Chemistry of Materials · doi:10.1021/cm401445h · Cited by 481 · see citing works
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Weber, A. Z., & Newman, J. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1639157 · Cited by 462 · see citing works
Transport in Polymer-Electrolyte Membranes
Weber, A. Z., & Newman, J. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1580822 · Cited by 411 · see citing works
Pervaporation membranes in direct methanol fuel cells
Pivovar, B. S., Wang, Y., & Cussler, E. L. (1999) · Journal of Membrane Science · doi:10.1016/s0376-7388(98)00264-6 · Cited by 403 · see citing works
Water Management in PEM Fuel Cells
Berg, P., Promislow, K., St. Pierre, J., Stumper, J., & Wetton, B. (2004) · Journal of The Electrochemical Society · doi:10.1149/1.1641033 · Cited by 353 · see citing works
Transient analysis of polymer electrolyte fuel cells
Wang, Y., & Wang, C.-Y. (2005) · Electrochimica Acta · doi:10.1016/j.electacta.2004.08.022 · Cited by 310 · see citing works
Quasi-3D modeling of water transport in polymer electrolyte fuel cells
Kulikovsky, A. A. (2003) · Journal of The Electrochemical Society · doi:10.1149/1.1611489 · Cited by 171 · see citing works
A phenomenological model of water transport in a proton exchange membrane fuel cell
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Computational study of water transport in proton exchange membrane fuel cells
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Effect of Interfacial Water Transport Resistance on Coupled Proton and Water Transport Across Nafion
Cheah, M. J., Kevrekidis, I. G., & Benziger, J. (2011) · The Journal of Physical Chemistry B · doi:10.1021/jp204785t · Cited by 68 · see citing works
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- Authors
- Zawodzinski, T. A., Davey, J., Valerio, J., & Gottesfeld, S.
- Affiliations
- Los Alamos National Laboratory (US)
- Venue
- Electrochimica Acta
- Publisher
- Elsevier BV
- Published
- 1995-02
- Volume
- 40
- Issue
- 3
- Pages
- 297-302
- ISSN
- 0013-4686 (ISSN-L)
- OpenAlex
- W2083961092
- Cited by
- 586
- References
- 1
- Citations by year
- 2026: 17 · 2025: 16 · 2024: 20 · 2023: 16 · 2022: 14 · 2021: 24 · 2020: 11 · 2019: 18 · 2018: 14 · 2017: 9 · 2016: 15 · 2015: 20 · 2014: 24 · 2013: 25 · 2012: 24
- FWCI
- 6.71
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Electrochimica Acta (publishedVersion)
- Topics
- Physical Sciences › Engineering › Electrical and Electronic Engineering › Fuel Cells and Related Materials
- Physical Sciences › Materials Science › Materials Chemistry › Advancements in Solid Oxide Fuel Cells
- Physical Sciences › Engineering › Biomedical Engineering › Membrane-based Ion Separation Techniques
- Keywords
- electro-osmotic drag, proton transport, proton conducting polymer electrolytes, perfluorosulfonic acid membranes, moisture content, fuel cells
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