The DOI matches its Crossref record.
Helicity Induction in Helicate Self‐Organisation from Chiral Tris(bipyridine) Ligand Strands
Abstract
The chiral tris, and pentakis(bipyridine) ligand strands 3a and 4 were synthesised, each in optically pure form with (S,S)‐configuration. Ligand 3a yielded substituted double‐helical metal complexes, derived from the parent trihelicate structure 2, with Cu I and Ag I ions. The spectral data, in particular the 1 H‐NMR spectra and the large positive Cotton effect, indicate that helicate formation occurs with very high induction of helicity. Together with consideration of the steric effects in the two possible helical diastereoisomers (P)‐1 and (M)‐1 that may be formed, the data favour the preferential generation of the right‐handed double helicate (P)‐1 from the tris(bipyridine) strand 3a of(S,S)‐configuration.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Yashima, E., Ousaka, N., Taura, D., Shimomura, K., Ikai, T., & Maeda, K. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00354 · Cited by 2,004
Complete asymmetric induction of supramolecular chirality in a hydrogen-bonded assembly
Prins, L. J., Huskens, J., de Jong, F., Timmerman, P., & Reinhoudt, D. N. (1999) · Nature · doi:10.1038/19053 · Cited by 481
Krämer, R., Lehn, J., De Cian, A., & Fischer, J. (1993) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199307031 · Cited by 313
Self-citation
Metadata
- Authors
- Zarges, W., Hall, J., Lehn, J., & Bolm, C.
- Venue
- Helvetica Chimica Acta
- Publisher
- Wiley
- Published
- 1991-12-11
- Volume
- 74
- Issue
- 8
- Pages
- 1843-1852
- ISSN
- 0018-019X (ISSN-L)
- 1522-2675
- OpenAlex
- W2144731471
- Cited by
- 196
- References
- 0
- FWCI
- 7.07
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Helicity Induction in Helicate Self‐Organisation from Chiral Tris(bipyridine) Ligand Strands. https://app.cochat.ai/papers/10.1002/hlca.19910740827
- The paper
- Zarges, W., Hall, J., Lehn, J., & Bolm, C. (1991). Helicity Induction in Helicate Self‐Organisation from Chiral Tris(bipyridine) Ligand Strands. Helvetica Chimica Acta. https://doi.org/10.1002/hlca.19910740827
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
