Cited by 15Chemical and Physical Properties in Aqueous SolutionsIonic liquids properties and applicationsBiofuel production and bioconversion

Aqueous two‐phase/reverse micelle continuous process for recycling and simultaneous purification of polar ionic liquid from enzymatic hydrolysate

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Feng, Yuanyuan, Li, Qiang, Kang, Guoping, Ji, Gengsheng, Tang, Yubin, Tu, Jie·2016·Journal of Chemical Technology & Biotechnology

Abstract

BACKGROUND: Recently, ionic liquid (IL) involved pretreatment and enzymatic saccharification of cellulose toward biofuel have attracted extensive attention. However, separation and recycling of ionic liquid from enzymatic hydrolysate pose challenges to their large‐scale application. Almost all present work has focused on the recovery rate of IL, but little work has been done to analyze the purity and functioning of recovered IL. In this work, IL was recycled and purified from hydrolysis mixtures using an aqueous two‐phase/reverse micelle process (APTs/RM). RESULTS: An ionic liquid recovery yield of 92.3% and purity of 99.1% was obtained from the aqueous two‐phase and reverse micelles extraction process with optimized parameters. Impurities (e.g. lignin, HCO 3−, (NH 4)2 SO 4 and enzyme protein) were removed from the ionic liquid. When recycling over 10 runs, the APTs/RM process has distinct advantage over other reported recovery methods. CONCLUSION: It is demonstrated that the APTs/RM process is efficient for recycling and simultaneous purification of polar ionic liquid from an enzymatic hydrolysate mxiture. This method is potentially sustainable, efficient, and attractive for large‐scale application. © 2014 Society of Chemical Industry

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  • Ionic liquids can be recovered from pretreated mixtures by adding anti-solvents, reverse micelle method, or membrane distillation.

    “On the other hand, ILs can be recovered from the pretreated mixture by adding anti-solvents (e.g., ethanol or H2O, which would cause the generation of impurities in recovered ILs) [260], reverse micelle method (which can extract almost pure [Mmim] and [DMP] from pretreated mixture), or membrane distillation (separating ILs and water) [261].”

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References 24 · Cited by 15

Authors
Feng, Y., Li, Q., Kang, G., Ji, G., Tang, Y., & Tu, J.
Affiliations
  • Jiangsu University of Science and Technology (CN)
  • Factory of Sericultural Chemicals Sericultural Research Institute, CAAS Zhenjiang 212018 China
Corresponding author
  • Li, Qiang
  • Tang, Yubin
Venue
Journal of Chemical Technology & Biotechnology
Publisher
Wiley
Published
2014-11-20
Volume
91
Issue
2
Pages
394-399
ISSN
  • 0142-0356 (ISSN-L)
  • 0268-2575
  • 1097-4660
OpenAlex
W1565983587
Cited by
15
References
24
Citations by year
2026: 1 · 2025: 1 · 2023: 1 · 2022: 2 · 2021: 1 · 2020: 3 · 2019: 2 · 2017: 3 · 2016: 1
FWCI
1.05
Type
journal article
Language
en
Open access
Locations
Journal of Chemical Technology & Biotechnology (publishedVersion)
Funders
  • Agricultural Sci-Tech Support Program of Zhenjiang (NY2013008)
  • Natural Science Foundation of Jiangsu Province (BK2011527)
Topics
  • Physical Sciences › Chemical Engineering › Filtration and Separation › Chemical and Physical Properties in Aqueous Solutions
  • Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
  • Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
Keywords
ionic liquid recycling, aqueous two-phase extraction, reverse micelles, enzymatic hydrolysate, ionic liquid purification, lignocellulosic biomass pretreatment, enzymatic saccharification, lignin removal, biofuel production

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