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Layer‐dependent resonant Raman scattering of a few layer MoS2

Chakraborty, Biswanath, Matte, H. S. S. Ramakrishna, Sood, A. K., Rao, C. N. R.·2013·Journal of Raman Spectroscopy

Abstract

We report resonant Raman scattering of MoS 2 layers comprising of single, bi, four and seven layers, showing a strong dependence on the layer thickness. Indirect band gap MoS 2 in bulk becomes a direct band gap semiconductor in the monolayer form. New Raman modes are seen in the spectra of single‐ and few‐layer MoS 2 samples which are absent in the bulk. The Raman mode at ~230 cm−1 appears for two, four and seven layers. This mode has been attributed to the longitudinal acoustic phonon branch at the M point (LA(M)) of the Brillouin zone. The mode at ~179 cm−1 shows asymmetric character for a few‐layer sample. The asymmetry is explained by the dispersion of the LA(M) branch along the Γ‐M direction. The most intense spectral region near 455 cm−1 shows a layer‐dependent variation of peak positions and relative intensities. The high energy region between 510 and 645 cm−1 is marked by the appearance of prominent new Raman bands, varying in intensity with layer numbers. Resonant Raman spectroscopy thus serves as a promising non invasive technique to accurately estimate the thickness of MoS 2 layers down to a few atoms thick. Copyright © 2012 John Wiley & Sons, Ltd.

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Metadata

Authors
Chakraborty, B., Matte, H. S. S. R., Sood, A. K., & Rao, C. N. R.
Venue
Journal of Raman Spectroscopy
Publisher
Wiley
Published
2012-09-10
Volume
44
Issue
1
Pages
92-96
ISSN
  • 0377-0486 (ISSN-L)
  • 1097-4555
OpenAlex
W2133418430
Cited by
508
References
23
FWCI
9.12
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Layer‐dependent resonant Raman scattering of a few layer MoS2. https://app.cochat.ai/papers/10.1002/jrs.4147
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Chakraborty, B., Matte, H. S. S. R., Sood, A. K., & Rao, C. N. R. (2013). Layer‐dependent resonant Raman scattering of a few layer MoS2. Journal of Raman Spectroscopy. https://doi.org/10.1002/jrs.4147

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