Gas phase reaction of NO2 with alkenes and dialkenes
Abstract
Abstract The kinetics of the gas phase reactions of NO2 with a series of organics have been studied at 295 ± 2 K. It was observed that only 2,3‐dimethyl‐2‐butene and the conjugated dialkenes studied reacted at observable rates, with rate constants which ranged from 1.5 × 10−20 cm3 molecule−1 s−1 for 2,3‐dimethyl‐2‐butene to 1.3 × 10−17 cm3 molecule−1 s−1 for α‐phellandrene. These rate constants are compared with the available literature data and the mechanisms of these reactions are discussed.
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The preferential reactivity of NO2 toward CLA originates from the conjugated diene moiety.
“This preferential reactivity of ⅐ NO 2 toward CLA originates from the conjugated diene moiety, which in the gas phase is more reactive than simple monoalkenes by a factor of 10 3 -10 4 (39).”
From Conjugated linoleic acid is a preferential substrate for fatty acid nitration (2012) · cites this paper as [39]
In the gas phase, the conjugated diene moiety is more reactive than simple monoalkenes by a factor of 10^3-10^4.
“This preferential reactivity of ⅐ NO 2 toward CLA originates from the conjugated diene moiety, which in the gas phase is more reactive than simple monoalkenes by a factor of 10 3 -10 4 (39).”
From Conjugated linoleic acid is a preferential substrate for fatty acid nitration (2012) · cites this paper as [39]
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Conjugated linoleic acid is a preferential substrate for fatty acid nitration
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The reactions of nitrogen dioxide with dienes
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- Authors
- Atkinson, R., Aschmann, S. M., Winer, A. M., & Pitts, J. N.
- Affiliations
- University of California, Riverside (US)
- Corresponding author
- Atkinson, Roger
- ORCID
- Atkinson, Roger
- Venue
- International Journal of Chemical Kinetics
- Publisher
- Wiley
- Published
- 1984-06
- Volume
- 16
- Issue
- 6
- Pages
- 697-706
- ISSN
- 0538-8066 (ISSN-L)
- 1097-4601
- OpenAlex
- W1984289546
- Cited by
- 76
- References
- 30
- Citations by year
- 2025: 2 · 2023: 1 · 2022: 1 · 2019: 3 · 2018: 1 · 2013: 1 · 2012: 1
- FWCI
- 3.18
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- International Journal of Chemical Kinetics (publishedVersion)
- Funders
- National Science Foundation
- Topics
- Physical Sciences › Earth and Planetary Sciences › Atmospheric Science › Atmospheric chemistry and aerosols
- Physical Sciences › Chemical Engineering › Fluid Flow and Transfer Processes › Advanced Combustion Engine Technologies
- Physical Sciences › Chemistry › Physical and Theoretical Chemistry › Advanced Physical and Chemical Molecular Interactions
- Keywords
- nitric oxide dimer, NO2, gas-phase reactions, alkenes, 2,3-dimethyl-2-butene, α-phellandrene, rate constants, reaction mechanism, atmospheric chemistry
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