Corrosion of 15Mo3 carbon steel superheater tubes in waste incineration plants: A comparison between a field‐returned tube and laboratory tests
Open accessAbstract
In this study, a field‐returned superheater tube of carbon steel 16Mo3 (1.5415) was analyzed in detail. In addition to cross‐section analysis, different scales were investigated layer by layer using microscopic, diffraction, and spectroscopic techniques. The corrosion products can be divided into three layers: The layer adjacent to the metallic tube surface was an iron‐ and chlorine‐rich scale, followed by an FeS layer present at the gas flow side, and the outermost layer was an iron oxide scale consisting of Fe 3 O 4 and α‐Fe 2 O 3. The different mechanisms responsible for the structure of such scale formation and the different corrosion products formed at the tube are discussed. Furthermore, the root cause for the disability to form a protective scale under such conditions was identified by comparison with results from laboratory tests.
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Alkali chlorides initiate chlorine-induced corrosion on boiler steels under thermodynamically favourable conditions, followed by active oxidation by chlorine.
“The alkali chlorides initiate chlorine-induced corrosion on boiler steels under thermodynamically favourable conditions, followed by active oxidation by chlorine.”
From High Temperature Corrosion Resistant and Anti-slagging Coatings for Boilers: A Review (2024) · cites this paper as [12]
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Grabke, H. J., Reese, E., & Spiegel, M. (1995) · Corrosion Science · doi:10.1016/0010-938x(95)00011-8 · Cited by 537 · see citing works
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High Temperature Corrosion Resistant and Anti-slagging Coatings for Boilers: A Review
Khantisopon, K., Singh, S., Jitputti, J., Berndt, C. C., & Ang, A. S. M. (2024) · High Temperature Corrosion of Materials · doi:10.1007/s11085-024-10251-0 · Cited by 24 · see citing works
- Authors
- Krumm, L., & Galetz, M. C.
- Affiliations
- Society for Chemical Engineering and Biotechnology (DE)
- Corresponding author
- Galetz, Mathias C.
- ORCID
- Galetz, Mathias C.
- Venue
- Materials and Corrosion
- Publisher
- Wiley
- Published
- 2019-11-18
- Volume
- 71
- Issue
- 1
- Pages
- 166-177
- ISSN
- 0043-2822 (ISSN-L)
- 0947-5117
- 1521-4176
- OpenAlex
- W2988035205
- Cited by
- 8
- References
- 1
- Citations by year
- 2026: 1 · 2024: 2 · 2023: 3 · 2022: 1 · 2020: 1
- FWCI
- 0.37
- Type
- journal article
- Language
- en
- Open access
- hybrid
- doi.org
- Licence
- Locations
- Materials and Corrosion (publishedVersion, cc-by)
- Funders
- Bundesministerium für Bildung und Forschung (Vokos/03X3589)
- Topics
- Physical Sciences › Engineering › Aerospace Engineering › High-Temperature Coating Behaviors
- Physical Sciences › Materials Science › Materials Chemistry › Corrosion Behavior and Inhibition
- Physical Sciences › Materials Science › Materials Chemistry › Material Properties and Failure Mechanisms
- Keywords
- superheater tubes, waste incineration, high-temperature corrosion, corrosion scale, iron oxide scale, magnetite, hematite
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