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Cited by 99Advanced Polymer Synthesis and CharacterizationPolymer Synthesis and Characterizationbiodegradable polymer synthesis and properties

The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.

Kinetics and mechanism of the isomerization polymerization of 2‐methyl‐2‐oxazoline by benzyl chloride and bromide initiators. Effect of halogen counteranions

Saegusa, Takeo, Kobayashi, Shiro, Yamada, Akira·1976·Die Makromolekulare Chemie
DOI 10.1002/macp.1976.021770805
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Abstract

Abstract Kinetic studies of the isomerization polymerization of 2‐methyl‐2‐oxazoline (2) initiated with benzyl chloride (1a) or bromide (1b) were carried out by NMR spectroscopy. The polymerization initiated with 1a proceeded exclusively via a covalently bonded alkyl chloride species 5, whereas the polymerization of the system initiated with 1b proceeded via a oxazolinium bromide 10 as the propagating end. The propagation rate constant kp with 1a was about 1/40 of that found with 1b at 40°C in CD3CN. The mechanistic difference is explained by the different nucleophilicities of the counteranions, Cl— and Br—. A model compound for the propagation with 1b as initiator was also examined changing the temperature and the solvent.

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Crossref · 10.1002/macp.1976.021770805

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6 of 6 references verified0 citation errors · 0 not checkable

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  • Polymerization of 2-alkyl-2-oxazolines can be initiated by classical alkylating reagents, such as benzyl bromide.

    “The polymerization of 2-Alkyl-2-oxazolines can be initiated by classical alkylating reagents, such as benzyl bromide [56] (see Figure 20).”

    From Ring-Opening Polymerization—An Introductory Review (2013) · cites this paper as [56]

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Metadata

Authors
Saegusa, T., Kobayashi, S., & Yamada, A.
Affiliations
Kyoto University (JP)
ORCID
Yamada, Akira
Venue
Die Makromolekulare Chemie
Publisher
Wiley
Published
1976-08
Volume
177
Issue
8
Pages
2271-2283
ISSN
0025-116X (ISSN-L)
DOI
10.1002/macp.1976.021770805
OpenAlex
W1537489237
Cited by
99
References
6
Citations by year
2026: 2 · 2025: 1 · 2024: 2 · 2023: 1 · 2022: 1 · 2021: 1 · 2019: 2 · 2018: 2 · 2017: 2 · 2016: 4 · 2015: 2 · 2014: 2 · 2013: 2 · 2012: 3
FWCI
1.17
Type
journal article
Language
en
Open access
closed
Licence
onlinelibrary.wiley.com/termsAndConditions#vor (vor, 9719 d)
Locations
Die Makromolekulare Chemie (publishedVersion)
Topics
  • Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Polymers and Plastics › Polymer Synthesis and Characterization
  • Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
Keywords
2-methyl-2-oxazoline, propagation rate constant, polymerization mechanism, solvent and temperature effects

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