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Synthetic and thermodynamic investigations in the polymerization of ethylene carbonate
Abstract
The polymerization of ethylene carbonate using different metal alkoxides results in poly(oxy‐ethylene‐alt‐ethylene carbonate). Polymers containing low amounts of CO 2 or pure poly(oxy‐ethylene) are formed with anionic and cationic initiators. Poly(ethylene carbonate) is not accessible from ethylene carbonate by variation of temperatures and concentration. The reason is not the low ceiling temperature, but the positive enthalpy of polymerization. A Δ Hp‐value of 125,6 kJ/mol was obtained from calorimetric investigations.
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Kricheldorf, H. R., Berl, M., & Scharnagl, N. (1988) · Macromolecules · doi:10.1021/ma00180a002 · Cited by 597
Polylactones 12. Cationic polymerization of 2,2‐dimethyltrimethylene carbonate
Kricheldorf, H. R., Dunsing, R., & Albet, A. S. I. (1987) · Die Makromolekulare Chemie · doi:10.1002/macp.1987.021881020 · Cited by 93
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Metadata
- Authors
- Vogdanis, L., Martens, B., Uchtmann, H., Hensel, F., & Heitz, W.
- Venue
- Die Makromolekulare Chemie
- Publisher
- Wiley
- Published
- 1990-03
- Volume
- 191
- Issue
- 3
- Pages
- 465-472
- ISSN
- 0025-116X (ISSN-L)
- OpenAlex
- W2156070878
- Cited by
- 162
- References
- 2
- FWCI
- 2.59
- Type
- journal article
- Language
- en
- Open access
- closed
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- Vogdanis, L., Martens, B., Uchtmann, H., Hensel, F., & Heitz, W. (1990). Synthetic and thermodynamic investigations in the polymerization of ethylene carbonate. Die Makromolekulare Chemie. https://doi.org/10.1002/macp.1990.021910301
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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
