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Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions
Open accessAbstract
The thermal decomposition of in a mixture (1:1 molar ratio) of ethylene carbonate (EC)/dimethyl carbonate (DMC) at 85°C is compared to the reaction between EC/DMC and gas. Both produce a brown solution and gaseous products. The reaction products from and in 1:1 EC/DMC, detected by gas chromatography, are similar. Proton nuclear magnetic resonance provided evidence for the presence of oligoether carbonates in the reaction products. © 2001 The Electrochemical Society. All rights reserved.
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Metadata
- Authors
- Sloop, S. E., Pugh, J. K., Wang, S., Kerr, J. B., & Kinoshita, K.
- Venue
- Electrochemical and Solid-State Letters
- Publisher
- The Electrochemical Society
- Published
- 2001
- Volume
- 4
- Issue
- 4
- Pages
- A42
- ISSN
- 1099-0062 (ISSN-L)
- OpenAlex
- W2050483263
- Cited by
- 577
- References
- 0
- FWCI
- 20.91
- Type
- journal article
- Language
- en
- Open access
- bronze
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- Sloop, S. E., Pugh, J. K., Wang, S., Kerr, J. B., & Kinoshita, K. (2001). Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions. Electrochemical and Solid-State Letters. https://doi.org/10.1149/1.1353158
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