Novel Aliphatic Polyesters Based on Functional Cyclic (Di)Esters
Abstract
Recent progress in the chemical synthesis of novel aliphatic polyesters via ring‐opening polymerization of functional cyclic (di)esters are reviewed in this article. Syntheses of these functional aliphatic polyesters are being classified into three groups according to the structure of the cyclic monomers: (i) cyclic diesters, (ii) morpholine‐2,5‐dione derivatives, and (iii) cyclic esters. Progress in the synthesis and polymerization of monomers in each category is reported with an emphasis on controlled synthesis. The recent achievements have enabled the synthesis of a variety of novel aliphatic polyesters, including hydrophilic, halogenated, and unsaturated polyesters. Structure of the most common R‐functionalized cyclic precursors of aliphatic polyesters. magnified image Structure of the most common R‐functionalized cyclic precursors of aliphatic polyesters.
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High molecular weight polyesters can be easily prepared under mild conditions from lactones of different ring-size, substituted or not by functional groups.
“High molecular weight polyesters can be easily prepared under mild conditions from lactones of different ring-size, substituted or not by functional groups [2,3].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [2]
The first strategy is based on synthesis and polymerization of lactones substituted in α or γ position.
“The first one is based on the synthesis and polymerization of lactones substituted in αor γ-position [99].”
From Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆ (2008) · cites this paper as [99]
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- Authors
- Lou, X., Detrembleur, C., & Jérôme, R.
- Affiliations
- University of Liège (BE)
- Corresponding author
- Jérôme, Robert
- Venue
- Macromolecular Rapid Communications
- Publisher
- Wiley
- Published
- 2003-02
- Volume
- 24
- Issue
- 2
- Pages
- 161-172
- ISSN
- 1022-1336 (ISSN-L)
- 1521-3927
- OpenAlex
- W2027424784
- Cited by
- 132
- References
- 1
- Citations by year
- 2025: 3 · 2024: 2 · 2023: 2 · 2022: 3 · 2021: 2 · 2020: 1 · 2019: 5 · 2018: 5 · 2017: 8 · 2016: 7 · 2015: 7 · 2014: 4 · 2013: 10 · 2012: 6
- FWCI
- 2.85
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Macromolecular Rapid Communications (publishedVersion)
- Open Repository and Bibliography (University of Liège) (submittedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › biodegradable polymer synthesis and properties
- Physical Sciences › Chemistry › Organic Chemistry › Advanced Polymer Synthesis and Characterization
- Physical Sciences › Materials Science › Polymers and Plastics › Polymer crystallization and properties
- Keywords
- aliphatic polyesters, ring-opening polymerization, cyclic diesters, cyclic esters, controlled polymerization, unsaturated polyester resin
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